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17 Cards in this Set

  • Front
  • Back

Equilibrium

Point at which concentration of of all reactants and products stop to change

Reaction rate

Rate at which reactants are converted into products

Activated complex

High energy arrangement of atoms

Concentration of reactants

If one or more reactants are gaseous or in solution , reaction rate can be increased by increasing the concentration of reactants


In cases of gases more pressure can be applied to do so

Surface area

Only surface areas of solids and liquids can be increased to increase rate of reaction

Temperature

Increase in temperature increases rate of reaction


10°C increase will double the rate of reaction

Nature of reactants

Weaker bonds result in increased rate of reaction

Reversible reactions

aA+bB= cC+dD


Rate of forward reaction= rate of reverse reaction

Equilibrium constant

K= [products]/[reactants] raised to the power of the coefficients


Solids and liquids like water are not included



K>1

Forward reaction favored

K< 1

Reverse reaction favored

Le Châtelier's principle

Equilibrium will be re-established and the equilibrium constant will remain the same even after the concentration of either of the reactants or products are increased

Effects of heat on equilibrium

Cause an equilibrium shift and change the value of K

Le Châtelier's principle

If some stress is placed on a reaction at equilibrium, then the equilibrium will shift in the direction that relieves the stress

Effect of pressure

Pressure increase - the side with fewer moles

Effect of catalysts

No effect

Solubility product constant

The smaller the value of Ksp, the more insoluble it is