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25 Cards in this Set

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alkane + Small base =?

c=c , makes sayszteff product
Alkane + Bulky base =?
c=c makes hoffman product
2,3-bromo-alkane + NaI =?
c=c (takes off Br's)
H2SO4 + heat + alkane w/ alcohol=?
c=c + H3O (takes off H and OH)
H3PO4 + heat+alkane w/ alcohol=?
c=c +H3O (takes off H and OH)
I I
H-X + C=C=?
I I
CH3
I I
-- C-C-CH3
I I
H X (syn)
alkene+ HBr + peroxides
adds H and Br (anti mark)
Dilute H2SO4+H2O+alkene
or
Dilute H3PO4+H2O+alkene
adds H and OH (syn)
Hg(OAc)2 (aq)+NaBH4+alkene
Adds H and OH (anti)
Hg(OAc)2+ROH+alkene
Adds H and OR (anti)
BH3*THF+alkene
--------------->
H2O2, OH-
Adds H and OH (syn)
X2 + Alkene
--------->
CH2Cl2
Adds 2 Br's (anti)
X2 + Alkene
-------->
H2O
Adds X and OH (anti)
H2 + alkene
------>
Pt,Pd,Ni
Adds 2H's (syn)
Peroxyacids + Alkene
Epoxide
Epoxide + H3O
--------->
H2O
Adds 2 OH's (anti)
MCPBA + alkene
------------>
CH2Cl2
Adds 2 OH's (anti)
OsO4 + alkene
---------->
H2O2
Adds 2 OH's (syn)
KMnO4 + alkene
----------->
OH-
Adds 2 OH's (syn)
2H2 + alkyne
-------->
pt,pd,ni
Adds 4 H's C trip C ---> C-C
H2 + alkyne
--------->
lindlars
Ni2B
Adds 2H's (syn) and C tripC ---> C=C
2X2 + alkyne
Adds 4 X's C trip C ----> C-C
H-X + alkyne
Adds H and X CtripC ----> C-C
HgSO4 + alkyne
---------->
H2SO4/H2O
Adds 2 H's and Keytone (R-C)
Hia2BH + alkyne
----------->
H2O2,NaOH
Adds 2 H's and Keytone (c-c)