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65 Cards in this Set

  • Front
  • Back
  • 3rd side (hint)

What is an Isothermal process?

During expansion or compression, quantities of Q and W so proportioned, temperature of fluid remains constant.

Expansion. Compression. Q and W proportion.

What is a path.

Line joining intermediates states of a process in a reversible process.

Line.

What is a reversible process?

A process that can be returned to its original state. (Both system and environment)

Both system and surrounding.

First Law Corollary 1

There exists a property of a closed system such that a change in its value is sum of net heat and work done during a change of state.

U = Q + W

First Law Corollary 2

Internal energy in a closed system remains unchanged if the system is isolated from the surroundings

Adiabatic

First Law Corollary 3

Perpetual motion machine of first kind impossible.

Too easy Bruhhhh.

Reversible process (Closed system)

When there are continuous series of equilibrium states during a process, intermediate states could be located on a diagram, line representing the path could be drawn.

Path. Cause of lines caused by intermediate equilibrium.

Thermodynamic equilibrium

When no further changes occur when a system is isolated form the surrounding such that no heat and work crosses

Changes due to heat and work.

System

A region in space containing a quantity of matter whose behavior is being investigated.

Region in space. Matter.

System

A region in space containing a quantity of matter whose behavior is being investigated.

Region in space. Matter.

Surrounding

Restricted to portions of matter external to the system which are affected by changes within the system

Boundary

Separates system and surrounding

Closed System

Contains same matter throughout process being investigated. Work and Heat only, cross the boundary.

It's content. What crosses boundary ?

Closed System

Contains same matter throughout process being investigated. Work and Heat only, cross the boundary.

It's content. What crosses boundary ?

Open system

Matter, heat and work may cross the boundary while the process is being investigated

What crosses boundary ? When ?

Property

Required to determine state of a simple Fluid

What's the importance ?


It's the Property of what ?

Property

Required to determine state of a simple Fluid

What's the importance ?


It's the Property of what ?

Irreversible process

Not in equilibrium in intermediate states.

First Law

When a closed system is taken through a cycle, the net work delivered to the surroundings is equal to the net heat intake from the surroundings

What type of system ?


C of E.

Zeroth Law

When two bodies equal in temperature to a third body, they are all equal in temperature.

Body A, B, C.

Thermometric Property

Observable characteristic in a system and can be used to make comparisons. Like temperature.

Work

Something which appears at the system boundary when a system changes state due to movement of boundary under action of a force

Where it appears?


When it appears?


Why it appears?

Heat

Something which appears at a system boundary during a change of state due to temperature difference between system and surrounding

Heat

Something which appears at a system boundary during a change of state due to temperature difference between system and surrounding

Where it appears?


When it appears?


Why it appears?

Cyclic Process

After a system passes through a series of states and the final state is equal to the initial state

When it happens?


What's noticed at the end?

Adiabatic

Heat prevented from crossing the boundary of a system

Second Law

It's impossible for a system that operates in a cycle to extract heat from a reservoir and do an equivalent amount of work

Heat loss.

Second Law

It's impossible for a system that operates in a cycle to extract heat from a reservoir and do an equivalent amount of work

Heat loss.

Kelvin Planck

Impossible to construct a device that operates in a cycle, receive heat from a single reservoir and do an amount of work

At least how many reservoirs ?

Second Law

It's impossible for a system that operates in a cycle to extract heat from a reservoir and do an equivalent amount of work

Heat loss.

Kelvin Planck

Impossible to construct a device that operates in a cycle, receive heat from a single reservoir and do an amount of work

At least how many reservoirs ?

Second Law, Corollary 1 (Clausius Statement)

Impossible to construct a system that operates in a cycle, transfers heat from a cooler to hotter body without work being done on the system by the surroundings.

Heat from cool to hot reservoir.

Second Law

It's impossible for a system that operates in a cycle to extract heat from a reservoir and do an equivalent amount of work

Heat loss.

Kelvin Planck

Impossible to construct a device that operates in a cycle, receive heat from a single reservoir and do an amount of work

At least how many reservoirs ?

Second Law, Corollary 1 (Clausius Statement)

Impossible to construct a system that operates in a cycle, transfers heat from a cooler to hotter body without work being done on the system by the surroundings.

Heat from cool to hot reservoir.

Second Law Corollary 2

Impossible to construct an engine operating between two reservoirs that would have a higher efficiency than a reversible engine.

Two reservoirs only

Second Law

It's impossible for a system that operates in a cycle to extract heat from a reservoir and do an equivalent amount of work

Heat loss.

Kelvin Planck

Impossible to construct a device that operates in a cycle, receive heat from a single reservoir and do an amount of work

At least how many reservoirs ?

Second Law, Corollary 1 (Clausius Statement)

Impossible to construct a system that operates in a cycle, transfers heat from a cooler to hotter body without work being done on the system by the surroundings.

Heat from cool to hot reservoir.

Second Law Corollary 2

Impossible to construct an engine operating between two reservoirs that would have a higher efficiency than a reversible engine.

Two reservoirs only

Second Law Corollary 3

All reversible engines between the same two reservoirs have the same efficiency

Talks about Two reservoirs.

Second Law Corollary 4

A scale of temperature can be constructed which is not dependent on any thermometric property and provides an absolute zero of temperature.

Second Law Corollary 5

The efficiency of any reversible engine operating between more than two reservoirs must be less than that of a reversible engine operating between only two reservoirs which have the highest and lowest temperature of the fluid in the original reservoir.

Now > 2 reservoirs.

Second Law Corollary 5

The efficiency of any reversible engine operating between more than two reservoirs must be less than that of a reversible engine operating between only two reservoirs which have the highest and lowest temperature of the fluid in the original reservoir.

Now > 2 reservoirs.

Second Law Corollary 6 (Clausius Inequality)

Whenever a system undergoes a cycle


dQ/T = 0 (if reversible)



< 0 (if irreversible)



For heat pump, > 0

Second Law Corollary 7

There exists a property of a closed system such that a change in it's value is dQ/T


for a reversible process between states 1 and 2

Entropy

Second Law Corollary 7

There exists a property of a closed system such that a change in it's value is dQ/T


for a reversible process between states 1 and 2

Entropy

Second Law Corollary 8

Entropy of a closed system thermally isolated from the surroundings either increases if irreversible or remains constant if reversible

Entropy in Adiabatic process

Second Law Corollary 7

There exists a property of a closed system such that a change in it's value is dQ/T


for a reversible process between states 1 and 2

Entropy

Second Law Corollary 8

Entropy of a closed system thermally isolated from the surroundings either increases if irreversible or remains constant if reversible

Entropy in Adiabatic process

Reservoir

Part of surrounding which exchanges energy with system as it is at a different temperature

Second Law Corollary 7

There exists a property of a closed system such that a change in it's value is dQ/T


for a reversible process between states 1 and 2

Entropy

Second Law Corollary 8

Entropy of a closed system thermally isolated from the surroundings either increases if irreversible or remains constant if reversible

Entropy in Adiabatic process

Reservoir

Part of surrounding which exchanges energy with system as it is at a different temperature

Isentropic Process

One which takes place from initiation to completion without change in entropy

There is no change in what ?

Second Law Corollary 7

There exists a property of a closed system such that a change in it's value is dQ/T


for a reversible process between states 1 and 2

Entropy

Second Law Corollary 8

Entropy of a closed system thermally isolated from the surroundings either increases if irreversible or remains constant if reversible

Entropy in Adiabatic process

Reservoir

Part of surrounding which exchanges energy with system as it is at a different temperature

Isentropic Process

One which takes place from initiation to completion without change in entropy

There is no change in what ?

Entropy

It is a property of a closed system such that its value equals dQ/T for any reversible process between state 1 and 2

Thermal equilibrium

Two bodies are said to be in thermal equilibrium when no heat flows between them when they are connected by a path permeable to heat. Obeys Zeroth Law.

Zeroth Law

Specific heat capacity (v)

The heat required to raise a unit mass by 1 degree during a reversible constant volume process

Specific heat capacity (v)

The heat required to raise a unit mass by 1 degree during a reversible constant volume process

Specific heat capacity (p)

The heat required to raise temperature of a unit mass by 1 degree through a reversible constant pressure process

Carnot cycle

An ideal cycle in which heat is taken at a constant upper temperature and rejected at a constant lower temperature. It consists of two reversible isothermal and isentropic processes.