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182 Cards in this Set
- Front
- Back
The presence of these results in no path of insertion or draw
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undercut
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What is the proper taper
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6 degrees between opposing walls. Angle of convergence. total over all taper is 12 degrees
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List the 10 steps involved in fabricating all metal crown
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1. prep tooth
2. fabricate provisional restoration 3. impression 4. cast 5. die 6. wax up 7. invest 8. cast 9. clean 10. mount |
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What is the number of times the tooth is duplicated in the process of fabricating a crown
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5 times
6 times if you inclded the provisional 1. impression 2. cast 3. wax up 4. invest 5. cast final |
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This is an cemented extra coronal restoration covering all of the clinical crown
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full crown or complete veeer crown
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This is a restoration where portions of the clinical crown are veneered
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partial veneer
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THis restoration fits with in the anatomic contours of the clinical crown of the tooth.
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Intracoronal cast restorations
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This is a thin layer of dental porcelain or cast ceramic bonded to facal surface with an appropriate resin
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laminate or facial veneer
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This is a prosthetic appliance that is permanently attached to remaining teeth replacing missing teeth
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fixed partial denture
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This is the tooth serving as attachment for FPD
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abutment
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This attaches to the pontic and is an extracoronal restoration cemented to the prepared abutment teeth
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retainer
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What are the different types of rigid connector
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solder joints and cast conectors
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What are the different types of non rigid connectors
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precision attachments stress breakers
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What are the 5 components of a complete diagnosis
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1. Med/dental history
2. TMJ/occlusal evaluation 3. intraoral exam 4. diagnostic casts 5. full mouth radiographs |
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What are 6 health findings that affect dental treatment
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1. Serum hep/HIV: must provide protection for yourself, patients, and staff
2. previous reaction to drug 3. Reaction to dental material: impression materials and nickel containing alloys are bad 4. Cardiovascular problems: hypertension 5. Epilepsy: keep anxiety low 6. Diabetic patients: beware of perio, healing delays 7. Hypoglycemic: may need to eat sugar, make sure pt eats meal 8. Xerostomia: increase in caries; caused by 375 drugs |
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If you evaluate the occlusion of a patient and determine that it is normal
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maintain the occlusion
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If the occlusion is abnormal determine
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if it can be improved prioro to restorations or if restorations can improve it
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During a TMJ evaluation which muscles need to be palpated
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massater
temporalis medial and lateral pterygoid, trapezius, sternomastoid |
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What are the steps for an intraoral exam
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1. oral hygiene
2. attached gingiva: if lacking poor candidate for crown 3. inflammation, pockets, mobility 4. caries, gingival lesions, decalcfied areas 5. examine previous restorations and prostheses 6. evaluate occlusion- facets, interferences, slide |
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What are the reasons and uses of diagnostic casts
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allows view of edentulous spaces/ curvature of arch
length of abutment teeth can be gauged for max retention and resistance further analysis of occlusion occlusal plane discrepancies and super erupted teeth diagnostic wax up |
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What are the reasons and uses of full mouth radiographs
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1. correlate all facts collected prior
2. examine for caries 3. examine for periapical lesions 4. bone levels 5. crown to root ratios 6. widening of the PDL 7. presence of retained root tips |
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Uncontrolled hypertension is defined as
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systolic above 160 and diastolic above 95
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What are the indications and advantages of a complete veneer crown
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1. most retentive of the veneer preparations and resistant
2. Used when less extensive and less destructive designs have been considered and lack in retention, resistance, coverage, or esthetics. 3. When all axial surfaces of posterior teeth are attacked by decay or caries, full metal crowns can strengthen and support a tooth |
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What are the 5 principles that govern the preparation for a CVC
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1. preservation of tooth structure
2. retention and resistance 3. structural durability 4. marginal integrity 5. preservation of peridontium |
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Preservation of tooth structure requires
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limited amount of sound tooth structure removed
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Structural durability must contain..
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bulk of material that can withstand forces of occlusion
must consider the occlusal reduction functional bevel and axial reduction |
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Margins that are smooth and fully exposed of cleansing action ensure
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preservation of periodontium
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are subgingival margins recommended
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no
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This prevents the removal of the restoration along the path of insertion
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retention
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This prevents dislodgment of the restoration by forces directed in apical and oblique direction and prevents movement of the resotration under occlusal forces
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resistance
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What is the essential element of retention?
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two opposing vertical surfaces on the same prep
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limiting the freedom of displacement from torquing or twiting forces in a horizontal plane _____ the resistance of the restoration
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increases
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Longer preps have more ____ and _____.
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surface area and retnetion
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If a prep has shorter walls, they should have ____ taper to increase resistance
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less taper
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What can be placed on a short walled prep on a large tooth
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grooves to decrease rotational radius
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What can be substitued for internal forces
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groove, box form, or pinhole can be substititued for a destroyed wall
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This is the path the restoration will be placed onto or removed. It is considered faciolingually and mesioditally.
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path of insertion
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The MD must _____ the contact area for path of insertion or
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else it will be locked out
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Define margin
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end prep
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Define finish line
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margin of prep, you want an acute angle with nearby pulp)
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define axial wall
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vertical walls of the prep that provide retnetion
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Define functional bevel
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prevents thin or overcontoured crown, provides sufficient bulk and is part of the occlusal reduction
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These are both used to limit the paths of insertion and freedom of displacement. They increase resistance and retention
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box and groove
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Tipping displacement is decreased by _____
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longer walls
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This describes the relationship between two opposing axial walls of a CVC prep
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angle of convergence/divergence
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True or false: the more nearly parallel the less the retention
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false, the greater!
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The average taper surveyed from labs is _____ degrees
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20, this is the maximum tper that can be accepted
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The maximum degree of taper which can be achieved clincially and still afford adequate retention
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16
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As surface area increases, retention ____
As length increases, retention _____ As diameter decreases, retention___ |
increases
increases increases |
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What are the 4 design features of a proper CVC prep
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1. occlusal reduciton
2. funcitonal cusp bevel 3. axial reduction 4. chamfered margin |
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What are the auxiliary retention devices and their indications
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grooves, boxes, pinholes, steps, occlusal shoulder
these increase retention and resistance along with prevent dislodgment |
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An offset ties ____ together while an isthmus ties ___ together
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grooves
boxes |
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the optimum bevel angle is ____degrees
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45
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How much occlusal reduction for the functional cusps and non functional cusps of a CVC
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1.5- functional
1 mm - non funcitonal |
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Crowns must end on ______
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natural tooth structure
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This is optimum condylar position; the condyle is in the most superoanterior position along the articular eminence of the glenoid fossa.
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Centric relation
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This is a physio unstrained position and it often used as a repeatable reference point for mounting on articulators
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centric relaiton
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centered contact position of occlusal surface of maxillary and mandibular teeth
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centric occlusion
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The mandible travels along a path that is guided by anterior teeth contacting and which disoccludes the posterior teeth
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anterior guidance
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condylar inclination linked to anterior guidance is 5-10 degrees _____ because anterior guidance guides the mandible ____
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steeper
down |
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True or false: anterior guidance is linked to vertical and horizontal overlap of anterior and occlusal morphology of posterior teeth
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true
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Anterior teeth, such as the canines guide what movement of teeth?
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lateral excursion and protrusive movement of the mandible
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distance from the fulcrum (condyles) reduces load, thus which teeth have the highest load?
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the molars
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The force load can be reduced by ______
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prprioceptive threshold and reflexes
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If a steep protrusive path exist, then the posterior cusps are
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longer
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A lot of horizontal overlap equals ____ cusps
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shorter
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List the 4 potential interferences in occlusion
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1. centric
2. working 3.non working 4. protrusive |
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this is a premature contact when the mandible close while condyles are in optimum position in the glenoid fossa. The mandible deflects post, ant, and or laterally
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centric
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This is a unwanted contact of maxillary and mandibular posterior teethon the side of movement.
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working
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this is unwanted contact on side opposite of directed movement. It is destructive to masticatory apparatus.
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nonworking
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Why are nonworking side interferences destructive
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mandibular leverage changes
force is outside of the long axis of tooth normal muscular function is disrupted |
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This is premature contact as the mandible moves forward
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protrusive
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why are protrusive interferences destructive
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teeth proximity to muscles
oblique vector force |
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What are examples and indications of pathological occlusion
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trauma
occlusal wear fractured cusps occlusal disharmony local factors |
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List the 5 criteria of a healthy occlusion
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1. condyles superoanteriorly against disc and along the eminence of the glenoid fossa; posterior teeth solidly and evenly contacted/ant teeth with slighter contact
2. occlusal force in long axis of the tooth 3. Working Contacts esp on canines disocclude NW instantly with lateral movement 4. ant teeth contact and disocclude posterior teeth during protrusive excursion 5. post teet contact heavier than anterior when upright in osture |
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Maximum number of teeth contact in all excursive movements . This reduces load on individual teeth by many teeth sharing stress.
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bilateral occlusion
-good for dentures |
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This is group function and eliminates all contact on the non working side.
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unilateral occlusion
-occurs in cases with ant bone loss and absent canines |
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This is canine protected; anterior overlap prevents nonworking and working posterior contact during excursion
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mutually protected occlusion
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The farther anterior a tooth is located, the _____ influence of the TMJ joint, and the ____ of anterior guidance
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less
greater |
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Why is PFM indicated over an all ceramic crown
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PFM is indicated because it is more resistant to fracture
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Why is PFM indicated over a metal FPD
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A pfm provides an esthetic fixed FPD
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What is another name for a PFM
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metal ceramic restoration
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Describe how a PFM is layered
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it consists of a ceramic layer bonded to a thin cast metal coping that fits over the tooth preparation.
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In areas where there will be ceramic coverage, reduction should be
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1.5-2.0 mm occlusally
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when prepping a tooth for a PFM, how far should the radial shoulder extend?
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1.0 mm pst the proximal contact
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What are the three layers of porcelain that are present on a PFM
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Opaque
dentin enamel |
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This type of porcelain conceals the metal underneath. It initiates the development of the shade and plays an important orle in the development of the bond between the ceramic and the metal
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opaque
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This porcelain makes up the bulk of a PFM restoration, providing most of the shade or color
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Dentin or body
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This porcelain imparts translucency to the restoration
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enamel or incisal
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If a PFM is to be prepped on an anterior tooth that has 4 mm of recession what must you consider?
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The optimum location for gingival finish line of a crown prep is on enamel. However in this type of situation the margin must be extended apically. A shoulder is a poor choice and would end in an axial reduction dangerously close to the pulp. You must create a chamfer finish line and the PFM will have a wide metal gingival collar
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Should the contacts of a PFM be in porcelain or metal
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metal if possible, porcelain is abrasive on enamel and gold restorations.
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What are the disadvantages of porcelain occlusal surfaces compared to metal
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abrasve on enamel
fracture more and weaker in strength need a more destructive, deeper crown prep to provide adequate space for porcelain |
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What are the advantages of porcelain over metal
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esthetics
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How far should the porcelain/metal junction be away from contacts
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1 mm
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On a mandibular anterior PFM will the contact be in metal or porcelain
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porcelain no way to avoid it
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True or false: relatively thin porcelain of uniform thickness and supported by rigid metal is strongest for a PFM.
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True
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What should be the minimum thickness of porcelain
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.7 mm, the desirable thickness is 1-1.5 mm
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For adequate strength and rigidity a noble metal coping for a PFM should be at least ___ to ____ thick
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.3 to .5 mm thick
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What are the 4 mechanisms of bonding between ceramic veneer and the metal substructure
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1. mechanical entrapment
2. compressive forces 3. van der waals forces 4. chemical bonding |
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This type of bond between ceramic veneer and the metal substructure is created by interlocking the ceramic with microabrasions in the surface of the metal coping, which are produced by finishing the metal with noncontaminating stones or disks and air abrasion
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mechanical entrapment
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When the coefficient of thermal expansion of a properly designed metal coping is slightly higher than that of porcelain veneered over it this type of bonding mechanism occurs
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compressive forces
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This bonding mechanism is formed by a mutual attraction of charged molecules
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van der waals
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This type of bonding is indicated by the formation of an oxide layer on the metal and by bond strength that is increased by firing in an oxidiing atmosphere.
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chemical bonding
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Why must the facial surface of maxillary anterior tooth prepared for a PFM crown be prepared in 2 planes
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If only one plane is reduced- opaque porcelain may show through, the labial surface may be overcontoured, and the pulp may be encroached upon.
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What is the difference between PFM and all ceramic
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All cereamic crowns contain no metal or gold
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True or false: All ceramic crowns produce the best esthetic effect of all dental restorations but are also the most susceptible to fracture
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true
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What are 3 common errors made in labial reduction
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1. reducing in one plane: the opaque porcelain may show through and the restoration will not be esthetic
2. extension of gingival plane; the labial surface may be over contoured and bulky 3. extension of the incisal plane: the pulp may be encroached upon and the facial surface will be over tapered |
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Name 7 advantages of All ceramic crowns
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1. optical properties (translucency and opaque if you wish to block color)
2. No metal 3. thermal conductivity 4. biocompatibility 5. can be bonded to tooth 6. in office fabrication, no provisional 7. cost |
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Should a patient with bruxism have ceramic crowns
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No
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If you are going to do all ceramic on a molar what type of material should be used
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Zirconia
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What type of material should be used for a all ceramic on a pre molar or an anterior
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E max
(can use z sethetic for anteriors as well) |
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Describe an articulator
|
An articulator is a mechanical device used to hold casts of the patients teeth and stimulate the mandibular movements by replication of the paths of movement of the posterior determinants, the TMJ
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What are the two basic types of articulators
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arcon and non arcon
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An arictulator that is anatomically accurate, condylar elements are attached to the lower member and the mechanical fossae are on the upper. accurate and easy to disassemble
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arcon
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An articulator that has condylar elements on the upper member and the paths simulating the glenoid fossa are on the lower, more popular for dentures
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non arcon
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The facebow is used with any ______ articulator. It transfers the position of the _____ cast in relation to the condyles of the articulator.
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adjustable
maxillary |
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What information does the face bow transfer
|
1. maxillary teeth
2. transverse horizontal axis 3. third reference point from the patients skull |
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What is the limitation of the arbitrary caliper style ear axis facebow
|
It does not capture the exact location of the hinge axis, but 75% of the time the arbitrary hinge axis is within 6 mm of the pt's true hinge axis so it usually sitll works pretty wel unless doing a full mouth reconstruction
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What is the accuracy of the kinematic face bow
|
It pinpoints the exact location of a persons hinge axis,
These are good for full mouth reconstruction |
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An articulator that closely duplicates mandibular movement will allow you to
|
fabricate a more accurate restorations and reduce chair time needed to make adjustments
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Does the size of the articulator have an effect on the restorations accuracy?
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Yes, as the mandible moves up and down the cusp tips move along a sagittal plane with with the cent of rotation at the transverse hinge axis which passes through the condyles. If the location of that axis relative to the cusp tips differes markedly from pt to articulator the radius of the arc of closure may be different and produce errors
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What are the advantages of a semi adjustable articulator
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larger size allows close approximation of distance between axis of rotation and teeth, reproduces the direction and end point of condylar track, and good for most single units and FPDs
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What is the disadvantages of a semi adjustable articulator
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It does not reproduce intermediate track of some condylar movements, intercondylar distances can only be adjusted to s, m l if at all. restorations will require some intraoral adjustment
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What are the capabilities of a fully adjustable articulator
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Reproduces all border movements, intercondylar distance is fully adjustable, highly accurate reproduction of mandibular movements
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Describe centric relation record
|
A record used to replicate on the articulator the relationship between the maxillary and mandibular arches that exists when the condyles are in their most anteriosuperior position in the glenoid fossa (no teeth should be contacting); used for diagnostic casts or restoration of significant portion of the occlusion
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Describe intercuspation record
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used for casts that are to be used for the fabrication of restorations for a small part of the occlusion; done with the bite registration material in a triple tray.
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what influence does anterior guidance have on natural dentition
|
anterior guidance permits the separtion of posterior teeth during lateral excursive and protrusive movements.
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Describe the amount of force on anterior teeth compared to posterior teeth
|
The anterior teeth are farther away from the fulcrum, so the load is less for them than th eposterior teeth. Without anterior guidance, all functional forces will be on the posterior teeth, resulting in excessive forces and potential damge
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Why should anterior guidance be recorded on an articulator
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To take into account the influence of the incisors and canines on the occlusion during excursive movements. Anterior guidance is linked to the combination of vertical and horizontal overlap of the anterior teeth, which affects the morphology of the posterior teeth
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What are the implications of not properly registering anterior guidance on an articulator
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If crowns involving the lingual contours of anterior teeth are to be placed and AG is not registered properly restorations may be made with lingual contours or length that will not provide AG
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If changes in occlusion are anticipate or teeth are going to be lengthened, it is important to make what?
|
a custom incisal guide table
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How do you make a custom incisal guide table
|
1. incisal guide pin is raised at least 1 mm off the incisal guide block
2. moisten guide block, round end of pin, and anterior teeth with vaseline 3. apply resin to the guide block 4. move articulator through all excursive movements repeatedly keeping the anterior teeth touching at all times 5. light cure |
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This is a negative likeness and is made by placing some soft, semi fluid material in the pt's mouth and allowing the material to set.
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Impression
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What is the indirect technique of making a restoration
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fabricating a restoration that is not directly fabricated on the pt's tooth. aka using an impression to produce a cast and then make a crown
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Define hydrophilic impression material
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readily wettable by gypsum
|
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what are examples of hydrophilic impression material
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alginate and polyether
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Define hydrophobic impression
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resistant to wetting
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What are examples of hydrophobic impression materials
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polyvinyl siloxane, condensation-reaction silicones
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A material that exhibits the property of becoming more fluid when the shear rate is increased by deforming or distrubing it (shaking, injecting through a syringe) is said to be
|
thixotropic
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Hydrophillic materials have surfaces that are ____ wettable therefore have _______ contact angles, and thus ____ the probablility of entrapping bubbles during pouring up of the impression.
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more
lower decrease |
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Materials that are hydrophobic are ___ wettable, have ____ contact angles, and _____ the probability of air entrapment during pouring up of the impression
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less
higher increase |
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Materials have _____ viscosity when the shear rate is increased, More thixotropic materials have this property and are therefore used during impression taking
|
lower
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What is the difference between accuracy and precision
|
An accurate, undistorted impresion must be provided to the lab. It must be as nearly an exact duplicate of the prepared tooth. Thus when the crown is made it will precisely fit onto the tooth
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List the characteristics of an acceptable impression
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1. Should be an accurate or exact duplication of the prepared tooth, including all of the preparation and enough uncut tooth surface beyond the preparation to allow the dentist and technician to e certain of the ocation and configuration of the finish line.
2. Other teeth and tissue adjacent to the prepared toth must be accurately reproduced to permit proper articulation of the cast and contouring of the restoration 3. It must be free of bubbles, especially in the area of the finish line an docclusion surfaces of the other teeth in the arch |
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Define contact angle
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ange at which a liquid meets a solid surface. The greater the contact angle the increased likelihood of air entrapment during pouring of an impression
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Define wettability
|
ability of a liquid to maintain contact with a solid surface, resulting from intermolecular interation between the two Surface with better wettability are hydrophilic, surfaces wiht poor wettability are hydrophobic
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Define tear strength
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A test that provides a measure of resistance to tearing
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Why is tear strength important to impression material
|
It is better to have an impression material that has a strong tear strength. This allows it to be removed from the mouth while still getting an accurate impression of the tooth and surrounding tissues instead of small pieces of the impression material tearing off It also allows a more accurate cast to be made.
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What type of tear strength does alginate and polysulfide rubber base have?
|
alignate has a weak tear strength and polysulfide rubber base has a good tear strength
|
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What is dimensional stability
|
ability of a substance to retain its shape when subjected to varying degrees of temperature, moisture, pressure, or other stress.
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Which impression material has the worst dimensional stability
|
Alginate (irreversible hydrocoloid) has the worst dimensional stability because it deforms readily which is why it has to be poured up almost immediately after the impression is taken.
|
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Which impression material has the best dimensional stability
|
polyvinyl siloxane
it can withstand multiple cast pours and be transported from one location to another |
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What impression material has intermediate dimensional stability
|
Polysulfide, but it contracts as it cures, thus to minimize inaccuracy from this an impression should be poured within one hour
|
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What are the least viscous materials used in impressions
|
Light bodied polysulfide and condensation silicone
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What is the most viscous materials used for impressions
|
heavy bodied polysulfide
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What type of viscosity do polyvinyl siloxane and polyether have
|
intermediate
|
|
What is the cheapest impression material
|
Alginate, because it is easily bought and stored in bulk and can be rationed out in exact amounts as needed
|
|
Of the elastomeric materials, which are the most and least expensive?
|
polyvinyl siloxane is the most expensive, it must be dispensed through a cartridge which makes it difficult to ration the amount of material being used.
Polysulfide impressions are the least expensive |
|
What are common problems that require remaking of impressions
|
Presence of blood, saliva, debris, calculus, plaque, soft tissue, tongue and lips can hind getting a good, accurate impression. the impression material is not able to displace these elements and they will be recorded in the impression rendering it inaccurate
|
|
How is an irreversible hydrocolloid mixed, its working time, and setting time?
|
water and powder are combined and hand mixed. working time is less tahn 1 minute. the material takes 2-4 minutes to set depending on the exact type of alginate
|
|
How is polysulfide mixed, its working time, and setting time
|
Acid and base components are mixed on a mixing pad for 30 sec, cannot exceed 1 minute. Syringe is loaded and the material takes 8-10 minutes to set
|
|
How is Condensation silicone mixed, its working time, and its setting time?
|
mix acid and base for 30 sec then roll into a cigar shape and place in tray. Place in patients mouth for 2 minutes
|
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How is Polyvinyl siloxane mixed, its mixing time, and setting time
|
If tube dispensed mix material with spatula for 45 sec until streaks are eliminated then load into syringe. IF using the cartridge system load the cartridge and place a new tip on the gun dispensing the material mixes the acid and base components. It takes 7 minutes for it to set
|
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How is polyether mixed, its mixing time, and setting time
|
mix with spatula for about 1 minute. Load material into a syringe and dispense into the tray. The material will set in 4 minutes
|
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What is the effect of the water/powder ratio on die stone properties
|
the proper ratio is key to getting a good stone pour. Improper ratio can alter properties of the set of the stone such as setting time, porosity, expansion, and strength of the stone Excess water should be removed from impressions before pouring them up
|
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Are die stone models trimmed on a wet or dry model trimmer
|
Dry to ensure excess water does not get into the stone and hinder its ablity to fully set correctly
|
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Discuss how die stone differs from other gypsum products
|
Die stone has a lower water:powder (22-25 per 100 g) and has 2x hardness of gypsum products. Dried dies are 2x strong than wet dies, even with all the extra strength and hardness, the best die stones still abrade with repeated insertion and removal of restorations
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|
List characteristics of an acceptable cast
|
1. bubble free, especially along the finish lines of the preparation
2. All portions of the cast must be distortion free with good reproduction of all necessary oral structures 3. The casts must be trimmed to ensure access for carving wax pattern margins |
|
What is the proper technique for making a pindex master cast
|
1. master cast poured using a vacuum mixed die stone
2. the cast is trimmed and marked for the drilling of pin holes 3. holes are drilled and notched 4. pindex pins are glued into position 5. separator is applied 6. pindex sleeves are positioned over pins 7. the base is poured and the cast is seated into the base 8. dies are separated with a saw 9. the cast is mounted |
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What are the requirements of a provisional restoration
|
1. pulpal protection
2. positional stability 3. occlusal function 4. easily cleaned 5. non impinging margins 6. strength and retention 7. esthetics |
|
How does a provisional provide pulpal protection?
|
the restoration must be fabricated of a material that will prevent the conduction of temperature extremes and the margins should be well adapted well enough to prevent leakage of saliva
|
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How does a provisional restoration give positional stability
|
It prevents the tooth from extruding or drifting away. Any such movement will require adjustments or remake of the final restoration
|
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Why must a provisional provide occlusal function
|
Being able to funciton occlusally on the provisional restoration will aid patient comfort, ward off tooth migraiton, and possibly prevent joint or neuromuscular imbalance
|
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Provisionals are classified by whether they are ____ or _____
|
prefabricate or custom made
|
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What are examples of prefabricated provisionsals
|
stock aluminum, anatomic metal crown forms, celluloid shells, polycarbonate crown forms
|
|
What are examples of custom made crowns
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fabricated of several different kinds of resins by a variety of methods direct or indirect such as polymethyl meth acrylate ,
poly ethyl methacrylate, poly vinylethyl methacrylate bisacryl composite vlc uerthane dimethacrylate. |
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What type of resin is alike
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poly methyl methacrylate
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What is the difference between making a provisional direct or indirect
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Direct is done on actual prepared teeth in the mouth, it is good for novices
Indirect is done outside of the mouth on a cast made of quick set plaster, preferred over direct for accuarcy |
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What are the basic principles of making a provisional
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The outer surface is made a variety of ways that capture the shape of the anatomy of a tooth
The inside of the provisional is made by the prepped tooth |
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What is the overimpession technique?
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Make an alginate overimpression befor eprepping the tooth and fill and smooth defects on the diagnostic cast if there are issueues with anatomy
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When custom provisionals are not possible or desirable, a quick and easy way to produce esthetic provisionals to protect the tooth and keep the patient comfortable is to use
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a prefabricated provisional
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What cements are commonly used for provisional restorations
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zinc oxide with eugenol-temp bond base and accelerator can be mixed with vaseline for weaker temporary bond
zinc oxide w/o eugenol- eugenol inhibits polymerization of resins like methacrylate, allows for the future addition of methacrylate to cured methacrylate |