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28 Cards in this Set

  • Front
  • Back

Phase Transformation Phases

Nucleation and Growth

Nucleation

The appearance of very small particles/nuclei of a new phase which are capable of growing. Similar to like seed crystals.

Growth

Nuclei increase in size resulting in the disappearance of some/all parent phase.

Equilibrium Fraction

The point where transformation stops growth

Types of Nucleation

Homogeneous and heterogeneous

Homogeneous Nucleation

Nucleation occurs uniformally throughout parent phase.

Heterogeneous Nucleation

Nucleation occurring at structural inhomogeneities (container surfaces, impurities, dislocations, grain boundaries)

Gibbs Free Energy

Change in the energy within the system.

Austenite

A solid solution of carbon in a nonmagnetic form of iron, stable at high temperatures. It is a constituent of some forms of steel.

Pearlite

Two phase lamellar structure composed of alternating layers of ferrite and cementing. Harder and stronger than Spheroidite.

Bainite

Very fine and parallel needles of ferrite separated by elongated particles of cementite. Stronger and harder than both Pearlite and Spheroidite

Spheroidite

A ferrite matrix


Weak and soft

Cementite

Spheroidal shaped particles

Coring

When a heated alloy cools in non-equalibrium conditions. The exterior solidifies before the interior. It also causes the centers of the grains to retain more of the higher melting temperature element.

Eutectic Composition solidification

Alloy forms a microstructure consisting of alternating layers of the two phases due to solidification atomic diffusion. Because of this layered configuration the diffusion path length for the atoms is a minimum.

Variables which dictate the microstructure of an alloy

Alloying elements present, the concentrations of these elements, the heat treatment of the alloy.

Superheating and Supercooling

Correspond respectively to heating or cooling above or below a phase transition temperature without the occurrence of the transformation. At the phase transition temperature, the driving force is not sufficient to cause the transformation. The driving force is enhanced during Superheating or supercooling.

Force of the formation of Spheroidite

The net reduction in ferrite-cementite phase boundary area.

Fatigue Striations

Microscopic features on a fatigue fracture surface which identify one propagation cycle of a fatigue crack. Seen through electron microscope. Used to identify fatigue fractures. Can be used to find the number of fatigue cycles.

Benchmarks

Macroscopic fatigue features marking an interruption of some sort in the fatigue cracking progress.

Four measures to increase the fatigue resistance of an alloy

Polish the surface to remove stress amplification sites


Reduce number of internal defects by altering processing and fabrication


Modify design to eliminate notches and sharp contour changes.


Harden the outer surface of the structure by case hardening or shot peening

Four Classifications of Steel, their properties and applications

Low Carbon Steels: Nonresponsive to heat treatments, soft and weak, machine able and well able. Autobodies, structural shapes, pipelines, buildings, bridges, tin cans.



Medium Carbon Steels: Heat Treatable, large combination of mechanical characteristics. Railway wheels and tracks, gears, crankshaft, machine parts.



High Carbon Steels: Hard, Strong, Brittle.


Chisels, hammers, knives, hacksaw blades



High Alloy Steels: Hard and wear resistant: Resistant to corrosion in a large variety of environments. Cutting tools, drills, cutlery, food processing, surgical tools.

reasons to use ferrous alloys

iron ores exist in abudance


Economical extraction, refining and fabrication techniques are available


alloys may be tailored to have a wide range of properties.

disadvantages of ferrous alloys

susceptible to corrosion


relatively high density


relatively low electrical conductivities


purpose of Alloying elements in tool steels

the alloying elements in tool steels combine with the carbon to form very hard and wear resistant carbide compounds.

why is gray iron brittle and weak in tension

the tips of the graphite flakes act as points of stress concentration.

gray vs malleable cast iron composition, microstructure, and mechanical characteristics.

white vs nodular cast iron composition, microstructure, and mechanical characteristics.