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33 Cards in this Set

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Dourmad 1999

17-19% of N intake is excreted in faeces...45-50% in urine

Chambers 2000

45 million tonnes of waste deposited directly onto fields by grazing cows, sheep and pigs

DEFRA 2002

In the UK an estimated 10 million tonnes of pig manure, with an N content of 70 kilotonnes is produced annually, a fertiliser value of £2 million

Pig manure

Wania & MacKay 1996

Higher concentrations of HCH found at the Arctic, evidence of transport events

Pretty et al 2000

Annual external cost of ammonia emissions in '96 was £48 million

Ammonia

DEFRA 2002

Largest source of ammonia in Europe is agriculture, with pig farming responsible for ~9% of UK emissions

DEFRA 2009

Agriculture is the source of 2/3 of all N2O produced in the UK

Pretty et al 2000

Nitrate in drinking water had a £16 mill total external cost in the UK (1996)

Nitrate

DEFRA 2009

About 60% of NO3- in English rivers is from agriculture

Rivers

Pretty et al 2000

Annual external cost from n2o is £738 million

N2O

Giesy and Kannan 2001

PFOS global distribution, measured in tissues of wildlife including mammals, fish, and birds...found in urbanised and remote areas. Urban animals higher

Godfrey et al 2010

More than 1 in 7 do not have access to sufficient protein and energy from their diet

Paton & Reid 2009

Using cyclodextrin in bioluminescence assays

Vienna, West Virginia

Contaminated with PCE, SVE and airsparging used. 99% decrease in PCE

Reid et al 2002

Spent mushroom compost and phenanthrene. 7 weeks to be 'trained' to degrade a chemical.


Pre induction not necessary

Malathion

Binds to acetylcholinesterase, prevents control of acetylcholine. Insect metabolism changes P=O bond to P=S, greater reactivity. Mammals remove non polar ester bond so more polar, can be excreted.

Neonicotinoids

Bind to acetylcholine receptors, stimulates nerve firing but acetylcholinesterase can't break down neons.

Galloway and Cowling 2002

Timeline of N 'discoveries' plotted onto human population.


Haber Bosch 1910, success started in 50s.

Watson 1996

mg NO3- vs year in London, see big jump in 70s. Groundwater fed. 4x increase.

Vitousek & Mason 1993

Global N fixation over time. Natural biological fixation and lightning unchanged, legume crops and green manures stayed steady but fossil fuels and fertilisers have increased.

Galloway & Cowling 2002

N cascade, human activities, atmosphere, terrestrial (soil) and aquatic systems all interlinked. Once N is introduced it can have multiple and repeated effects.

N cascade

Brender et al 2013

Birth defects

Blue baby syndrome

Last death 1959, last case 1972


Drove nitrate regulations but set at 4 x higher than conc of fatality.

Bryan et al 2012

Stomach cancer, in theory is possible but in reality only poor quality studies find this. Need to take account of Vit c intake, salt. Nitrate considered essential for cardiovascular health. Normal dietary exposure does not increase stomach cancer risk.

Galloway and Cowling 2002

Vegetarian diet is 14% efficient, meat is 4%

Addiscott et al

Seasonal N utilisation- in UK in winter soil holds enough N to sustain crops (little growth). Only need to apply fertiliser in spring and summer.

Fate of fertilizer nitrate

Soil N was mostly in OM. 2% PRESENT AS NO3-. Of the remainder that was lost, 1/3 leaches and 2/3 denitrifies.

Addiscott et al 1991

Of 1326ktN applied, 1072 is lost.

Seitzinger et al 2006

As N load increases, denitrification increases but it becomes less efficient, making more N2O.

Lancelot 1995

Adding N to the N sea has made it so DF blooms are larger than in normal conditions.

Duce 2008 Galloway 2004

N inputs to the oceans


Rivers 50-80 TgN yr-1


Atm 40-80


N fixation 60-200


Lightning <60

Bianchi 2012

Made the global n budget balance


Previous estimates had more loss of N than input. Bianchi suggests overestimated denitrification due to scaling issues

Stevens et al 2010

Species richness decreases with inc inorganic N deposition.