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18 Cards in this Set

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  • Back

What is the first law of thermodynamics?

Energy must be exchanged between a chemical system and the surroundings, but the total energy remains constant

What are standard conditions?

273K


1 atm


1mol dm-3

Define enthalpy change of formation

The enthalpy change when 1 mole of a compound is formed from its constituent elements in standard conditions

Define enthalpy change of combustion

The enthalpy change when 1 mole of a substance is completely burnt in excess oxygen

What are the products of combustion?

carbon dioxide and water

Define Hess's Law

The overall enthalpy change is independent of route taken, providing the initial states of the reactants and final states of the products remain constant

Why are bond enthalpies average values?

The same bond can exist in different environments

What does the m represent in the calorimetry equation?

Mass of liquid

What does the c represent in the calorimetry equation?

Specific heat capacity

Why do you have to add excess magnesium in the p.s.c experiment?

To be able to calculate moles

Why is extrapolating the graph more accurate than using the highest temperature recorded?

It gives the answer based on an immediate reaction with no heat loss to the surroundings

Name 4 major pollutants

sulphur dioxide




carbon dioxide




carbon monoxide




unburnt hydrocarbons

What does sulphur dioxide cause?

acid rain

How is ethanol carbon neutral?

The carbon dioxide removed from the atmosphere (photosynthesis) is equal to that given in burning

How are super catalysts more efficient?

They lower the activation energy more than the conventional catalysts

Why are super catalysts good?

Can run industrial processes at a lower temperature and pressure = less energy required, therefore less pollution and a lower running cost


Product may also be formed faster

What are the advantages of recycling?

Doesn't replete raw materials




Less energy used = less pollution




Rids of waste




Gives people jobs

Why is it useful for the reaction to produce steam?

It can be trapped and used to generate energy