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11 Cards in this Set
- Front
- Back
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Produce an aldehyde from a terminal alkyne.
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1)Sia2BH-THF
2)H2O2, NaOH |
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Terminal alkyne
1)Sia2BH-THF 2)H2O2, NaOH |
aldehyde
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Terminal alkyne
NaNH2 |
acetylide
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Produce a ketone from a terminal alkyne
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HgSO4/H2SO4
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Terminal alkyne
HX |
Dihalide
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produce a cis alkene
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internal alkyne
H2 Pd/BaSO4, quinoline |
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produce a trans alkene
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NaNH3
internal alkyne |
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produce an alpha diketone
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KMnO4 cold and dilute
internal alkyne |
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Alkyne and neutral KMnO4
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alpha diketone
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Turn an internal alkyne to 2 carboxylic acids
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1)KMnO4 with OH-
2)H+ or 1)O3 2)H2O |
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What is PCC and its use
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Oxidizes primary alcohols to aldehydes and secondary alcohols to ketones
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