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23 Cards in this Set

  • Front
  • Back

Electrochemical cell

Chemical → Electrical energy

Electrolytic cell

Electrical → chemical

Salt Bridge Properties

Salt + Agar Agar → net like structure to decrease the speed of ions


Salt should maintain neutrality


Anion size~ Cation Size


If electrodes are made of Ag, Hg or Tl then K/NH4NO3 is used as salt.

IUPAC notation

Anode|| Cathode

SHE

Standard Hydrogen Electrode


Reference for ECS

ECS

Relation between reactivity and SRP values

SRP increases, Reactivity decreases

Relation between gibb's free energy and emf of cell

G= -nFE

Nernst Equation

pH of Anode ___________ pH of Cathode

>

If [ cathode] > [anode]

Cell will be spontaneous

Metal / Metal Insoluble Reaction for Anode

Metal / Metal Insoluble for cathode

Calomel reactions

Which ion is deposited at the cathode?


Anode?

High SRP


" " SOP

Z =?

Chemical equivalent


E/F

Current efficiency (nu) =

(Actual wt x 100) / theoretical wt

Resistance =

Rho ( l/A)

Cell constant

L/ A

Molar conductivity

Relation between K and /\m

Equivalent conductivity

Relation between /\e and /\m