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42 Cards in this Set

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Kinetic-molecular theory

particles of matter are always in motion

Ideal gas

A hypothetical gas that perfectly fits all assumptions of the kinetic-molecular theory


Elastic collision

Collision between gas particles and container walls, and there is no net loss of total kinetic energy

Diffusion

spontaneous mixing of the particles of two substances caused by their random motion

Effusion

A process by which gas particles pass through a tiny opening

Real gas

A gas that does not behave completely according to the assumptions of the kinetic-molecular theory

5 assumptions of kinetic theory

1. Tiny particles are far apart


2. Elastic collision


3. Particles are in continuous motion


4. No attraction between particles


5. Temperature of gas depends on average K.E.

5 properties of gases

1. Expansion


2. Fluidity


3. Low density


4. Compressibility


5. Diffusion and Effusion

Fluid

A substance that can flow and take the shape of its container

Surface tension

Force that pulls parts of a liquids surface tension together, decreasing surface area to the smallest possible size the at

Capillary action

The attraction of the surface of a liquid to the surface of a solid

Vaporization

Liquid or solid changes to a gas

Freezing

Physical change of a liquid to solid by removal of energy as heat

Evaporization

Particles escape from the surface of a non boiling liquid and enter gaseous state

6 properties of liquids

1. Relatively high densities


2. Incompressibility


3. Ability to diffuse


4. Surface tension


5. Evaporation and boiling


6. Formation of solids

Boiling

Change of liquid to bubbles of vapor that appears throughout the liquid

Crystalline solids

Solids that consist of crystals

Amorphous solids

Particles are arranged randomly

Melting

Physical change of a solid to a liquid, by the addition of energy as heat

Melting point

Temperature at which solid becomes a liquid

Supercooled liquids

Substances that retain certain extent liquid properties even at temperature wich they appear to be solid

Crystal structure

The total three-dimensional arrangement of particles of a crystal

Unit cell

Smallest portion of a crystal lattice that shows the three-dimensional pattern of entire lattice

4 properties of solids

1. Definite shape and volume


2. Definite melting point


3. High density and incompressibility


4. Low rate of diffusion

4 properties of crystals solids form

1. Ionic crystals


2. Covalent network crystals


3. Metallic crystals


4. Covalent molecular crystals

2 major types of amorphous solids

1. Glasses


2. Polymers

Phase

Any part of a system that has uniform composition and properties

Condensation

Process by which gas changes to a liquid

Equilibrium

A dynamic condition in which two opposing changes occur eat equal rates in a closed system

Equilibrium vapor pressure

The pressure exerted by vapor in equilibrium with its correct liquid at given temperature

Volatile liquids

Liquids that evaporate readily

Boiling point

The temperature at which the equilibrium vapor pressure equals the atmospheric pressure

Molar enthalpy of vaporization

The amount of energy that is needed to vaporize one mole of liquid at the liquids boiling point at constant pressure

Freezing point

Temperature at which the solid and liquid are at equilibrium at 1atm pressure

Molecular enthalpy of fusion

The amount of energy as heat required to melt one mole of solid at the solids melting point

Sublimation

Change of solid directly to a gas

Deposition

Change of gas directly to a solid

Phase diagram

A graph of temperature vs pressure that conditions under which the phase substance exits

Triple point

Indicates the temperature and pressure conditions at which the solid, liquid and vapor can coexist at equilibrium

Critical point

Indicates the criticical temperature and pressure

Critical temperature

Temperature above which the substance cannot exit in liquid state

Critical pressure

Lowest pressure at which the substance can exit as a liquid at the critical temperature