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35 Cards in this Set

  • Front
  • Back

hydrocarbons

compounds only containing carbon atoms

Name 3 groups of hydrocarbon compounds

alkanes, alkenes, alkynes

Alkanes

single bonds between carbon atoms

Alkenes

contain 1+ carbon-carbon double bond

Alkynes

contain 1+ carbon-carbon triple bond

Systematic name

based on chemical structure

Generic name

internationally accepted name

Trade name

assigned by manufacturing company

Octet Rule

main group elements want to have 8 e- around them - atoms will loose, gain or share to achieve 8

electron deficient elements

elements with les than 8 electrons

expended octets

elements with more than 8 e-

radicals

odd number of e-

formal charge

valence electrons - # of nonbonding electrons - 1/2(# of bonding electrons)

Valence Shell Electron Pair Repulsion theory

electron groups arrange themselves in a way to minimize repulsion

Why do lone pairs take up more space around the central atom?

they cause more repulsion

electron geometry

determined by the number of groups around the central atom

Bond angle of linear electron geometry

180

Bond angle of trigonal planar electron geometry

120

Bond angle of tetrahedral electron geometry

109.5

What happens to the bond angles when the central atom has a lone pair?

The angles around the central atom decrease.

If the difference between the electronegative values of 2 atoms in a bond is </= 0.5 then the bond is...?

polar

If a molecule has a net dipole then it is a ____ molecule

polar

No net dipole means that the molecule is ____

nonpolar

What are the 2 posibilites that make a molecule nonpolar?

Having all nonpolar bonds in a molecule or all the polar bonds cancel out

What are Intermolecular forces?

nonbonding forces that exist between molecules and influence the physical properties of the substance

Name the types of intermolecular forces:

Ion-ion, dipole-dipole, h-bonding, van der Walls

ion-ion

interactions only between cations and anions (metal and nonmetals)

dipole-dipole

interactions between polar covalent molecules

Hydrogen bonding

between molecules that contain N, O, F

van der Waals

all covalent molecules and are only forces that exist between nonpolar molecules

strength of van der Waals interactions depends on:

polarizability & surface area

Polarizability

determined by the size of electron cloud in a molecule (MW)

From weakest to strongest name the IM forces:

van der Waals, dipole-dipole, H-bonding, ion-ion

boiling point

phase change from a liquid to a gas state the IM forces need to be broken

The stronger the force the higher the boiling point, true or false?

true