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20 Cards in this Set
- Front
- Back
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C=C
[HX/ETHER] >> |
Mark addition of X & H
X = Cl, Br, I |
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C=C
[X2/CCl4] >> |
Anti addition of X & X
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C=C
[X2/H2O] >> |
Mark, anti addition of X & OH
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C=C
[Hg(OAc)2, H20/THF // NaBH4 ] >> |
Mark addition of OH & H
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C=C
[BH3/THF H2O2, -OH] >> |
Non-mark, syn addition of OH & H
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C=C + CHCl3 [KOH] >>
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Dichlorocarbene addition
cyclo propane + Cl "ears" |
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C=C + CH2I2
[ZnCu/ETHER] >> |
Cyclopropane formation
syn addition of 1 C |
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C=C
[H2 // Pd/C or PtO2] >> |
Syn addition of H & H
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C=C
[peroxyacid] >> |
Syn addition of 1 O
formation of an epoxide |
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EPOXIDE
[H3O+] >> |
Anti addition of OH & OH
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C=C
[OsO4// NaHSO3, H2O] >> |
Syn addition of OH & OH
lots and lots of O's rxn |
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C=C-C-H
[NBS // CCl4] >> |
C=C-C-Br
replaces allylic H with Br |
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C-OH
[HX // ETHER] >> |
C-X
replaces OH with X 3*/2*/1* |
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H-C-OH
[SOCl2 // PYRIDINE] >> |
H-C-Cl
replaces OH with Cl 1*/2* |
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H-C-OH
[PBr3 // ETHER] >> |
H-C-Br
replaces OH with Br 1*/2* |
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R-X
[Mg // ETHER] >> |
R-Mg-X
Grignard |
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R-X
[2 Li // PENTANE] >> |
R-Li + Li-X
Gilman |
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2 R-Li + CuI
[in ETHER] >> |
(R-Cu-R)-Li + LiI
Gilman |
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R2CuLi + R'X
[in ETHER] >> |
R-R' + RCu + LiX
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R-X
[Mg // ETHER] R-Mg-X [H3O+] >> |
RH + HOMgX
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