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21 Cards in this Set

  • Front
  • Back
Subatomic Particles

What are the 3 major parts and their charges?
Protons=positive charge

Neutrons=no charge

Electrons=negative
Atomic Weights and Isotopes

Atomic Weights?
Carbon-12 atom has a mass of 12.000
Atomic Weights and Isotopes

Isotopes?
Different numbers of neutrons(different mass numbers)
Bohr's Model of the Hydrogen Atom

Quantum Theory?

Planck's Constant?

Frequency?
Quantum theory- energy emitted as electromagnetic radiation from matter comes in discrete bundles called quanta. E=hf

Planck's constant(h)= 6.626x10^-34 js

Frequency=sometimes V
Bohr's Model of the Hydrogen Atom

The Bohr Model?
The centripetal force acting on the electron as it revolved around the nucleus was the electrical force between the positively charged proton and the negatively charged electron.
Bohr's Model of the Hydrogen Atom

The Bohr Model
Angular Momentum?
nh/2pi

n=quantum number
h=Planck's constant
Bohr's Model of the Hydrogen Atom

The Bohr Model
Angular Momentum of Electrons?
E=-RH/n^2

RH=experimentally determined constant, 2.18x10^18j/electrons

n=quantum number
Bohr's Model of the Hydrogen Atom

Applications of the Bohr Model?
Quantized=quantum theory, the energy of an electron is quantized.

Ground State=level, the electron is in its lowest energy state.
Bohr's Model of the Hydrogen Atom

Applications of the Bohr Model
Atomic Emission Spectra?

Balmer Series?

Lyman Series?
Atomic Emission Spectrum=Different distinct energy levels, each one possesses a unique atomic emission spectrum, which can be used as a fingerprint for the element.

Balmer series=The group of hydorgen emission lines corresponding to transitions from upper levels n>2, light in the visible region.(4 wavelengths)

Lyman Series=higher energy transitions, occur in the UV region.
Bohr's Model of the Hydrogen Atom

Applications of the Bohr Model
Atomic Emission Spectra

Planck's emitted photon?
E=hc/wave=-RH[1/(ni)^2-1/(nf)^2]

-RH=2.18x10^18j/electrons
h=Planck's constant
c=light speed
Bohr's Model of the Hydrogen Atom

Atomic Absorption Spectra?

absorption spectrum?
When an electron is excited to a higher energy level, it must absorb energy.

Absorption spectrum=In addition to an emission spectrum, every element possesses a characteristic absorption spectrum.
Quantum Mechanical Model of Atoms

Heisenberg uncertainty principle?
Which states that it is impossible to determine, with perfect accuracy, the momentum and the position of the electron simultaneously.
Quantum Mechanical Model of Atoms

Quantum Numbers?
Pauli Exclusion Principle?
N,L,Ml, and Ms

No Two electrons in a given atom can possess the same set of four quantum numbers.
Quantum Mechanical Model of Atoms
Quantum Numbers

Principal Quantum Number?
The first quantum number,n.

The Higher "n" higher energy and radius.

The maxzimum number of electrons in energy level n is 2n^2.
Quantum Mechanical Model of Atoms
Quantum Numbers

Azimuthal Quantum Number?
2nd quantum number is called azimuthal(angular momentum) quantum number,L.

L=0,1,2, and 3
L=s,p,d, and f

Max that can exist 4L+2

The greater value of L the greater the energy of the sub shell.
Quantum Mechanical Model of Atoms
Quantum Numbers

Magnetic Quantum Number?
3rd quantum number is magnetic quantum number,ML.

ML= L to -L including 0
Quantum Mechanical Model of Atoms
Quantum Numbers

Spin Quantum Number?
4th quantum number is also called the spin quantum number and is denoted by Ms.
Quantum Mechanical Model of Atoms
Electron Configuration and Orbital Filling?
For a given atom or ion, the pattern by which subshells are filled and the number of electrons within each principal level and subshell are designated by an electron configuration.
Quantum Mechanical Model of Atoms
Electron Configuration and Orbital Filling

Hund's rule?
Hund's reule states that within a given subshell, orbitals are filled such that there are a maximum number of half-filled orbitals with parallel spins.
Quantum Mechanical Model of Atoms
Electron Configuration and Orbital Filling

Paramagnetic and Diamagnetic?
Paramagnetic- If the material has unpaired electrons, a magnetic field will align the spins of these electrons and weakly attract the atom.

Diamagnetic- Materials that have no unpaired electrons and are slightly repelled by a magnetic field are said to be diamagnetic.
Quantum Mechanical Model of Atoms

Valence Electrons?
The valence electrons of an atom are those electrons that are in its outer energy shell or that are available for bonding.