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9 Cards in this Set
- Front
- Back
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(alk)oxymercuration/demercuration
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1. Hg(OAc)2, H2O (ROH for alk)
2. NaBH4 |
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hydroboration/oxidation
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1. BH3*THF for ene->ane, Sia2BH*THF for yne->ene
2. H2O2, OH- |
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make radical subst > ionic addition
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NBS, hv (trace Br2)
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Halohydrin
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Br2, H2O
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Syn Hydroxylation
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1. KMnO4
2. OH-, H2O (cold, dilute) OR OsO4, H2O2 |
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ozonolysis
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1. O3
2. (CH3)2S |
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keto/enol
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add to alkYNES
acid catalyzed -> markonikov O on internal C, ketone base catalyzed (hydrB/Ox) -> anti markonikov **Sia2BH to stop addition at alkene O can be on terminal C -> aldehyde keto form |
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alkyne -> trans alkene
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metal/ammonia reduction
Na, NH3 |
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addition of water (only to alkyne??)
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H2O, HgSO4, H2SO4
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