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36 Cards in this Set

  • Front
  • Back

Catalyst

Speeds up the rate of reaction by lowering the activation energy needed for the reaction


Not consumed

Ozone

Form of oxygen containing three atoms in its molecular structure


Occurs in upper layers of earth's atmosphere


3O2 + electrolysis = 2O3


More reactive than oxygen


Protects harmful UV rays

Cold water reactivity

Very active metal + Water = Hydrogen + Metal hydroxide


K


Ca


Na

Dilute acids

Active metal + Dilute acid = Hydrogen + salt of acid


Al


Zn


Fe


Sn

Preparation of hydrogen

Electrolysis of water


Passing steam over red hot iron or through hot coke


Decomposing natural gas with heat


CH4+H2O= CO+3H2

Properties of hydrogen

Colourless,odourless,tasteless when pure


Slightly soluble in water


Becomes liquid at -240°C and 13 atm


Diffuses more rapidly


0.9g/L at 0°C and 1 atm

Chemical properties of hydrogen

Burns in air or oxygen giving off large amounts of heat


Does not support combustion


Good reducing agent ( withdraws oxygen)


Pressure

Force/Area

Atmospheric pressure

Result of weight of a mixture of gases


Approximately 10N

Normal atmospheric pressure

Sea-level air pressure which can support 760mm column of mercury


Measurement of air pressure

Mercury barometer


Manometer


Top meniscus for mercury


Lower meniscus for water

I atm = ... Hg mm

769 mm Hg


1 atm = ... Torr

760 Torr

1 atm = ...Pa

101,325 Pa

1 atm = ... Kilopascal

101.325 kilopascal

Calculation of pressure

Kinetic molecular theory

Matter is composed of extremely small particles


The space occupied by the gas particles themselves is ingnored in comparison with the whole volume occupied of the container


The particles are in constant motion


When these particles collide with eachother or the walls of the container there is no loss of energy

Temperature

Average kinetic energy

Diffusion

The random motion of gases in moving from one position to another

Effusion

Passing of gas through an oriface into an evacuated chamber.

Effusion

Passing of gas through an oriface into an evacuated chamber.

Graham's law of effusion

The rate of effusion is inversely proportional to the square root of its molecular mass


Rate A/Rate B = √molecular mass of B/ √molecular mass of A

STP

Standard temperature - 273K and 0°C


Standard pressure - 1 atm

Charles law

V1/T1= V2/T2


At constant pressure

Boyle's law

P1V1=P2V2


at constant temperature


Combined gas law

P1V1/T1= P2V2/T2


Gay Lussac's law

P1/T1=P2/T2


At constant volume

Dalton's law of partial pressure

In a mixture of gases , the total pressure = sum of partial pressures


P(total)= P(gas1)+P(gas2)+P(gas3)

Partial pressure

65% of nitrogen,15% of oxygen at 760mm


0.65×760


0.15×760

Ideal gas law

PV=nRT

R

0.0821 L.atm/mol.K

Correction of pressure when level.is higher inside (when mercury)

Outside reading - barometric pressure (height of mercury)


And then correct the partial pressure by subtracting water vapour pressure

Correction of pressure ( in case of water) and is higher inside

Divide the pressure with 13.6 and then subtract from mercury level

Correction of pressure when lower inside

Addition of difference

Ideal gas behaviour

Under conditions of low pressure and high temperature

Partial pressure

Moles of gas/ Total moles in container= partial pressure/ Total pressure