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18 Cards in this Set

  • Front
  • Back

What arethe major classes of fatty acids and lipids?

fatty acids, waxes, fats, and oils

Nonhydrolyzable

Lipidscannot be cleaved into smaller units by aqueous hydrolysis.

Lipidscannot be cleaved into smaller units by aqueous hydrolysis.

waxes

Waxes are esters (RCOOR’) formed from a fatty acid and a high molecular weight alcohol.

Waxes are esters (RCOOR’) formed from a fatty acid and a high molecular weight alcohol.

wax hydrolysis

inthe presence of acid or base to re-form thecarboxylic acid and alcohol theycame from

inthe presence of acid or base to re-form thecarboxylic acid and alcohol theycame from

fatty acids

The naturally occurring fats and oils arearecomposed of long-chain carboxylic acids




A long-chain carboxylic acid; those inanimal fats and vegetable oils often have 12–22 carbon atoms

Triacylglycerols (triglycerides)

are triesters- formed from glycerol and three molecules of- fatty acids.



carboxylic acid triestersof glycerol, a three-carbon trialcohol

Oil

Amixture of triacylglycerolsthat is liquid because it contains a high proportion of unsaturated fattyacids.

Fat

A mixture of triacylglycerolsthat is solid because it contains a high proportion of saturated fatty acids

properties of fats and oils with double bonds

Themore double bonds there are in a triacylglycerol, the harder it is for it tosolidify.

Glycerol

Triacylgylcerol


(ester groups in red)

cis-doublebonds to trans-double bonds not usually found in nature

margerine,shortning,high fat baked goods

saponification

Hydrolysis of fats and oils carried outby strong aqueous bases to form soaps

Hydrolysis of fats and oils carried outby strong aqueous bases to form soaps

Micelle

A spherical cluster formed by theaggregation of soap or detergent molecules so that their hydrophobic ends arein the center and their hydrophilic ends are on the surface

simple lipids

containjust two types of components (fatty acids and alcohols)

complex lipids

containmore than two types components (fatty acids, an alcohol, and other components)

Phospholipid

A lipid that has an ester link betweenphosphoric acid and an alcohol (either glycerol or sphingosine)and another alcohol (usually containing an amine

A lipid that has an ester link betweenphosphoric acid and an alcohol (either glycerol or sphingosine)and another alcohol (usually containing an amine

Glycerophospholipid