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65 Cards in this Set
- Front
- Back
- 3rd side (hint)
What is an Isothermal process? |
During expansion or compression, quantities of Q and W so proportioned, temperature of fluid remains constant. |
Expansion. Compression. Q and W proportion. |
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What is a path. |
Line joining intermediates states of a process in a reversible process. |
Line. |
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What is a reversible process? |
A process that can be returned to its original state. (Both system and environment) |
Both system and surrounding. |
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First Law Corollary 1 |
There exists a property of a closed system such that a change in its value is sum of net heat and work done during a change of state. |
U = Q + W |
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First Law Corollary 2 |
Internal energy in a closed system remains unchanged if the system is isolated from the surroundings |
Adiabatic |
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First Law Corollary 3 |
Perpetual motion machine of first kind impossible. |
Too easy Bruhhhh. |
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Reversible process (Closed system) |
When there are continuous series of equilibrium states during a process, intermediate states could be located on a diagram, line representing the path could be drawn. |
Path. Cause of lines caused by intermediate equilibrium. |
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Thermodynamic equilibrium |
When no further changes occur when a system is isolated form the surrounding such that no heat and work crosses |
Changes due to heat and work. |
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System |
A region in space containing a quantity of matter whose behavior is being investigated. |
Region in space. Matter. |
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System |
A region in space containing a quantity of matter whose behavior is being investigated. |
Region in space. Matter. |
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Surrounding |
Restricted to portions of matter external to the system which are affected by changes within the system |
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Boundary |
Separates system and surrounding |
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Closed System |
Contains same matter throughout process being investigated. Work and Heat only, cross the boundary. |
It's content. What crosses boundary ? |
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Closed System |
Contains same matter throughout process being investigated. Work and Heat only, cross the boundary. |
It's content. What crosses boundary ? |
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Open system |
Matter, heat and work may cross the boundary while the process is being investigated |
What crosses boundary ? When ? |
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Property |
Required to determine state of a simple Fluid |
What's the importance ? It's the Property of what ? |
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Property |
Required to determine state of a simple Fluid |
What's the importance ? It's the Property of what ? |
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Irreversible process |
Not in equilibrium in intermediate states. |
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First Law |
When a closed system is taken through a cycle, the net work delivered to the surroundings is equal to the net heat intake from the surroundings |
What type of system ? C of E. |
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Zeroth Law |
When two bodies equal in temperature to a third body, they are all equal in temperature. |
Body A, B, C. |
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Thermometric Property |
Observable characteristic in a system and can be used to make comparisons. Like temperature. |
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Work |
Something which appears at the system boundary when a system changes state due to movement of boundary under action of a force |
Where it appears? When it appears? Why it appears? |
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Heat |
Something which appears at a system boundary during a change of state due to temperature difference between system and surrounding |
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Heat |
Something which appears at a system boundary during a change of state due to temperature difference between system and surrounding |
Where it appears? When it appears? Why it appears? |
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Cyclic Process |
After a system passes through a series of states and the final state is equal to the initial state |
When it happens? What's noticed at the end? |
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Adiabatic |
Heat prevented from crossing the boundary of a system |
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Second Law |
It's impossible for a system that operates in a cycle to extract heat from a reservoir and do an equivalent amount of work |
Heat loss. |
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Second Law |
It's impossible for a system that operates in a cycle to extract heat from a reservoir and do an equivalent amount of work |
Heat loss. |
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Kelvin Planck |
Impossible to construct a device that operates in a cycle, receive heat from a single reservoir and do an amount of work |
At least how many reservoirs ? |
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Second Law |
It's impossible for a system that operates in a cycle to extract heat from a reservoir and do an equivalent amount of work |
Heat loss. |
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Kelvin Planck |
Impossible to construct a device that operates in a cycle, receive heat from a single reservoir and do an amount of work |
At least how many reservoirs ? |
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Second Law, Corollary 1 (Clausius Statement) |
Impossible to construct a system that operates in a cycle, transfers heat from a cooler to hotter body without work being done on the system by the surroundings. |
Heat from cool to hot reservoir. |
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Second Law |
It's impossible for a system that operates in a cycle to extract heat from a reservoir and do an equivalent amount of work |
Heat loss. |
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Kelvin Planck |
Impossible to construct a device that operates in a cycle, receive heat from a single reservoir and do an amount of work |
At least how many reservoirs ? |
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Second Law, Corollary 1 (Clausius Statement) |
Impossible to construct a system that operates in a cycle, transfers heat from a cooler to hotter body without work being done on the system by the surroundings. |
Heat from cool to hot reservoir. |
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Second Law Corollary 2 |
Impossible to construct an engine operating between two reservoirs that would have a higher efficiency than a reversible engine. |
Two reservoirs only |
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Second Law |
It's impossible for a system that operates in a cycle to extract heat from a reservoir and do an equivalent amount of work |
Heat loss. |
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Kelvin Planck |
Impossible to construct a device that operates in a cycle, receive heat from a single reservoir and do an amount of work |
At least how many reservoirs ? |
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Second Law, Corollary 1 (Clausius Statement) |
Impossible to construct a system that operates in a cycle, transfers heat from a cooler to hotter body without work being done on the system by the surroundings. |
Heat from cool to hot reservoir. |
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Second Law Corollary 2 |
Impossible to construct an engine operating between two reservoirs that would have a higher efficiency than a reversible engine. |
Two reservoirs only |
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Second Law Corollary 3 |
All reversible engines between the same two reservoirs have the same efficiency |
Talks about Two reservoirs. |
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Second Law Corollary 4 |
A scale of temperature can be constructed which is not dependent on any thermometric property and provides an absolute zero of temperature. |
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Second Law Corollary 5 |
The efficiency of any reversible engine operating between more than two reservoirs must be less than that of a reversible engine operating between only two reservoirs which have the highest and lowest temperature of the fluid in the original reservoir. |
Now > 2 reservoirs. |
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Second Law Corollary 5 |
The efficiency of any reversible engine operating between more than two reservoirs must be less than that of a reversible engine operating between only two reservoirs which have the highest and lowest temperature of the fluid in the original reservoir. |
Now > 2 reservoirs. |
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Second Law Corollary 6 (Clausius Inequality) |
Whenever a system undergoes a cycle dQ/T = 0 (if reversible)
< 0 (if irreversible)
For heat pump, > 0 |
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Second Law Corollary 7 |
There exists a property of a closed system such that a change in it's value is dQ/T for a reversible process between states 1 and 2 |
Entropy |
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Second Law Corollary 7 |
There exists a property of a closed system such that a change in it's value is dQ/T for a reversible process between states 1 and 2 |
Entropy |
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Second Law Corollary 8 |
Entropy of a closed system thermally isolated from the surroundings either increases if irreversible or remains constant if reversible |
Entropy in Adiabatic process |
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Second Law Corollary 7 |
There exists a property of a closed system such that a change in it's value is dQ/T for a reversible process between states 1 and 2 |
Entropy |
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Second Law Corollary 8 |
Entropy of a closed system thermally isolated from the surroundings either increases if irreversible or remains constant if reversible |
Entropy in Adiabatic process |
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Reservoir |
Part of surrounding which exchanges energy with system as it is at a different temperature |
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Second Law Corollary 7 |
There exists a property of a closed system such that a change in it's value is dQ/T for a reversible process between states 1 and 2 |
Entropy |
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Second Law Corollary 8 |
Entropy of a closed system thermally isolated from the surroundings either increases if irreversible or remains constant if reversible |
Entropy in Adiabatic process |
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Reservoir |
Part of surrounding which exchanges energy with system as it is at a different temperature |
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Isentropic Process |
One which takes place from initiation to completion without change in entropy |
There is no change in what ? |
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Second Law Corollary 7 |
There exists a property of a closed system such that a change in it's value is dQ/T for a reversible process between states 1 and 2 |
Entropy |
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Second Law Corollary 8 |
Entropy of a closed system thermally isolated from the surroundings either increases if irreversible or remains constant if reversible |
Entropy in Adiabatic process |
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Reservoir |
Part of surrounding which exchanges energy with system as it is at a different temperature |
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Isentropic Process |
One which takes place from initiation to completion without change in entropy |
There is no change in what ? |
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Entropy |
It is a property of a closed system such that its value equals dQ/T for any reversible process between state 1 and 2 |
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Thermal equilibrium |
Two bodies are said to be in thermal equilibrium when no heat flows between them when they are connected by a path permeable to heat. Obeys Zeroth Law. |
Zeroth Law |
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Specific heat capacity (v) |
The heat required to raise a unit mass by 1 degree during a reversible constant volume process |
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Specific heat capacity (v) |
The heat required to raise a unit mass by 1 degree during a reversible constant volume process |
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Specific heat capacity (p) |
The heat required to raise temperature of a unit mass by 1 degree through a reversible constant pressure process |
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Carnot cycle |
An ideal cycle in which heat is taken at a constant upper temperature and rejected at a constant lower temperature. It consists of two reversible isothermal and isentropic processes. |
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