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74 Cards in this Set

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Thermal Efficiency

The extent of the energy conversion from heat to work. The thermal efficiency is the ratio of the net work of the cycle to the heat added. (e=Wnet/Qa)

Otto Cycle

An ideal cycle that assumesheat addition occurs instantaneously while the piston is at top dead center.It consists of four internally reversible processes.



1-2. Isentropic compression


2-3. Constant volume heat addition


3-4. Isentropic expansion


4-1. Constant volume heat rejection

Diesel Cycle

An ideal cycle thatassumes heat addition occurs during a constant-pressure process thatstarts with the piston at top dead center.



1-2. Isentropic compression


2-3. Constant pressure heat addition


3-4. Isentropic expansion


4-1. Constant volume heat rejection

Dual Cycle

An air-standard cycle that can be made to approximate thepressure variations more closely.



1-2. Isentropic compression


2-3. Constant volume heat addition


3-4. Constant pressure heat addition


4-5. Isentropic expansion


5-1. Constant volume heat rejection

Displacement Volume

The volume displaced by the piston as it moves between top dead center (tdc) and bottom dead center (bdc).

Clearance Volume

The minimum volume formed in the cylinder when the piston is at TDC is called the clearance volume

Percent Clearance

ratio of clearance volume and displacement volume (V2/V1-V2)

Compression Ratio

defined as the volume at bottom dead center divided by the volume at top dead center.

Isentropic Compression Ratio

?

Mean Effective Pressure

A parameter used to describe the performance of reciprocating piston engines. It is a fictitious pressure that, if it acted on the piston during the entire power stroke, would produce the same amount of net work as that produced during the actual cycle.

Brayton Cycle

was first proposed by George Brayton for use in thereciprocating oil-burning engine that he developed around 1870.


1-2 Isentropic compression (in a compressor)


2-3 Constant-pressure heat addition


3-4 Isentropic expansion (in a turbine)


4-1 Constant-pressure heat rejection

Back work ratio

The fraction of the turbine work used to drive the compressor is called the back work ratio. (Compressor work/turbine work)

Compressor efficiency

the isentropic efficiency of a compressor is defined as the ratio of the work input required to raise the pressure of a gas to a specified value in an isentropic manner to the actual work input.

Turbine Efficiency

isentropic efficiency of a turbine is defined as the ratio of the actual work output of the turbine to the work output that would be achieved if the process between the inlet state and the exit pressure were isentropic.

Fossil Fuels

Fossil fuels primarily consist of natural gas, crude-oil-derived fuels, and coal. Non-renewable. Fossil fuels are made from decomposing plants and animals. These fuels are found in the Earth's crust and contain carbon and hydrogen, which can be burned for energy.

Biofuels

liquid, solid, or gaseous fuel produced by conversion of biomass such as bioethanol from sugar cane or corn, charcoal or woodchips, and biogas from anaerobic decomposition of wastes.

Renewable fuel

fuels produced from renewable resources. Examples include: biofuels and Hydrogen fuel.

Non-renewable fuel

Non-renewable energy comes from sources that will run out or will not be replenished in our lifetimes—or even in many, many lifetimes. Most non-renewable energy sources are fossil fuels: coal, petroleum, and natural

Carbon Neutral Fuel

Carbon-neutral fuel is fuel which produces no net-greenhouse gas emissions or carbon footprint.

Non-carbon Neutral Fuel

produces greenhouse emissions.

Methane

produced by waste digesters and landfills.

Methanogenic Bacteria

Methane is created in landfills by methanogenic bacteria. Methanogenic bacteria decompose these organic materials to produce primarily carbon dioxide and methane.

Biodigester

a system that biologically digests organic material, either anaerobic (without oxygen ) or aerobically (with oxygen).

Ethane (C2H6)

Ethane is the second simplest alkane followed by methane. It contains 2 carbon atoms and 6 hydrogen atoms. So the formula for ethane is C2H6. mainly used to produce ethylene, a feedstock to make plastics.

Liquified Petroleum Gas

produced at natural gas-processing plants consists of ethane, propane, and butane. LPG produced from crude oil at refineries also includes refinery gases such as ethylene, propylene, and butylene. LPG is stored in tanks under pressure as a liquid and is a gas at atmospheric pressure. At 38°C, the maximum vapor pressure is 208 kPa for commercial LPG.

Natural gas

is a mixture of hydrocarbons and small quantities of various non-hydrocarbons existing in the gaseous phase or in solution with crude oil

Syngas

(synthetic gas, historically called producer gas or town gas) is created by passing a less than stoichiometric amount of air or oxygen through a hot bed of coal or biomass particles. This is a process called gasification and is accomplished in a gasifier, where input air is restricted so that the main output is hydrogen and carbon monoxide along with nitrogen and carbon dioxide.

Carbon monoxide

Carbon monoxide (CO) is an odorless, colorless gas formed by the incomplete combustion of fuels.

Hydrogen

is manufactured by reforming natural gas, partial oxidation of liquid hydrocarbons, or extraction from syngas. For example, natural gas can be converted to H2, CO, and CO2 by a reaction with steam over a catalyst at 800°C–900°C. A further shift of CO and H2O to H2 and CO2 is then carried out, and the gas is cooled and scrubbed to remove CO2.

Fractional Distillation

the separation of a mixture into its component parts, or fractions.

Gasifier

where gasification takes place

Particulate scrubber

a scrubber in which a liquid is mixed with the gas to collect solids. In particulate scrubbers, the liquid is dispersed into the gas as a spray, and the liquid droplets are the main collectors for the solid particles.

Heating value

is the heat release per unit mass when the fuel, initially at 25°C, reacts completely with oxygen, and the products are returned to 25°C.

Higher heating value

when the water in the combustion products is condensed

Lower heating value

when the water in the combustion products is not condensed

Latent heat of vaporization

the thermal energy required for a liquid to vaporize to a gas or the amount that is released when a gas condenses to a liquid.

Volumetric Analysis

this method involves measurement of the volume of a solution whose concentration is known and applied to determine the concentration of the analyte. In other words, measuring the volume of a second substance that combines with the first in known proportions is known as Volumetric analysis or titration.

Density

mass per unit volume

Autoignition Temperature

is the lowest temperature required to initiate self-sustained combustion in a standard container in atmospheric air in the absence of a spark or flame.

Flash Point

indication of the maximum temperature at which a liquid fuel can be stored and handled without serious fire hazard. Flash point is the minimum temperature at which fuel will rapidly catch fire when exposed to an open flame located above a mixture.

Ultimate analysis

is an analysis of the composition of fuel which gives on mass basis, the relative amounts of carbon, hydrogen, oxygen, sulfur, ash and moisture.

Cracking

in petroleum refining, the process by which heavy hydrocarbon molecules are broken up into lighter molecules by means of heat and usually pressure and sometimes catalysts. Cracking is the most important process for the commercial production of gasoline and diesel fuel.

Thermal Cracking

a process in which hydrocarbons present in crude oil are subject to high heat and temperature to break the molecular bonds and breaking down long-chained, higher-boiling hydrocarbons into shorter-chained, lower-boiling hydrocarbons.

Hydrogenation

- a chemical reaction between molecular hydrogen and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum.

Aliphatic Hydrocarbon

any chemical compound belonging to the organic class in which the atoms are connected by single, double, or triple bonds to form nonaromatic structures. Have open chains. ( 3 types: alkanes, alkenes and alkynes)

Alkanes (paraffins)

are saturated hydrocarbons and are composed ofcarbon and hydrogen atoms connected by single bonds (C–C or C–H bonds)

Alkenes ( olefins )

double bond. also have the formula CnH2n, but two neighboring carbon atoms share a pair of electrons forming a double bond.

Alkynes

triple bond. They can appear as intermediate species in the fuel-rich zone due to incomplete combustion.

Aromatic Hydrocarbon

polycyclic aromatic hydrocarbons (PAHs), can be formed in the refining process and can also be formed during incomplete combustion in the fuel rich zone.

Specific Gravity

the density of the fuel divided by the density of water at the same temperature.

Viscosity

a measure of a liquid’s resistance to flow.

Distillation curve

a graphical depiction of the boiling temperature of a fluid mixture plotted against the volume fraction distilled.

Sulfur content

Fuel sulfur content is the sulfur content of the fuel as a percentage of its mass. Sulfur is considered an undesirable contaminant because, when burned, it generates sulfur oxides.

Octane number

(ON) indicates the ability of a fuel to resist engine knock (onset of autoignition), an abnormal combustion phenomenon in a spark ignition engine. The higher an octane number, the more stable the fuel.

Cetane number

(CN) indicates the tendency of a fuel to autoignite when undergoing compression ignition.

A fuel with a high cetane number autoignites easily, resulting in a short ignition delay, the time between fuel injection and autoignition. The cetane number of a fuel correlates inversely with its octane number.

Reid Vapor Pressure (RVP)

Volatility is measured by Reid vapor pressure, which is the equilibrium pressure exerted by vapor over liquid at 37.8°C and is expressed in units of pounds per square inch (psi) absolute.

If the RVP is too high, too much of the gasoline will evaporate before reaching the engine, causing vapor lock.

Automotive Gasoline -

a carefully selected blend of alkanes (paraffins), alkenes (olefins), cycloalkanes (naphthenes), and aromatics, which varies slightly at different refineries and is blended slightly differently depending on geographic region and season of the year.

Diesel

a mixture of C10 to C15 hydrocarbons with a higher boiling point range than gasoline.

Gas Turbine Fuel

not limited by antiknock or ignition delay requirements and have a wide range of boiling points.

Fuel Oil (for heating)

any of various fractions obtained from the distillation of petroleum (crude oil). It covers a wide range of petroleum products, which have been divided into six grades.

coal

a heterogeneous mineral consisting principally of carbon, hydrogen, and oxygen, with lesser amounts of sulfur and nitrogen.

Anthracite

The highest rank of coal. It is a hard, brittle, and black lustrous coal, often referred to as hard coal, containing a high percentage of fixed carbon and a low percentage of volatile matter.

Lignite

brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat content

Bituminous coal

or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt.

Sub-bituminous Coal

a lower grade of coal that contains 35–45% carbon. The properties of this type are between those of lignite, the lowest grade of coal, and those of bituminous coal, the second-highest grade of coal. Sub-bituminous coal is primarily used as a fuel for steam-electric power generation.

Biomass

a range of organic materials recently produced from plants and waste from animals that feed on plants.

Peat

formed from decaying woody plants, reeds, sedges, and mosses in watery bogs and marshlands and is usually formed in northern climates.

Refuse-Derived Fuels

Refuse solid fuel includes municipal solid waste (MSW) and agricultural waste.

Proximate Analysis [ASTM D3172] -

[ASTM D3172 in the Annual Book of ASTM Standards] determines the moisture, volatile combustible matter, fixed carbon, and ash in a fuel sample.

Ultimate Analysis [ASTM D3176]

[ASTM D3176 in the Annual Book of ASTM Standards] provides the major elemental composition of the fuel, usually reported on a dry, ash-free basi

Heating Value [ASTM D5865]

is determined in a calorimeter [ASTM D5865 in the Annual Book of ASTM Standards]. A small sample of fuel is placed in the calorimeter, which is pressurized with excess oxygen. A spark ignites the sample, and the temperature rise in a surrounding water jacket is measured.

Hardgrove Grindability Test [ASTM D409]

[ASTM D409 in Annual Book of ASTM Standards, Vol. 5.06] is used to determine the relative ease of pulverization of coals.

Free Swelling Index [ASTM D720]

[ASTM D720 in Annual Book of ASTM Standards, Vol. 5.06] is an indication of the caking characteristics of coals when burned as a fuel.

Ash Fusion Temperature [ASTM D1857] -

[ASTM D1857 in the Annual Book of ASTM Standards, Vol. 5.06] is determined by heating a ground fuel sample at 850°C in air and then in oxygen to ensure complete oxidation of the fuel.