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17 Cards in this Set
- Front
- Back
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Addition of HX
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HX -H, -X Markovnikov N/A Yes
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Addition of HBr with H2O2
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HBR, Peroxide -H, -Br Anti-Markovnikov N/A No
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Acid-Catalyzed Hydration
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H2O, H+ -H, -OH Markovnikov N/A Yes
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Oxymercuration-Demercuration
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1)Hg(OAc)2, H2O
2) NaBH4 -H, -OH Markovnikov N/A No |
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Alkoxymercuration-Demercuration
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1)Hg(OAc)2, ROH
2) NaBH4 -H, -OR Markovnikov N/A No |
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Hydroboration-Oxidation
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1)“BH3”
2) H2O2, -OH -H, -OR Anti-Markovnikov Syn No |
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Hydrogenation
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H2 and Pt, Pd, or Ni -H, -H N/A Syn No
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Simmons-Smith
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CH2I2, Zn -CH2- N/A Retention of stereochemistry No
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α-elimination
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CH2X2 or CHX3 with strong base -CHX- or
-CX2- N/A Retention of stereochemistry No |
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Addition of halogens
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X2, inert solvent -X, -X N/A Anti No
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Halohydrin formation
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X2, H2O -X, -OH -OH to more substituted side Anti No
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Epoxidation
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R-CO3H -O- N/A Retention of stereochemistry No
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Epoxidation+ Ring Opening
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R-CO3H, H+ (aq) -OH, -OH N/A Anti No
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Osmium tetroxide
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OsO4 -OH, -OH N/A Syn No
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KMnO4 (mild)
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KMnO4 (mild) -OH, -OH N/A No
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Ozonolysis
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1)O3
2)Peroxide N/A Splits the bond N/A N/A |
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KMnO4 (vig)
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KMnO4 (vig) N/A Splits the bond Further oxidizes aldehydes To COOH
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