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61 Cards in this Set

  • Front
  • Back
Main-Group Elements
Elements whose valence electrons fill an s or p orbital sublevel (Groups 1, 2, 13-18)
Elements found in the earth's atmosphere
oxygen, nitrogen, and hydrogen
Ores
how metals are found naturally in the earth's crust (metal + oxygen)
Metallurgy
process of obtaining a metal from its core. It always involves the reduction of ions to the elemental metal (oxidation number of zero)
Physical characteristics of hydrogen
colorless, odorless, gas
Boiling point of hydrogen
low
Melting Point of Hydrogen
low
Flammability of hydrogen
high (Hindenburg)
Ways to produce hydrogen gas
reaction of methane with water at high temps (and metal catalyst), and eletrolysis of water
Industrial uses of hydrogen
production of ammonia via Haber process and to saturate liquid vegetable oils
Compounds formed with Hydrogen
ionic hydrides (Group 1/2), Covalent Hydrides (nonmentals), metallic hydrides (transition metals)
Possible way to store hydrogen as a fuel
metallic hydrides
Source of Lithium
Silicate Minerals such as spodumene (LiAl(Si2O6))
Method of Preparation of Lithium
Electrolysis of molten LiCl
Source of Sodium
NaCl
Method of Preparation of Sodium
Electrolysis of molten NaCl
Source of Potassium
KCl
Method of Preparation of Potassium
Electrolysis of molten KCl
Two Group 1 elements in the human body
Potassium and Sodium
Source of Rubidium
Impurity in lepidolite, Li2(F,OH)2Al2(SiO3)3
Method of Preparation of Rubidium
Reduction of RbOH with Mg and H2
Source of Cesium
Pollucite (Cs4Al4Si9O26·H2O) and an impurity in lepidolite (Li2(F,OH)2Al2(SiO3)3)
Method of Preparation of Cesium
Reduction of CsOH with Mg an H2
2M + X2 →
2MX; Alkali Metals; X2 = Any halogen molecule
4Li + O2 →
2Li2O; Excess oxygen; Alkali Metals
2Na + O2 →
Na2O2; Alkali Metals
M + O2 →
MO2; M = K, Rb, or Cs; Alkali Metals
2M + S →
M2S; Alkali Metals
6Li + N2 →
2Li3N; Li only; Alkali Metals
12M + P4 →
4M3P; Alkali Metals
2M + H2 →
2MH; Alkali Metals
2M + 2H2O →
2MOH + H2; Alkali Metals
2M + 2H+ →
2M+ + H2; Alkali Metals; Violent reaction!
Group 2 ions essential for human life
Calcium (bones) and Magnesium (Metabolism, Muscle)
Hard Water
Prescence of Ca2+ and Mg2+ ions in water, which interferes with actions of detergents and form precipitates with soap ; pass through limestone
Group 2 Trend in Ionization Energy
Decreasing vertically
Grou two trend in radius
Increasing vertically
Energy of metallurgy redox reaction
Decreasing vertically
Source of Beryllium
Beryl (Be3Al2Si6O18)
Method of Preparation of Beryllium
Electrolysis of molten BeCl2
Source of Magnesium
magnesite (MgCO3), Dolomite (MgCO3·CaCO3), Carnallite (MgCl2·KCl· 6H2O)
Preparation of Magnesium
Electrolysis of molten MgCl2
Kidney stones from this element
Calcium
Source of Calcium
Various minerals containing CaCO3 (like marble and limestone)
Preparation of Calcium
Electrolysis of molten CaCl2
Source of Strontium
Celestite (SrSO4), Strontianite (SrCO3)
Preparation of Strontium
Electrolysis of molten SrCl2
Source of Barium
Baryte (BaSO4), Witherite (BaCO3)
Preparation of Barium
Electrolysis of motlen BaCl2
Source of Radium
Pitchblende (1 g of Ra/7 tons of ore)
Preparation of Radium
Electrolysis of molten RaCl2
Elements from Pitchblende
Radium, Uranium
M + X2 →
MX; Group 2A Elements; X2 = Any halogen molecule
2M + O2 →
2MO; Group 2A Elements; Ba gives BaO2 as well
M + S →
MS; Group 2A Elements
2M + N2 →
M3N2; Group 2A Elements; High temperatures
6M + P4 →
2M3P2; Group 2A Elements; High Temperatures
M + H2 →
MH2; Group 2A Elements; M = Ca, Sr, or Ba; High temperatures; Mg at high pressure
2M + 2H2O →
M(OH)2 + H2; Group 2A Elements; M = Ca, Sr, or Ba
M + 2H+ →
M2+ + H2; Group 2A Elements
Be + 2OH- + 2H2O →
Be(OH)42- + H2; Group 2A Elements