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20 Cards in this Set

  • Front
  • Back

Rate formuka

Rate= k[A]^x[B]^y

For the rate formula, which portion of the formula is used for it?

Only the reactants

Keq formula for reversible reaction

Kforward/Kreverse

Collision theiry

Rate of reaction is proportional to the number of collisions/second

Exothermic reactions are

Spontaneous


Have -ΔH and -ΔG

Endothermic reactions are

Non-spontaneous


+ΔG and +ΔH

What’re the 4 factors that affect reaction rate?

1.) concentration of reactants


2.) temperature


3.) medium


4.) catalysts

Transition states are located at which part of a graph?

The top of energy barriers

If the Ea of the forward reaction is smaller than the Ea of the reverse, what kind of reaction was it?

Exothermic

Reaction quotient (Q) formula?

Q = prod/react

How do you know of equilibrium hasn’t been reached?

If Qeq


Spontaneous


Proceeds in reverse

If a plan has exceeded equilibrium, how is it indicated?

Q>Keq


Non spontaneous


Proceeds in reverse

Le’Chateliers principle states

A system to which stress is applied shifts to relieve applied stress

Adding reactants or removing products causes

Qeq

Removing reactants or adding products causes

Q>Keq

In other words, Le’Chateliers principle means

The system reacts in the direction away from added species or toward removed species

If change in Peessure occurs, which way will a reaction proceed?

The direction with lower total moles

What does temperature affect and not affect

Changes Keq


Doesn’t change Q

If ΔH is positive, it’s seen as a

Reactant

If ΔH is negatives, it’s viewed as a

Product