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17 Cards in this Set

  • Front
  • Back

Parallel plate capacitor

C= e*eo*A/d, units farad

e

Relative permittivity

eo

Permittivity of space

Charge capacitor

Q=CV

Energy stored in capacitor

E=.5CV^2

Capacitive charging current

Non faradic current, occurs because electrode solution interface behaves like an electrical capacitor Q=CV

C

Capacitance

Q

Charge stored at electrode solution interface

V

Potential difference across interface volts

Solvation shell

Electrostatic interactions cause the formation of a shell of solvent molecules around dissolved ions

Electric double layer

C=e*eo*A/d d is really small therefore C is large. D 1nm or less

Ihp

Oriented solventmolecules and ions that lose solvation shell

Ohp

Solvated ions adsorbed onto electrode surface

Diffuse layer

Solvated ions that don't adsorb into surface

Electrochemical capacitors

Store electricity in separate charges, store charge in the electric double layer that forms at the interface between a metal electrode and electrolyte, capacitance are much higher than conventional capacitors because of smaller D and higher a by using high surface carbon electrodes

Challenge and improve

Increase energy density of ecs

Energy density

E=.5CV^2, max power p=v^2/4R