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36 Cards in this Set

  • Front
  • Back

How do you form an aldehyde from a primary alcohol?

Gently heating excess alcohol with a controlled amount of potassium dichromate and sulfuric acid under distillation


Oxidation reaction

How do you produce a carboxylic acid from an acid anhydride?

Room temperature


Hydrolysis using water


Nucleophilic addition elimination

How do you produce an ester from an acid anhydride?

With an alcohol under room temperature


(Nucleophilic addition elimination)

How do you produce Nitrobenzene from benzene?

Low temperature of below 55 degrees


Electrophilic substitution (nitration)


Concentrated nitric acid and concentrated sulfuric acid

How is phenylethanone produced from benzene?

Electrophilic substitution (acylation)


AlCl3 catalyst


CH3COCl

How do you produce a primary alcohol from a halogenoalkane?

NaOH


Nucleophilic substitution


Heat under reflux

How do you produce a tertiary alcohol from a halogenoalkane?

NaOH


Heat under reflux


Nucleophilic substitution

How do you produce a halogenoalkane from an alkane?

Halogen


UV light


Free radical

How do you produce a secondary alcohol from a secondary halogenoalkane?

NaOH


heat under refluc


Nucleophilic substitution

How do you form a carboxylic acid from an acid/acyl chloride?

Water


Nucelophilic addition elimination


Room temperature

How do you produce a ketone from a secondary alcohol?

Oxidation


Heat under reflux


Acidified potassium dichromate

How do you produce a carboxylic acid from an aldehyde?

Vigorous oxidation


Heat under reflux


Excess acidified potassium dichromate

How do you produce an amide from an acid anydride?

Concentrated ammonia


Room temperature


(nucleophilic addition elimination)

How do you produce a dihaloalkane from an alkene?

With a halogen


Electrophilic addition

How do you produce a halogenoalkane from an alkene?

HX


Electrophilic addition

How do you produce an aldehyde from a carboxylic acid?

Reduction


In dry ether


LiAlH4

How do you produce an ammonium salt from a carboxylic acid?

Ammonia solution


Room temperature


Neutralisation

How do your produce a primary amide from an acid/acyl chloride?

Ammonia


Room temperature


Nucleophilic addition elimination

How do you produce an ester from an acid/acyl chloride?

Alcohol


Room temperature


Nucleophilic addition elimination

How do you produce an alcohol from an alkene?

Water


Concentrated sulfuric acid catalyst


300 degrees, 7MPa


Electrophilic addition

How do you produce a hydroxynitrile from an aldehyde or ketone?

KCN, followed by dilute acid


Nucleophilic addition

How do you produce a primary alcohol from a carboxylic acid?

LiAlH4


dry ether


Nucleophilic addition-reduction

How do you produce a primary amine from a nitrile?

Nucleophilic addition- reduction


Dry ether


LiAlH4

How do you produce a primary amine from a primary halogenoalkane?

concentrated NH3


Excess NH3 dissolved in ethanol


Nucleophilic substitution

How do you produce a sodium salt from a carboxylic acid?

NaOH


Room temperature


Neutralisation

How do you produce a nitrile from a primary halogenoalkane?

KCN dissolved in ethanol


Nucleophilic substitution

How do you produce a secondary alcohol from a ketone?

Nucleophilic addition- reduction


NaBH4


Dissolved in water with methanol

How do you produce a primary alcohol from an aldehyde?

Nucleophilic addition- reduction


NaBH4


Dissolved in water with methanol

What is the reaction for Nitrobenzene to Phenylamine?

Sn/HCl


Heat under reflux, add NaOH


Reduction

What is the reaction for a carboxylic acid to an Ester?

Alcohol


Concentrated sulfuric acid catalyst


Nucleophilic addition elimination

What is the reaction for an Ester to a carboxylic acid?

Acid hydrolysis


Dilute HCl , water


Heat under reflux

What is the reaction for an alcohol to an alkene?

Elimination


170 degrees


concentrated sulfuric acid


concentrated phosphoric acid

What is the reaction for a primary halogenoalkane to a secondary amine?

Primary amine


Amine dissolved in ethanol


Nucleophilic substitution

What is the reaction for an Ester to a salt of a carboxylic acid?

Sodium hydroxide solution


Heat under reflux


Base hydrolysis

What is the reaction for a halogenoalkane to an alkene?

KOH dissolved in ethanol


Heat under reflux


Elimination

What is the reaction for an alkene to dibromoalkane?

Br2


25 degrees