Use LEFT and RIGHT arrow keys to navigate between flashcards;
Use UP and DOWN arrow keys to flip the card;
H to show hint;
A reads text to speech;
12 Cards in this Set
- Front
- Back
What type of alcohol is this? |
Primary alcohol |
|
What type of alcohol is this? |
Secondary |
|
What type of alcohol is this? |
Tertiary |
|
What is the pKa of the alcohol shown? |
Cyclohexanol has a pKa of 16 |
|
What is the pKa of the alcohol shown? |
Phenol has a pKa of 10 |
|
What is the pKa of the alcohol shown? |
A phenol with a nitro group in the ortho position has a pKa of 7 |
|
What is the pKa of the alcohol shown? |
A phenol with a nitro group in the meta position it has a pKa of 10. The pKa does not decrease with addition of meta nitro groups. |
|
What is the pKa of the alcohol shown? |
A phenol with a nitro group in the para position it has a pKa of 7 |
|
What is the pKa of the alcohol shown? |
For every nitro group added to a phenol, the pKa decreases by 3 units. This compound has a pKa of around 1 |
|
What is the name of the reaction, the major product, and any other important details? |
1. Acid-Catalyzed Hydration 2. 3. Follows Markovnikov's Orientation, Rearrangements allowed due to carbocation formation, Addition of -OH and -H. |
|
What is the name of the reaction, the major product, and any other important details? |
1. Oxymercuration-Demercuration 2. 3. Follows Markovnikov's Orientation, Rearrangements not allowed due to no carbocation formation, Addition of -OH and -H. |
|
What is the name of the reaction, the major product, and any other important details? |
1. Hydroboration-Oxidation 2. 3. Anti-Markovnikov's Orientation, Syn-Addition (Regioselective), Adds -OH and -H. |
