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27 Cards in this Set

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ELEMENT
Cannot be broken down into simpler substances by either physical or chemical means
Can exist as atoms (Na) or as molecules (Nitrogen, N2)
MOLECULE
It is the smallest electrically neutral particle, of an element or compound that can exist on its own.
Example: water (H2O) - compound / oxygen (O2) - element
It is also the name given to the smallest part of those elements which do not exist as atoms in the free state
Example: hydrogen H2, Nitrogen N2, F2, Cl2, Br2
Ionic compounds do not exist as molecules
Ion
An atom or group of atoms which carry an electrical charge
COMPOUND
A substance formed when two or more elements chemically combine together
Have properties that are different from its component elements
Can be broken down into simpler substances by chemical methods.
ISOTOPES
Atoms of the same element having same proton number but different neutron number
Example: 35-Cl and 37-Cl
Empirical Formula
Smallest whole number ratio of atoms in a compound
Molecular Formula
Actual number of atoms in a compound
1) Calculate empirical Formula mass
2) divide molecular mass by empirical formula mass
3) Molecular Formula = (empirical formula)*n
Atomic Mass unit
Mass of a carbon-12 atom divided by 12. This is the standard reference scale to measure mass of atoms and molecules
Relative Atomic Mass
The weighted average mass of an atom of that element divided by the 1/12th the mass of a carbon-12 atom.
Relative molecular mass
The sum of the relative Atomic Masses of all the atoms in the chemical formula
Relative Isotopic Mass
The mass of an atom of that isotope divided by 1/12th the mass of a carbon-12 atom
Mole
Amount of substance which contains the same number of particles (atoms, ions, molecules) as there are carbon atoms in 12g of carbon-12)
Avogardro's Constant
The number of particles in a mole
1 mole = 6.02x10²³ particles (atoms ions or molecules)
Molar mass
Molar mass of a substance is the mass of one mole in grams
Number of moles = mass in grams / molar mass of atoms
Molar volume
Volume occupied by one mole at room temperature and pressure
=24dm³ at rtp
Number of moles = volume of gas / molar volume
Concentration
Measured in moles per cubic decimeter (mol/dm³)
1 litre = 1 dm³ = 1000 cm³
1M [of NaCl]
Means that each dm³ of the solution contains 1 mole (58.5g) [of NaCl]
OR ITS CONCENTRATION IS 1 mol/dm³
Molarity
Concentration in mol/dm³
Molarity = moles of solute / volume of solution
Conversion to g/dm³
Molarity x molar mass of solute
Parts per million
Equivalent to one milligram of something per kg of solvent
Salts
Consist of lattice of positive and negative ions
Salts with water of crystallisation are hydrated salts
Formed by the reaction between an acid and a base
Double Salts
Crystals that contain two different salts (two different anions or cations)

Mixing two different salts and crystallising it would form a double salt
Example: when iron (II) sulfate solution is mixed with ammonium sulfate solution, the salt ammonium iron (II) sulfate is formed
It can also be formed from raw materials using iron, ammonia, and sulfuric acid
Percentage yield
Used to measure the efficiency of a reaction.

Theoretical yield
Mass of product that should be formed
Can be calculated using mass of reactants and chemical equation
Actual yield
Experimental yield - actual mass of product formed
Always less than the theoretical yield. Because
~all the reactants do not undergo complete reaction
~some product is lost during handling
~solution loss during filtration or during transfer between containers
Atom Economy
Also used to measure efficency of reaction.
It is a measure of the proportion of reactant atoms that become a part of the desired products rather than by products
A reaction that has a very high yield could still be very wasteful if a lot of the atoms of the reactants form other products
Atom Economy in addition and substitution reactions
Addition reactions have 100% atom economy since ONLY ONE PRODUCT is formed and NO atoms are WASTED AS BY-PRODUCTS

Substitution reactions have lower atom economy than addition reactions since at least two products will be formed, where only one product is the desired product