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22 Cards in this Set
- Front
- Back
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Axial or Equatorial for stability on a ring?
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Equatorial
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Carboxypropane
= Propanoic Acid |
3C backbone
functional group: dblbondO,OH on a C |
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Propanoate
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functional group:
Ester R has dblbond 0, OR |
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Propanoyl halide
= Halocarbonyl |
Acyl Halide
R has dblbond O, X |
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Amidopropane
= Propanamide |
R has dbl bond 0, NH2
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Nitrilepropane =?
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Cyanopropane
R has C-trplBnd-N |
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Aldehyde on a group?
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Oxo-
-al backbone has dblbondO, H |
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Ketone?
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Oxo-
-one R has dbl bond 0, R |
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ROH
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alcohol
hydroxy- -ol |
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RSH
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Thiol
sulhydryl- -thiol |
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RNH2
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amino-
-amine |
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R2C=NR'
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amino-
-amine |
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ROR
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Ether
alkoxy- -ether |
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RN3
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azide
azido- |
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RN2+
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diazo-
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hybridization, angles of bond
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single bond: sp3; 109.5
double bonds: sp2; 120 triple bonds: sp; 180 |
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isobutane vs neopentane vs isopropyl vs t-butyl
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DRAW
p335 |
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Phys props:
longer molecule |
heavier-->
higher density, mp and bp |
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Phys Props:
more branch molecule |
Lower density and bp
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Phys Props:
Symmetry |
More symmetric has higher MP
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Free Radical Halogenation
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Br2 + hv(UV light)
react with the most substitued group on a carbon molecule; Cl2 as a free radical usually replaces primary hydrogens |
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pyrolysis
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occurs when molecule broken down- also called cracking
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