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24 Cards in this Set

  • Front
  • Back

2000-2200

Alkynes

5-6

Alkenes

6.5-8.5

Benzene

3300

Alcohol

1700-1500

Carbonyl

10-12

Carboxylic Acid

9-10

Aldehyde

2-5

Ether

Degree of Unsaturation



[2C+2+N-X-H] / 2

ZnCl2/HCl

Lucas Reagent

Lucas Reagent order

3>2>1 almost no 1

Lucas Reagent RXN

ROH+HCl -> RCl+H2O


PPT

CrO3/H2SO4

Jones Reagent

Jones Reagent order

1 and 2 oxidize

Jones Reagent RXN

Color change from orange to blue/green

2,4 DNPH RXN

Acidic addition to 2,4DNPH


PPT + carbonyls - for alcohols

Phenyl isocyanate RXN

Addition to phenyl isocyanate with alcohol


melting points

Haloform or Iodoform RXN

Determine aldehyde or ketone or 2 methyl alcohol.


Pale yellow forms with CH3I

Tollens Reagent RXN

Oxidizes in presence of aldehyde.


Positive for aldehyde with mirror from silver



Permanganate or Baeyer Reagent RXN

Oxidant KMnO4 oxidizes alcohols and aldehydes. Purple to brown + aldehydes + alcohols - ketones

AgNO3 / EtOH RXN

Cloudy ppt if halogens are present

Chlorox CaO/Zn RXN

Yellow orange indicates bromide, violet indicates iodide, clear indicates chloride

NaI/Acetone RXN

SN2 1>2>3 White ppt

TCICA trichloroisocyanuric acid

2>1>3 teritary alcohols


does not react