Reading...
Play button
Play button
Use LEFT and RIGHT arrow keys to navigate between flashcards;
Use UP and DOWN arrow keys to flip the card;
H to show hint;
A reads text to speech;
10 Cards in this Set
- Front
- Back
|
Hydroboration/Oxidation
|
Reagents: 1)BH3, THF 2) H2O2, NaOH
syn addition anti-Markovnikov |
|
|
Oximercuration/Reduction
|
Reagents: 1)Hg(OAc)2, H2O 2) NaBH4
anti addition Markovnikov |
|
|
Osmylation
|
Reagents: 1)OsO4, pyridine 2)NaHSO3, H2O
syn addition --> forms cis-1,2-diol |
|
|
Epoxidation/Ring Opening
|
Reagents: 1)RCO3H, CH2Cl2 2) H3O+
forms trans diol |
|
|
Common reagents in reduction of carbonyls
|
NaBH4, LiAlH4
|
|
|
Common reagent in reduction of carboxylic acids and esters
|
LiAlH4 (must use this)
|
|
|
product of the reduction of carboxylic acids and ethers
|
primary alcohol
|
|
|
product of the reduction of an aldehyde
|
primary alcohol
|
|
|
product of the reduction of a ketone
|
secondary alcohol
|
|
|
catalyst in Friedel-Crafts alkylation and acylation
|
AlCl3
|
