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23 Cards in this Set

  • Front
  • Back

If the overall order of a reaction is 0, what is the unit for the rate constant?

M S^-1

If the overall order of the reaction is first order, what are the units for the rate constant?

S^-1

If the overall order of the reaction is second order, what are the units for the rate constant?

M^-1 S^-1

If the overall order of the reaction is third order, what are the units for the rate constant?

M^-2 S^-1

What is the rate expression?

-change in concentration/ change in time



🔺[ ]/🔺time

What's the average rate of reaction?

The rate at which a reaction proceeds over a time period.

What is instantaneous rate?

The rate at which a reaction is proceeding at a specific time or [ ].

What is the initial reaction rate?

The instantaneous reaction rate at time zero.

Given:


aA + bB ➡️ cC + dD


Relate the rates of consumption of the products to the rates of formation of the products.

How does concentration affect the rate of a reaction?

Higher concentration= faster rate

How does temperature affect the rate of a reaction?

Temperature increase=rate increase and vice versa

For the reaction:


aA + bB ➡️ cC + dD



What is the rate law?

Rate=k[A]^x[B]^y

What is the overall order?


What does molecularity mean?

The number of reactant species.

What is the overall order of this reaction?

0 order

What is the overall order of the reaction?

0 order

What is the overall order of the reaction?


1st order

What is the overall order of the reaction?

1st order

What is the overall order of the reaction?

2nd order

What is the overall order of the reaction?

2nd order

What are the 3 postulates of collision theory?

1. The rate of the reaction is proportional to the rate of reactant collisions.


2. Must collide in correct/same orientation for bonding.


3. Collision must occur w/enough energy

What is the Arrhenius equation?

k=Ae ^-Ea/RT



Where R=8.314J/mol/K and T=kelvin (c+273)