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13 Cards in this Set

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Know the ten groups

See pic

Homologous series

Group of compounds in which it differs by one methylene group (CH2)

One possible structure

Methane, ethane, and propane

Constitutional isomers

Have same molecular formula but differ in how atoms are connected


Ie: butane is 4 C’s with an iso structural unit

Alkyl groups

Removing a H from an alkane replacing “ane” with “yl “

Alcohol amine and halide

When a H is replaced by an OH: alcohol


When a H is replaced with a NH2: amine


When a H is replaced with a halogen: alkyl halide


When replaced by a OR: ether

2 alkyl 3-C groups

Propyl: when H is removed from primary C of propane


isopropyl: when H is removed from secondary C of propane

4 four-C alkyl groups

Butyl and isobutyl have H removed from primary C


Sec-butyl:H is removed from secondary C


Tert-butyl: H is removed from tertiary C

G

G

Primary secondary tertiary carbons

Primary is bound to one carbon


Secondary is bound to 2 carbons


Tertiary is bound to 3 carbons


Note: a tertiary amine would also be bound to 3 carbons

Favoring hydrophilicity

Presence of ions


Dipole moments


Presence of van der waals: when comparing 2 non polar molecules, liquids larger will be more polar

Lowest boiling point

Choices are:


Ch3Ch2Ch2Ch3


Ch3ch2ch2oh<—answer


(Ch3)choh


Ch3och2ch3

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Pic