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55 Cards in this Set

  • Front
  • Back

Where does the word Ceramic come from?

It comes from “Keramos” which is Greek for pottery.

How were the early forms of ceramics formed?

They were formed by the heat treatment of clay.

What are some early forms of ceramics?

- Kaolinite clay (after firing above 1000 degrees Celsius from porcelain and ceramic)


- Earthenware


- Stoneware


- Bone China

What are some general properties of ceramics?

- inorganic, nonmetallic solid


- low elasticity compared to metals


- low electrical conductivity - used in power transmission


- low heat conductivity - used in power transmissions


- high strength, hardness and melting point


- chemically resistant


- crystallinity varies from crystalline (quartz) to semi crystalline to amorphous (glass)

What are some examples and functions of ceramics?

- oxides (silicon oxide used in glass)


- nitrides (silicon nitride used in bearing surfaces - wear resistant)


- carbides (silicon carbides, grinding disks, angle grinders - very hard material)

What is the structure of crystalline quartz?

The constituent atoms are stacked together in a regular, repeating pattern.

What is glass?

Glass is amorphous and its structure is random.

What are some properties of glass?

- inorganic, nonmetallic solid


- metal, nonmetal or metalloid atoms primarily held in ionic and covalent bonds


- brittle, high melting point, poor conductor, chemically resistant, waterproof


- it is not a crystal - it is amorphous (structure is random)


- it is inherently unstable so will crystallize with time (called vitrification)


- melts at 1713 degrees C - very high


- with heat, it gets no more than 1000 degrees C


What is vitrification?

It means it is unstable but will crystallize with time.

What are some forms of glass?

Oxides, Borides, Polymers, even Metals

What is vitrification?

It means it is unstable but will crystallize with time.

What are some forms of glass?

Oxides, Borides, Polymers, even Metals

What are most common glasses based on?

They are based on 72% wt. silica: SiO2


There is also sodium oxide and calcium oxide.

What is the earliest forms of glass?

Obsidian


- volcanic glass


- didn’t need a fire


- used for spear points or sharp knives

What is the earliest forms of glass?

Obsidian


- volcanic glass


- didn’t need a fire


- used for spear points or sharp knives

What was made by using Nile sediment?

Faience which contains Natron (NaCO3)

What is the earliest forms of glass?

Obsidian


- volcanic glass


- didn’t need a fire


- used for spear points or sharp knives

What was made by using Nile sediment?

Faience which contains Natron (NaCO3)

How did Soda Lime get its name?

Lime was added to sodium silicate and they called it soda lime glass.

What is the earliest forms of glass?

Obsidian


- volcanic glass


- didn’t need a fire


- used for spear points or sharp knives

What was made by using Nile sediment?

Faience which contains Natron (NaCO3)

How did Soda Lime get its name?

Lime was added to sodium silicate and they called it soda lime glass.

What are used to change the color of glass?

Blue - cobalt


Red - metallic gold and metallic copper


Yellow - silver nitrate, uranium


Purple - manganese, nickel


White - tin oxide with antimony or arsenic oxides

What is the earliest forms of glass?

Obsidian


- volcanic glass


- didn’t need a fire


- used for spear points or sharp knives

What was made by using Nile sediment?

Faience which contains Natron (NaCO3)

How did Soda Lime get its name?

Lime was added to sodium silicate and they called it soda lime glass.

What are used to change the color of glass?

Blue - cobalt


Red - metallic gold and metallic copper


Yellow - silver nitrate, uranium


Purple - manganese, nickel


White - tin oxide with antimony or arsenic oxides

What are some additives put in glass?

Na2CO3 (Natron or Soda Ash): network modifier


CaO (lime): network


MnO2: masks the green color from

How is most flat glass manufactured today?

Float glass

What are some additives put in glass?

Na2CO3 (Natron or Soda Ash): network modifier


CaO (lime): network


MnO2: masks the green color from iron


Antimony: makes colorless


PbO (leaded glass): high dispersion crystal


B2O3 (Pyrex): low thermal expansion


Al2O3: fiberglass


ThO2: low dispersion lenses; radioactive so no longer used


La2O3: rare earth glass for cameras and telescopes

What is one of the toughest glass on the market?

Gorilla glass

What is one of the toughest glass on the market?

Gorilla glass

Which glass revolutionized communications?

Fiber optics

What is one of the toughest glass on the market?

Gorilla glass

Which glass revolutionized communications?

Fiber optics

What are the major raw materials for glass?

Sand, limestone, and sodium bicarbonate

What is one of the toughest glass on the market?

Gorilla glass

Which glass revolutionized communications?

Fiber optics

What are the major raw materials for glass?

Sand, limestone, and sodium bicarbonate

What are the pollution problems of glass?

- mirror glass manufacturing generates acidic waste with concentrations of copper or lead


- there is little recycling of flat glass. Most goes to landfills.

What is one of the toughest glass on the market?

Gorilla glass

Which glass revolutionized communications?

Fiber optics

What are the major raw materials for glass?

Sand, limestone, and sodium bicarbonate

What are the pollution problems of glass?

- mirror glass manufacturing generates acidic waste with concentrations of copper or lead


- there is little recycling of flat glass. Most goes to landfills.

What are some uses for waste glass?

Asphalt


Concrete


Construction backfill


Roofing shingles


Ceramic tiles

How can ceramics be formed?

They can be formed by:


- fusion casting which is like metal casting


- slip casting


- sintering


- hot isostatic pressing

How can ceramics be formed?

They can be formed by:


- fusion casting which is like metal casting


- slip casting


- sintering


- hot isostatic pressing

What are the chemical divisions of glass?

- silicates


- nonsilicates

How can ceramics be formed?

They can be formed by:


- fusion casting which is like metal casting


- slip casting


- sintering


- hot isostatic pressing

What are the chemical divisions of glass?

- silicates


- nonsilicates

In glass forming, what do you have to carefully control?

The viscosity of the supercooled liquids.

How can ceramics be formed?

They can be formed by:


- fusion casting which is like metal casting


- slip casting


- sintering


- hot isostatic pressing

What are the chemical divisions of glass?

- silicates


- nonsilicates

In glass forming, what do you have to carefully control?

The viscosity of the supercooled liquids.

What are glass ceramics?

They are another type of crystalline ceramics that are initially formed as glasses and then crystallized in a carefully controlled way. They require an additional step of controlled devitrification to form a fine grained, fully crystalline product.