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51 Cards in this Set

  • Front
  • Back

Radioisotope

Radioactive isotopes wherein the nucleus of an isotope is unstable, and therefore it decays and emits radiation in the form of gamma rays, alpha particles or beta particles

Gamma Rays

High density photons that are high in kinetic energy and require dense material to stop

Beta Particle

Electron Emitted From Electron Decay, Less Dense and High Energy

Alpha Particle

2 neutrons and 2 protons, dense and easy to stop

Iodine-131

Thyroid absorbs I-131, Iodine emits radiation in the form of gamma rays, a single photon emission computed tomography scanner detects radiation, 3-D maps thyroid showcasing any cancers, tumours or abnormalities

Iodine-125

Used to treat prostate cancer and brain tumours, emits gamma rays.

Cobalt-60 (Co-60)

Common in radiotherapy for cancer treatment

Positron Emission Tomogrpahy

Tissues absorb radioactive isotopes of elements and scanners recreate images and models of them

Gamma Rays, X-Rays, UV

Shorter Wavelength, High Frequency, High Energy

Infrared, Microwaves, Radiowaves,

Long Wavelength, Low Energy, Lower Frequency

Lambda

Wavelength

E

Energy

V (nu)

Frequency of wavelength per unit of time

C

Speed of light (3.00 x 10^8 ms^-1)

Formula for c

Lambda x frequency

When is the relationship between frequency and wavelength

Inversely proportional: High frequency means shorter wavelength

What is the relationship between energy and wavelength

Inversely proportional: High energy, low wavelength

Continuous Spectrum

Seen as white light, includes all the wavelengths on the visible spectrum

Emission Spectrum

Contains all the wavelengths of light that are not absorbed (and are thus emitted) by an atom

Absorption Spectrum

All wavelengths of light that are absorbed by an element

Formula for Energy

E=hv or hc/lambda

What is Planck’s Constant

6.63 x 10^-34 Js

Convergence

As the energy levels increase in energy they get closer together

What’s the limit of convergence

Continuum, beyond this continuum, once electrons pass this continuum, they have too much energy to be affected the gravitational force of the nucleus and can leave the atom as a free electron

Balmer Series (3 to 2)

656nm, red

Balmer Series (4 to 2)

486nm, blue-green

Balmer Series, 5 to 2

434nm, blue

Balmer Series, 6 to 2

410nm, 6 to 2

Paschen Series

The Paschen series is the set of emission lines from atomic hydrogen gas, due to electrons descending from an electron shell of number n greater than 3 down to that of n = 3: Wavelength emitted is infrared

Lyman Series

In physics and chemistry, the Lyman series is a hydrogen spectral series of transitions and resulting ultraviolet emission lines of the hydrogen atom as an electron goes from n ≥ 2 to n = 1: Energy emitted is in the UV spectrum

What is the quantum mechanical model?

A model of the atom that describes the possibility of placing electrons within an atom by describing the principal energy level, energy level, orbital (arbitrary level), and spin of electrons. Derived from the Schrodinger equation.

What is Heisenburg’s Uncertainty Principle

The idea that all substances behave like a wave and a particle, and that the values for certain pairs of physical quantities of a particle, such as position, x, and momentum, p, can not be predicted from initial conditions and will always be uncertain.

Schrodinger Equation

The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system: allows for the prediction of electrons in orbitals.

Energy Levels

In chemistry, the principal energy level of an electron refers to the shell or orbital in which the electron is located relative to the atom's nucleus. This level is denoted by the principal quantum number n.

Atomic Orbitals (Sublevels)

Atomic orbitals, as determined by Schrödinger’s equation, describe the probability of finding a given electron of an atom in a given region of space. Any orbital can hold 2 electrons with complementary spins. They are denoted by the letter L.

The energy of sublevels, suborbitals

S


Magnetic Quantum Number

Specifies the orientation in space of an orbital of a given energy (n) and shape (l). Denoted by +/-

Hund’s Rule

Hund's rule states that: Every orbital in a sublevel is singly occupied before any orbital is doubly occupied.

Pauli’s Exclusion Principle

Pauli's Exclusion Principle states that no two electrons in the same atom can have identical values for all four of their quantum numbers. In other words, (1) no more than two electrons can occupy the same orbital and (2) two electrons in the same orbital must have opposite spins

Aufbau Principle

It states that electrons are filled into atomic orbitals in the increasing order of orbital energy level. According to the Aufbau principle, the available atomic orbitals with the lowest energy levels are occupied before those with higher energy levels.

AMU

1.66 x 10^-24 g

t1/2 of C-14

5730 years

Mass Spectrometer

Apparatus used to find the mass and abundance of isotopes

Group 15 Elements

Pnictogens

Period

A period in the periodic table is a row of chemical elements. All elements in a row have the same number of electron shells, highest occupied energy level and same principle quantum number

Main Group Elements

1-2,13-18

Zeff

Effective Nuclear Charge: net positive charge experienced by valence electrons

Atomic Radius

The atomic radius of a chemical element is a measure of the size of its atom, usually the mean or typical distance from the center of the nucleus to the outermost isolated electron.

Ionization Energy

Ionization Energy is the minimum energy required to remove one mole of the most loosely bound electron of an isolated gaseous atom, positive ion, or molecule.

Electron Affinity

The electron affinity refers to the amount of energy released when a mole of electrons electron attaches to a neutral atom or molecule in the gaseous state to form an anion.

Electronegativity

Electronegativity, symbolized as χ, is the tendency for an atom of a given chemical element to attract shared electrons (or electron density) when forming a chemical bond.