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35 Cards in this Set
- Front
- Back
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Alkene to epoxide |
1) Cl2, H2O 2)NaOH, H2O
Or m-CPBA |
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Alkenes to Alcohols |
1)BH3 2)NaOH (non-mark./syn)
H3O/H2O (mark.)
1)Hg(OAC), H2O 2)NaBH3 (mark.) |
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Alkenes to aldehydes/Ketones |
1)O3 2) (CH3)2S (Cleave) |
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Alkene to alkanes |
H2/Pd, Pt, or Ni (Syn) |
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Alkenes to allylic halides |
NBS (more substituted) |
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Alkene to haloalkane |
H-X (mark.)
HBr, peroxide (non-mark.) |
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Alkenes to ethers |
ROH/Acid (secondary/tertiary rearrangement) |
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Alkene to halohydrin |
X2/H2O (anti) |
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Alkene to vicinal dihaloalkane |
X2 (anti) |
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Alkene to vicinal diol |
1)OSO4 (syn), NaHSO3 (cleave) |
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Alcohol to aldehyde/ketone |
PCC- Primary alcohol to aldehyde
H2CrO4 - Secondary alcohol to ketone
DMP |
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Alcohol to alkene |
H3PO4 |
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Alcohol to silyl ether |
t-BuMe, SiCl/Pyridine |
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Alcohol to haloalkane |
HX or PBr3 or SoCl2 (HX cause rearrangement) |
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Alcohol to carboxylic acid |
H2CrO4 |
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Epoxide to alcohol |
1)LiAlH4 2) H2O |
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Epoxide to vicinal animoalcohol |
NH3 |
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Epoxide or vicinal diol |
H3O/H2O |
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Vicinal diol to aldehyde/ketone |
HIO4 (cleave) |
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Silyl ether to alcohol |
TBAF |
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Alkenes to aldehyde/ketone |
1)(sia)2BH 2)H2O2, NaOH
1)BH3 2)H2O2, HgSO4 |
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Alkyne to alkene |
NaNH3 (trans alkene)
H2/Lindlar catalyst (cis alkene) |
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Alkyne to alkane |
H2/Pd, Pt, or Ni |
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Alkyne to vicinal tetrahaloalkane |
2X2 |
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Alkyne to geminal dihaloalkane |
2HX (mark.) |
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Vicinal dihaloalkane to alkyne |
NaNH3/NH3 |
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Alkane to haloalkane |
X2, Hv or heat (3>2>1) |
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Haloalkane to alkene |
NaC(=_)CR (Me & 1)
C-C bond form |
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Haloalkane to alcohol |
NaOH
H2O/Acid
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Haloalkane to ether |
NaOR (Me& 1)
ROH (2&3: rearranged) |
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Haloalkane to nitrile |
NaCN |
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Haloalkane to thiols (R-S-H) |
NaSH |
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Haloalkane to thioether (R1-S-R2) |
NaSR |
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Haloalkane to amine (HNR2) |
NaHR2 |
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Haloalkane to alkyl azide(R-N3) |
NaN3 |
