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20 Cards in this Set

  • Front
  • Back
Homogeneous vs. Heterogeneous reactions.
Heterogeneous reactions involve reactions in two different phases whilst a homogeneous reaction's reactants and products exist in a single phase.
How does the energy of the activated complex compare with the energies of reactants and products?
The activated complex has more energy than the reactants and products.
What are the 5 factors that influence the rate of reaction?
The nature of the reactants, surface area, temperature, concentration, and the presence of a catalyst.
Explain the importance of the collision theory in chemical reaction.
Determines if and in what order a reaction will occur.
Explain the importance of the rate determining step in chemical reactions.
It's the slowest step.
Draw an energy profile with and without a catalyst.
Catalyzed will have a high hump, uncatalyzed will have second highest hump, and enzyme catalyst will have the lower hump.
Write the rate reaction and explain each variable.
R = k[A]^n[B]^m

R = reaction rate
k = specific rate constant
[A]/[B] = molar concentrations of reactants
n/m = respective powers to which the concentrations are raised and represented.
What is the reaction mechanism?
The step-by-step sequence of reactions by which the overall chemical change occurs.
What are intermediates?
Species that appear in some steps but not in the net equation.
What is the collision theory?
The set of assumptions regarding collisions and reactions.
What is activation energy?
The minimum energy required to transform the reactants into an activated complex.
What is an activated complex?
A transitional structure that results from an effective collision and that persists while old bonds are breaking and new bonds are forming.
What is a catalyst?
A substance that changes the rate of a chemical reactions without itself being permanently consumed.
What is the action of a catalyst called?
Catalysis.
What is a a homogeneous catalyst?
A catalyst that is in the same phase as all the reactants and products in a reaction system.
What is a heterogeneous catalyst?
A catalyst that has different phases than it's reactant's.
What is the order in a reactant?
The power to which a reactant concentration is raised.
What is the rate law of a reaction?
An equation that relates reaction rate and concentrations of reactants.
An order of ____ means that the rate does not depend on the concentration of the reactant, as long as some of the reactant is present.
zero