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24 Cards in this Set
- Front
- Back
- 3rd side (hint)
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Hydrohalogenation -Markovnikov Addition -Racemic Mixture -Susceptible to carbocation rearrangement |
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Acid Catalyzed Hydration -Markovnikov -Racemic -Carbocation Rearrangement |
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Oxymercuration-Demercuration -Markovnikov -No Carbocation Rearrangement |
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Hydroboration Oxidation -Anti-Markovnikov -Syn Addition |
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Catalytic Hydrogenation -Syn Addition |
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Halogenation -Anti Addition |
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Halohydrin Formation -OH group at more substituted position -Anti Addition |
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Anti Dihydroxylation -Epoxide intermediate -MCPBA is a common peroxy acid |
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Syn Dihydroxylation -OsO4 acts as a catalyst when paired with a co-oxidant |
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Ozonolysis |
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Preparation of Alkynes -E2 reaction with a strong base (NaNH2) |
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Hydrohalogenation (Excess) -Markovnikov |
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Hydrohalogenation -Markovnikov |
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Acid-Catalyzed Hydration -Markovnikov -Acid-catalyzed keto-enol tautomerization favors ketone product |
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Hydroboration Oxidation -Anti-Markovnikov -Disiamylborane and 9-BBN are examples of R2BH -Undergoes base-catalyzed tautomerization |
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Halogenation -Anti Addition |
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Ozonolysis -Forms carboxylic acids/carbon dioxide |
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Alkylation |
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Catalytic Hydrogenation |
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Catalytic Hydrogenation (Poisoned Catalyst) -Lindlars Catalyst: Pd prepared with CaCO3 -Syn Addition |
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Dissolving Metal Reduction -Anti Addition |
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Radical Bromimation -Occurs at more substituted position -Racemic |
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Anti-Markovnikov Addition of HBr -Requires trace amounts of alkyl peroxide |
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Allylic Radical Bromimation -Avoids the addition of Br2 across the pi bond -NBS is an alternative source of radical bromine |
