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24 Cards in this Set
- Front
- Back
Durability, or service life, must always be related to what for the useful life of a material? |
The context/ particular site conditions involved. |
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What property of a material determines the reactivity of it to other materials and to some elements of the environment? |
The chemical nature |
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True or False: Small changes in composition canhave a profound influence on the resulting properties |
True, Even trace amounts of some substances, as with metal alloys |
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What is a common influence of ultraviolet radiation onorganic materials? |
Organic molecule has bonds that can be broken and that other changes can be induced through the action of UV radiation. NOTE: This does not happen with metals or cementitious materials. |
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True or False: Gypsum plaster can be unstable at relatively moderate temperature conditions and can undergo decomposition at low relative humidity. |
True |
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What should be considered when determining the physical and mechanical behaviour of a material? |
Consideration must be given tothe grain, crystallite or polymer molecules, the assemblage of these into the many geometricarrangements that occur, the space or porosity around the units, and the nature and extent of the"bonds," which are the forces that hold these building blocks together. Microstructure |
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What are Non-Porous materials? |
Includes polymers, metals and ceramics.They are polycrystalline and characterized by continuous grain boundaries. main characterisitic = placticity |
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What are Porous Materials? |
Most naturally occurring materials and cementitious materials are porous. They contain spaces around crystallites or grains that are interconnected. Important to distinguish spaces that are isolated 'bubbles' vs interconnected. |
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Which material would be considered to have a larger surface area, one with interconnected openings or one with isolated bubbles? |
The one with interconnected openings aka the porous material. |
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What is the most important parameter to consider when determining the microstructure of a material? |
Total Porosity It has a greateffect upon strength but, more important, it providesthe "reservoir" for water which can undergo freezing with corresponding dilation, or a medium fordissolution of constituents for reactions with foreign substances from the atmosphere. |
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True or False: Normal plastercan have a porosity over 50 per cent by volume, and concrete can be equally porous in extreme cases. |
True, |
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What are some environmental factors that interact with a material? |
NOTE: Their significance to the performance of a material lies in the degree of their interaction with the material. Temperature - material responds to actual temperature and its variation inside the material. Moisture - moisture content and its change in the material (cycle from wet to dry or reverse). is influenced by rain, wind, humidity and other factors Solar radiation - UV light deterioration of organic materials, Foreign matter - any substance or agent that comes in direct contact with a given material. (gas, liquid, bacteria, fungus, animal, insect or even another component of the same structure) |
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Why is identification of the environmental processes or factors responsible for failure extremely difficult? |
Because environmental factors act in combinations & go through daily & seasonal cycles,imposing constantly changing conditions, resulting in a complex set of variables that controlsthe successive or simultaneous chemical and physical processes responsible for changes in materials. |
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What is the aging of a material vs curing. |
Aging- slow chemical and physical changes some period after their manufacture. They may involve the completion ofsome of the reactions of forming or the reverse reactions when the material tries to adjust toconditions of storage or service. Curing - to process or promote the hardening of. |
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True or False, Plastics and Sealants do not undergo aging. |
False, Many organic materials such as plastics and sealants undergo aging. Plastic floor tile often shrinks fora period after manufacture; and freshly fired brick or clay tile also may undergo dimensional changesin storage while adjusting to new conditions of moisture content. |
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What is the chemical/physical process characterized by salts being dissolved and moved by free water in the pores of a materialto the surface where the water evaporates, leaving the salts in the form of a stain? |
Efflorescence and Crystallization of Soluble Salts Because of this action ofcrystallizing salts the process has often been linked with frost action, where water in the pores of material crystallizes to ice, also with an expansive force. The best safeguard is to prevent entry ofwater into the material. |
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What chemical/physical process is characterized by the freezing of water in porous materials? |
Frost Action The most important cause of weathering of materials in canada. Occurs only in materials that are frequently frozen when very wet, much effort has been made to establish a criterion for the degree of wetness at which a materialbecomes susceptible to frost action, but no single parameter has been established. |
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What are the characteristics of materials that are generally more susceptible to frost action? |
high porosity and small pores |
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What are some failures that may present in a material affected by wetting and drying movement and/or thermal movement? |
Can result in stresses within the material and can cause cracking as is the case with dryingshrinkage of concrete. Cracks caused by moisture and thermal movements may not always cause failure bythemselves, they often serve as openings through which more rain can enter the structure, making iteasy for other processes of salt crystallization and frost action to take place. |
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What are some common "chemical attack" changes in materials? |
Corrosion of metals Alkali-aggregate reactions in concrete Sulphate attack on concrete Weathering of stone and mortar by the action of rain water acidified by the sulphur gases in the air Photochemical reactions involving ultraviolet light from sunlight and organic materials |
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True or False, If materials are kept dry much of the failures associated with "chemical attack" can be stopped. |
True, For chemical reaction to take place the "ingredients" must come into contact, usually through acommon medium such as water. Reactions usually occur at the surface (in porous materials this includes the internalsurface), so that a highly porous stone is much more subject to attack by sulphur gases than lessporous stone. |
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Temperature is also a contributing factor to chemical attack. At what temperature intervals does the reaction rate double? |
With every10-degree Centigrade rise in temperature |
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What is a Dilating Pressure? |
The pressure produced when a Chemical attack alters the properties of the parent material and produces products that may occupy a larger volume. It is a destructive process similar to frost action, that may initiate cracks in the material. |
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What is the only complete test of performance? |
Trial by Use. Predictionwill always be limited by lack of complete knowledge; trial by use will be limited by time and inabilityto extrapolate to new conditions. Test methods can be used to supplement knowledge and experiencein predicting performance. |