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19 Cards in this Set

  • Front
  • Back
Arrhenius equation
equation relating reaction rate constant, temperature, and activation energy.
activation energy
minimum energy required for a chemical reaction to take place.
bimolecular
elementary reaction that results from a collision between two reactant molecules.
catalyst
substance that increases the rate of reaction without itself being consumed.
collision theory
bimolecular reactions occur when two properly oriented reactant molecules come together in a sufficiently energetic collision.
Ea
height of the energy barrier between reactants and products.
elementary process
single chemical step in a reaction mechanism.
first order
rate proportional to the concentration of a single reactant raised to the first power.
half-life
amount of time required for the amount of a reactant to decrease to half of its initial amount (concentrations).
rate (law)
equation that tells how reaction rate depends on the concentration of each reactant.
rate constant
proportionality constant in a rate law.
rate-determining step
the slowest step in a reaction mechanism.
rate law
an equation that shows the dependence of the reaction rate on the concentration of each reaction.
reaction mechanism
sequence of elementary steps that defines the pathway from reactants to products.
second order
rate proportional to either the concentration of a single reactant raised to the second power or two different reactants each raised to the first power.
termolecular
elementary reaction that results from collisions between three reactant molecules.
transition state theory
configuration of atoms at the maximum in the potential energy profile for a reaction.
unimolecular
elementary reaction that involves a single reactant molecule.
zero order
rate of change is independent of the concentration of reactant.