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10 Cards in this Set
- Front
- Back
- 3rd side (hint)
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Reactions of Carbonyls
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Ketone to secondary alcohol
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NaBH4
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Reactions of Carbonyls
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Aldehyde to primary alcohol
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NaBH4
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Reactions of Carbonyls
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Ketone to tertiary alcohol
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R'--MgBr
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Reactions of Carbonyls
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Aldehyde to secondary alcohol
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R'--MgBr
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Reactions of Carbonyls
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Reactions that form carbonyls
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- oxidation of 1* or 2* alcohols
- ozonolysis of alkenes - warm KMnO4 on alkene (dihydroxylation, then cleavage) - Formation of a diol, HIO4 cleavage |
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Breaking- Open of Epoxides
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H+ MeOH
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add to more sub. position
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Breaking- Open of Epoxides
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NaOMe
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add to less substituted position
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Breaking- Open of Epoxides
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organo-cuperates R2Cu
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Add to less substituted position
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Formation of epoxides
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Br2/ H2O then NaOH
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Formation of epoxides
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RCO3H = peroxide = mcPBA
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