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21 Cards in this Set

  • Front
  • Back
Calorimeter
The NRG absorbed/released as heat in a chem. or phys. change is measured by this
Joule
SI unit of heat and all other forms of NRG
Temperature
Measure of the average kinetic NRG of the particles in a sample of matter.
Thermochemistry
Study of transfer of NRG as heat that accompany Chemical and physical changes
Heat
NRG transferred between samples of matter
specific heat
NRG required to raise one gram of substance 1 degree celcius or kelvin
Heat of reaction
quantity of NRG released and or absorbed as heat during a chemical reaction
Thermochemical Equation
Equation including quantity NRG released/absorbed as heat during the reaction as written
enthalpy change
NRG lost/absorbed by system as heat during a process constant pressure
Molar heat of formation
NRG released absorbed as heat when one mole of compound is formed by combination
Heat of combustion
NRG released as heat by complete combustion of one mole of a substance
Hess's Law
The overall enthalpy change in a reaction is equal to the sum of enthalpy changes for the individual steps in the process
Entropy
Measure of the degree of randomness of the particles in a system
Free Energy
Combined enthalpy-entropy function
Free energy Change
At a constant pressure and temperature, Change G of a system is defined as the difference between the change in enthalpy, change H and the product of the Kelving temperature and the entropy change, which is defined as T change S
Reaction mechanism
Step by step sequence of reactions by which the overall chemical change occurs
Intermediates
Species that appear in some steps but not in the net equation.
Homogeneous reaction
reaction whose reactants + products exist in a single phase
Collision Theory
The set of assumptions regarding collisions and reactions
Activation NRG
Minimum energy required to transform the reactants into an activated complex
Activated complex
A transitional structure that results from an effective collision and that persists while old bonds are broken and new bonds are formed