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20 Cards in this Set
- Front
- Back
Homogeneous vs. Heterogeneous reactions.
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Heterogeneous reactions involve reactions in two different phases whilst a homogeneous reaction's reactants and products exist in a single phase.
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How does the energy of the activated complex compare with the energies of reactants and products?
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The activated complex has more energy than the reactants and products.
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What are the 5 factors that influence the rate of reaction?
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The nature of the reactants, surface area, temperature, concentration, and the presence of a catalyst.
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Explain the importance of the collision theory in chemical reaction.
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Determines if and in what order a reaction will occur.
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Explain the importance of the rate determining step in chemical reactions.
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It's the slowest step.
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Draw an energy profile with and without a catalyst.
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Catalyzed will have a high hump, uncatalyzed will have second highest hump, and enzyme catalyst will have the lower hump.
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Write the rate reaction and explain each variable.
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R = k[A]^n[B]^m
R = reaction rate k = specific rate constant [A]/[B] = molar concentrations of reactants n/m = respective powers to which the concentrations are raised and represented. |
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What is the reaction mechanism?
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The step-by-step sequence of reactions by which the overall chemical change occurs.
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What are intermediates?
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Species that appear in some steps but not in the net equation.
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What is the collision theory?
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The set of assumptions regarding collisions and reactions.
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What is activation energy?
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The minimum energy required to transform the reactants into an activated complex.
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What is an activated complex?
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A transitional structure that results from an effective collision and that persists while old bonds are breaking and new bonds are forming.
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What is a catalyst?
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A substance that changes the rate of a chemical reactions without itself being permanently consumed.
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What is the action of a catalyst called?
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Catalysis.
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What is a a homogeneous catalyst?
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A catalyst that is in the same phase as all the reactants and products in a reaction system.
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What is a heterogeneous catalyst?
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A catalyst that has different phases than it's reactant's.
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What is the order in a reactant?
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The power to which a reactant concentration is raised.
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What is the rate law of a reaction?
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An equation that relates reaction rate and concentrations of reactants.
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An order of ____ means that the rate does not depend on the concentration of the reactant, as long as some of the reactant is present.
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zero
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