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11 Cards in this Set
- Front
- Back
What does this do to a Thiol?
O₂ |
No Conversion of bonds.
Converts Thiol to disulfide 2 RSH become RSSR |
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What does it do to a alkoxide ion?
CH₃Br |
Removes metal (Na, K) and attaches methyl to create ether
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What does it do to an alcohol?
H₂SO₄ ----------> heat |
Combines the two alcohols and creates ether and H₂O
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What does it do to an alkene?
CH₃OH ------------> acid |
Converts alkene to alkane.
Adds R group from alcohol to carbocation |
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What does it do to an epoxide?
1. LiAlH₄ -------------> 2. H₂O |
Breaks epoxide ring leaving OH on more substituted side
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What is the role of Chloro-tert-butyldimethylsilyl (Sylil ether)?
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Reacts with an alcohol to produce tert-butyldimethylsilyl (t-BuMe₂Si) which Protects primary & secondary alcohols, leaving HCl as a by-product
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What does it do to an alkene?
RCO₃H or MCPBA |
Converts alkene to Alkane
Forms Epoxide Alkane has O bonded to both Carbons from double bond (epoxide). RCOOH is byproduct |
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What does it do to an alkene?
1. Cl₂, H₂O -----------------> 2. NaOH, H₂O |
Converts alkene to epoxide
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What does it do to an halohydrin, e.g. OHCH₃HC-CHCH₃Cl?
NaOH, H₂O |
Converts halohrydin to epoxide, removing HCl and binding two central Carbons to Oxygen anti to original halogen
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What does it do to an epoxide?
H⁺ ---> H₂O |
Breaks expoxide ring and leaves OH groups trans on both Carbons in ring (racemic)
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What does it do to an epoxide?
NH₃ |
Breaks expoxide ring and leaves OH & Amino groups trans on both Carbons in ring
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