Whats In A Medicine

Front 1

Alcohols contain the________

Back 1

Hydroxyl functional group
-OH

Front 2

The alkoxy group is ___

Back 2

-O-R'

Front 3

Alcohols are polar because _____

Back 3

OH bond is polarised

Front 4

Alcohols bond between molecules of alcohols via:

Back 4

Hydrogen bonding

Front 5

Primary alcohol is:

Back 5

end of hydrocarbon chain

Front 6

Secondary alcohol is:

Back 6

middle of hydrocarbon chain

Front 7

Tertiary alcohol is:

Back 7

Attached to carbon with no hydrogen

Front 8

Alcohols are oxidised by:

Back 8

Acidified potassium dichromate

Front 9

Primary alcohol oxidation reagants and products:

Back 9

Acidified potassium dichromate
DISTILL for aldehyde
REFLUX for carboxylic acid

Front 10

Secondary alcohol oxidation reagents and products:

Back 10

Acidified potassium dichromate
Reflux for Ketone

Front 11

Aldehyde suffix =

Back 11

-al

Front 12

Ketone suffix =

Back 12

one

Front 13

Carboxylic acid suffix =

Back 13

-oic acid

Front 14

Dehydration of alcohols is __
Conditions are __

Back 14

Removal of water
Alumina at 300*C or heating with concentrated sulfuric acid

Front 15

For an aldehyde, the oxidising solution ( ___________) is:

Back 15

acidified potassium dichromate dripped slowly into hot alcohol and distilled off

Front 16

Carboxylic acids contain the_______________ group

Back 16

Carboxyl group

Front 17

Ester group looks like:

Back 17

O
||
-C-O-R'

Front 18

Acyl chloride looks like:

Back 18

O
||
-C - Cl

Front 19

Amides look like:

Back 19

O
||
-C - NH2

Front 20

Acid anhydrides look like:

Back 20

O
||
-C
\
O
/
- C
||
O

Front 21

In order of OH goup acidity:

Back 21

ethanol<water<phenol<carboxylic acid

Front 22

OH group acidity varies because of

Back 22

the stability of the R-O- ion

Front 23

More stable R'-O- ions are ____ acidic
These arise because of:

Back 23

more
Arise because of delocalisation of electrons across the ion

Front 24

Iron chloride gives ______ when reacted with a ____

Back 24

Iron chloride gives purple solution with a phenol

Front 25

The test for a phenol is :

Back 25

iron(III) chloride
Gives a purple complex with a phenol

Front 26

Esters are formed using:

Back 26

Conc. Sulfuric acid - Reflux

-Acid anhydride of Acyl Chloride - Anhydrous (phenols)

Front 27

Ester suffix is -

Back 27

-oate

Front 28

In an ester, the remaining O in the ester link is from the

Back 28

alcohol

Front 29

CH3-CH2-O-C-CH3 would be named
||
O

Back 29

Ethyl Ethanoate

Front 30

Hydrolysis of esters goes to completion with

Back 30

alkali i.e. dilute sodium hydroxide

Front 31

Hydrolysis of esters forms a carboxylate salt with

Back 31

acid

Front 32

Dilute HCL hydrolysis of an ester does/does not__

Back 32

does not go to completion

Front 33

When a molecule interacts with electromagnetic radiation

Back 33

it can vibrate, rotate, translate or electronic changes

Front 34

In infrared spectroscopy changes are in

Back 34

vibrational energies of the molecules

Front 35

Wavenumber =

Back 35

1/wavelength :cm3

Front 36

Wavelength =

Back 36

h :um

Front 37

Frequency =

Back 37

v : Hz

Front 38

Vibrational changes cause bonds to

Back 38

Stretch

Front 39

In the machine, the infrared source is:

Back 39

A heated filament

Front 40

Infrared energy is reflected through two samples which are:

Back 40

-Sample solution
-Reference solution of solvent only

Front 41

Once passed through sample/reference, light passes through a

Back 41

NaCl prism

Front 42

The NaCl prism is chosen as:
Light passes through to the IR detector which records :

Back 42

It does not absorb IR light
Transmittance

Front 43

On an IR spectrum the baseling is at the___

Back 43

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