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137 Cards in this Set

  • Front
  • Back

The energy that a moving object possesses is known as:

kinetic energy

The type of chemical reaction in which a substance absorbs energy is an:

endothermic reaction

Which model includes the chemical chain reaction to explain the gas phase combustion of fire?

fire tetrahedron

Which type of ignition occurs without any external heat or flame igniting the fuel?

Autoignition

Smoldering charcoal is an example of __________ combustion.

nonflaming

When the air supply to a fire is limited, the level of incomplete combution is higher, which:

produces more smoke

Carbon monoxide acts as a chemical asphyxiant and commonly causes civilian fire fatalities as the products of __________ produced in a structure fire?

combustion

A toxic and flammable by product of combustion that is 35x more toxic than carbon monoxide is:

hydrogen cyanide

In a fire gases will always:

move from areas of higher pressure to areas of lower pressure

Which term describes the mearuse of energy flowing to an area or object?

Heat flux

Two surfaces rubbing together creates friction which generates:

mechanical energey

Which material is least able to conduct heat?

AIR

Which method of heat transfer occurs when energy is transferred by the circulation or movement of a liquid or gas?

Convection

When a fire transmits energy to an object some distance away from it thorugh electromagnetic waves, this is an example of:

radiation

An example of an inorganic fuel is:

plastics

For flaming combustion to occur, fuels must be:

in the gaseous state

In order to burn, liquid fuels must:

vaporize

The temperature at which a piloted ignition of sufficient vapors will begin a sustained combustion reaction is the:

fire point

The term that described the extent to which a fuel substance will mix with water is:

solubility

What is the term used to describe flammable liquids that will mix readily with water?

polar solvents

Pyrolysis occurs when a:

solid fuel is heated suficiently so that it decomposes and gives off combustible vapors

What is the primary consideration when determining how easily solid fuels ignite?

surface to mass ratio of the fuel

Air normally conssts of __________ % oxygen.

21

How would an atmosphere that has a low oxygen concentration of 15% affect combustion of materials?

materials could still ignite and burn at regular temperatures

Which is a true statement about fires in an oxygen-enriched atmosphere?

materials that burn at normal oxygen levels will burn more intensely in an oxygen-enriched atmosphere

What is the concentration limit above which the gas or vapor is said to be too rich to burn?

Upper exlosive (flammable) limit (UEL)

Flaming combustion is one example of a:

chemical chain reaction

What occurs when an extinguishing agent interfere with the chemical chain reaction and stops combustion?

Chemical flame inhibition

When sufficient oxygen is available for flaming combustion, a fire is said to be:

fuel-limited

In a ventilation-limited fire, the heat and growth is limited by the:

amount of oxygen available to the fire

Which stage of fire development occurs when the fire is small and confined to the fuel first ignited?

incipient

At the end of the growth stage, ventilation-limited fires tend to enter an early state of decay because there is no longer enough available __________ for the fire to become fully developed

oxygen

In the incipient stage of fire growth, the:

compartment provides adequate oxygen and development depends on the fuel characteristics

When a fire draws in air from around it, this is known as:

entrainment

The area surrounding a heat source in which there is sufficient air available to feed a fire is the __________ zone.

combustion

The tendency of gases to form into layers according to temperature, gas density, and pressure is thermal:

layering

The apperance of isolated or intermittent flames moving through the hot gas layer in a compartment can indicate that:

flashover is about to occur

The interface between the hot gas layer and cooler layer of air in a compartment fire is known as the:

neutral plane

While a closed compartment reduces the heat release rate of a fire, fuel may continue to pyrolize, which:

creates fuel-rich smoke

In ventilation limited fires any kind of ventilation will:

increase the combustion rate

As flashover occurs, the:

combutible materials and gases in the compartment ignite almost simultaneously

When unburned fire gases that have accumulated at the top of a compartment ignite and flames propagate through the hot gas layer or across the ceiling, this is called:

rollover

In order for a fire to progress to flashover, there must be sufficient heat relase rate and:

ventilation

What is an indicator that flashover is about to occur in a compartment fire?

lowering of the neutral plane

A ventilation limited compartment fire can produce a large volume of flammable smoke and other gases due to:

incomplete combustion

What can lead to backdraft?

Ventilating a space filled with fuel-rich smoke

Anytime a compartment or space contains hot combustion products, firefighters must consider the potential for backdraft before:

creating any opening into the compartment

The fully developed stage occurs when teh heat release rate of teh fire has:

reached its peak

The most effective method of increasing the heat release rate in a fuel limited, fully developed fire is to:

provide more fuel

Adding ventilation points to a compartment fire that is ventilation-limited will:

add-oxygen that will allow the fire to grow

It is __________ to make enough openings in a compartment to transition a fire from ventilation limited to fuel limited conditions

not possible

When a fire runs out of available fuel or oxygen, it is:

in the decay stage

The __________ in a structure fire consists of ambient air flow in and hot gases flowing out the exhaust.

flow path

Which factor affets a flow path's effectiveness to transport ambient air throughout the compartment?

size of ventilation openings

Which statement concerning flow path is true?

when firefighters create openings for ventilation or to make entry, they establish new flow paths

How can wind affect fire development in a structure fire?

It can create pressure differences that cause windows to fail and provide oxygen to the fire

A structure's fuel load is made up of:

all combustible materials inside, including any flammable construction materials

How is fire likely to react and spread within a structure?

a fire burning within hidden cavities in the building can make it more difficult to find and can increase the potential for collapse

Given enough available fuel, fire will follow oxygen through a building along any available __________.

flow path

Which feature of modern construction (homes built after 1990) poses problems for firefighters during extinguishment and ventilation?

Synthetic interior finishes and light wood components

How can lightweight or engineered trusses react under fire conditions?

the trusses can fail without warning, even without flam contact

Inoperative standpipes and sprinkler systems have become a contributing factor in fires in buildings __________.

under demolition, renovation, or construction

Asphyxiation

fatal condition caused by seere oxygen deficiency and an excess of carbon monoxide and/or other gases in the blood

Autoignition

initiation of combustion by heat but without a spark or flame

Autoignition Temperature (AIT)

The lowest temperature at which a combustible material ignites in air without a spark or flame

Backdraft

instantaneous explosion or rapid burning of superheated gases that occurs when oxygen is introduced into an oxygen-depleted confined space. The stalled combustion resumes with explosive force; may occur because of inadequate or improper ventilation procedures

Buoyant

The tendency or capacity of a liquid or gas to remain afloat or rise

Carbon-Based Fuels

Fuels in which the energy of combustion derives principally from carbon; includes materials such as wood, cotton, coal, or petroleum

Carbon Dioxide (CO_2)

Colorless, odorless, heavier than air gas that neither supports combustion nor burns, used in portable fire extinguishers as an extinguishing agent to extinguish Class B or C fires by smothering or displacing the oxygen

Ceiling Jet

Horizontal movement of a layer of hot gases and combustion by products from the center point of the plume, when a horizontal surface such as a ceiling redirects the vertical development of te rising plume

Chemical Flame Inhibition

extinguishment of a fire by interruption of the chemical chain reation

Combustion

a chemical process of oxidation that occurs at a rate fast enough to produce heat and usually light in the form of either a glow or flame

Combustion Zone

Area surrounding a heat source in which there is sufficient air availalbe to feed a fire

Compartmentation

the way that the arrangement of compartments creates or does not create a series of barriers designed to keep flames, smoke, and heat from spreading from one room or floor to another

conduction

physical flow or transfer of heat energy from one body to another, through direct contact or an intervening medium, from the point where the heat is produced to another location, or from a region of high temperature to a region of low temperature

Convection

transfer of heat by the movement of heated fluids or gases, usually in an upward direction

Endothermic Reaction

chemical reaction in which a substance absorbs heat

Energy

Capacity to perform work; occurs when a force is applied to an object over a distance, or when a substance undergoes a chemical, biological, or physical transformation

Entrain

to draw in and transport solid particles or gass by the flow of a fluid

Exothermic Reaction

chemical reaction between two or more materials that changes the materials and produces heat

exposure fire

a fire ignited in fuel packages or buildings that are remote from the initial fuel package or buildings of origin

Fire

A rapid oxidation process, which is a gas-phase chemical reaction resulting in the evolution of light and heat in varying intensities

Fire Point

Temperature at which a liquid fuel produces sufficient vapors to supportcombustion once the fuel ignites and is usually a few degrees above the flash point

Fire Tetrahedron

model of the four elemetns/conditions required to have a fire which represent fuel, heat, oxygen, and self-sustaining chemical chain reation

Fire Triangle

plane geometric model of an equilateral triangle that is used to explain the conditions/elements necessary for combustion the sides represent heat, oxygen, and fuel

Flammable (Explosive) Range

range between the upper flammable limit and lower flammable limit in which a substance can ignite

Flash Point

minimum temperature at which a liquid gives off enough vapors to form an ignitable mixturewith air near the surface of the liquid

Flashover

Rapid transition from the growth stage to the fully developed stage

Flow Path

the space between at least one intake and one exhaust outlet. The differene in pressure determines the direction of the flow of gases through this space. Heat and smoke in a high pressure area will flow toward areas of lower pressure

Free Radical

Electricially charged, highly reactive parts of molecues released during combustion reactions

Fuel

A material tat will mantain combustions under specified environmental conditions

Fuel-limited

Fire with adequate oxygen in which the heat release rate and growth rate are determined by the characteristics of the fuel, such as quantity and geometry

Fuel Load

The total quantity of combustible contents of a building, space, or fire area, including interior finish and trim, expressed in heat units of the equivalent weight in wood

Heat

Form of energy associated with the motion of atoms or molecules within a fuel which is transferred from one body to another as a result of a temperature difference between the bodies, such as from the sun to the earth. To signifiy its intensity, it is measured in degrees of temperature

Heat of Combustion

total amount of thermal energy that could be gnerated by the combustion reaction if a fuel were completely burned. it is typically measured in kilojoules per gram (kJ/g) or megajoules per kilogram (Mj/kg)

Heat Flux

the measure of the rate of heat transfer to or from a surface, typically expressed in kilowatts per square meter (kW/m^2)

Heat Release Rate

Total amount of heat released per unit time and is typically measured in kilowatts (kW) or Megawatts (MW) of output

Hydrocarbon Fuel

petrolum based organic compound that contains only hydrogn and carbon; may also be used to describe those materials in a fuel load which were created using hydrocarbons such as plastics or synthetic fabrics

Hydrogen Cyanide (HCN)

Colorless, toxic, and flammable liquid until it reaches 79 degrees F and (26 degree C) Above that temperature it becomes a gas with a faint odor similar to bitter almonds, produced by the combustion of nitrogen bearing substances

Incomplete Combustion

Result of inefficient combustion of a fuel; the less efficient the combustion, the more products of combustion are produced rather than burned during the combustion process

Isolated Flames

Flames in the hot gas layer that indicate the gas layer is within its flammable range and has begun to ignite; often observed imediately before a flashover

Joule (J)

unit of work or energy in the International System of Units (SI); the energy (or work) when a unit force (1 newton) moves a body thorugh a unit distance (1 meter) ; defined in terms of mechanical energy.



In terms of thermal energy, these refer to teh amount of additional heat needed to raise the temperature of a substance

Kinetic Energy

Energy possessed by a moving objet because of its motion

Lower Exposive (Flammable) Limit (LEL)

lower limit at which a flammable gas or vapor will ignite and support combustion; below this limit the gas or vapor is too lean or thing to burn

Matter

Anything that occupies space and has mass

Miscible

materials tha are capable of being mixed in all proportions

Neutral Plane

Level at a compartment opening where there is an equal difference in pressure exerted by expansion and buoyancy of hot smoke flowing out of the openng and the inward pressure of cooler, ambent temperature air flowing in thorugh the opening

Open Burning

Description of a fire burning in the open with no restrictions to its oxygen supply

Oxidation

chemical process that occurs when a substance combines with an oxidizer such as oxygen in the air; a common example is the formation of rust on metal

Oxidizer

any material that readily yields oxygen or other oxidizing gas, or that readily reacts to promote or initiate combustion of combustible materials

Piloted Ignition

moment when a mixture of fuel and oxygen encounters an external heat (ignition) source with sufficient heat or thermal energy to start the combustion reaction

Polar Solvents

Flammable liquids that have an attraction to water, much like a positive magnetic pole attracts a negative pole; examples include alcohols, esters, ketones, amines, and lacquers

Potential Energy

Stored energy possessed by an object that can be released in the future to perform work once released

Power

Amount of energy deliered oer given period of time

Pressure

Force per unit area exerted by a liquid or gas measured in pounds per square inch (psi) or kilopascals (kPa)

Products of Combustion

Materials produced and released during burning

Pyrolysis

The chemical decomposition of a solid material by heating; precedes combustion of a solid fuel

Radiation

transmission or transfer of heat energy from one body to another body at a lower temperature through intervening space by electromagnetic waves

Reducing Agent

Fuel that is being oxidized or burned during combustion

Rollover

Condition in whichthe unburned fire gases that have accumulated at the top of a compartment ignite and flames propagate thorugh the hot gas layer or across the ceiling

Self-Heating

The result of exothermic reactions, occurring spontaneously in some materials under certain conditions, whereby heat is generated at a ratesufficient to raise the temperature of the material

smoke explosion

form of fire gas ignition; the ignition of ccumulated flammable products of combustion and air that are within their flammable range

Solubility

degree to which a solid, liquid, or gas dissolves in a solvent

Specific Gravity

Mass (weight) of a substance compared to the weight of an equal volume of water at a given temperature



less than 1 indicates a substance lighter than water



greater than 1 indicates a substance heavier than water

Spontaneous Ignition

Initiation of combustion of a material by an internal chemical or biological reaction that has produced sufficient heat to ignite the material

Surface-To-Mass ratio

ratio of the surface area of the fuel to the mass of the fuel

Temperature

Measure of the average kinetic energy of the particles in a sample of matter, expressed in terms of units or degrees designated on a standard scale

Thermal Conductivity

The propensity of a material to conduct heat within its volume. Measured in energy transfer over distance per degree of temperature

Thermal Energy

Kinetic energy associated with the random motions of the molecules of a material or object; often used interchangeably with the terms heat and heat energy

Thermal Equilibrium

The point at which two regions that are in thermal contact no longer transfer heat between them because the yhave reached the same temperature

Thermal Layering

Outcome of combustion in a confined space in which gases tend to form into layers according to temperature, gas density, and pressure with teh hottest gases found at the ceiling and the coolest gases at floor level

Upper Explosive (Flammable) Limit (UEL)

Upper limit at which a flammable gas or vapor will ignite above this limit the gas or vapor is too rich to burn

Vapor Density

Weight of pure vapor or gas compared to the weight of an equal volume of dry air at the same temperature and pressure



less than 1 indicates a vapor lighter than air


greater than 1 indicates a vapor heavier than air

Vapor Pressure

The pressure at which a vapor is in equilibrium with its liquid phase at a given temperature; liquids that have a greater tendency to evaporate have higher vapor pressures at a given temperature

Vaporization

physical process that changes a liquid into a gaseous state; the rate of vaporization depends on the substance involved, heat, pressure, and exposed surface area

Ventilation-Limited

Fire with limited ventilation in which the heat release rate or growht is limited by the amount of oxygen available to the fire

Watt (W)

The SI unit of power or rate of work equal to 1 joule per second (J/s)