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597 Cards in this Set
- Front
- Back
fatty acids with one (mono) or two or more double bonds (polyunsaturated )
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mono- and polyunsaturated fatty acids
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Nearly ____ of foods on our grocery shelves have added sweeteners - for sweetness or as preservative
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98%
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Sweeteners elicit pleasurable sensations with ______ or without ______ energy
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nutritive or non-nutritive
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Naturally sweet foods _____ and ____ contain important nutrients to support health
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fruit and breast milk
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_________ are generally recognized as safe (GRAS) by the Food and Drug Administration ; yet concern exists about increasing sweetener use relative to optimal nutrition and health
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Nutritive sweeteners ( ex: sucrose and fructose)
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Dietary quality suffers at intake above _____ of total daily energy
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25%
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Sweet taste is stimulated by a wide variety of compounds include ____, ____, and _____
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sugars, sugar alcohols, dipeptides
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True or false: The various mono- and disaccharides are the most common natural sweeteners used in foods, however, non-carbohydrate compounds such as saccharin and aspartame are also incorportaed into manufactured foods
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true
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Sweeteners are valuable in foods because of the physical and functional properties including what 7 characteristics?
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1. sweetness
2. hygroscopicity 3. solubility 4. hydrolysis 5. degradation 6. caramelization 7. maillard reaction |
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The properties of foods and beverages affect sweetening power including _____, ______, and ________
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physcial state, temperature, and the presence of other flavors
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When dissolved, all sugars are sweet to the tongue, but some are sweeter than others;
The ability of sugar to sweeten a food product is of interest because ________________. |
sugars contribute to the total kcal content of foods at 4 kcal/g.
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sugar that is very sweet can be used in smaller quantities than the less sweet type minimizing total kcal without sacrificing sweetness; The relative sweetness of sugar is affected by ______________________
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the temperature of the solution is of the solution it is dissolved
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FRuctose is the sweetest sugar and is 1.4 times sweeter than sucrose at 5 ' C but 0.8 times as sweet at 40 ' C; is an example of what affect on sugar?
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temperature affecting the relative sweetness of sugar
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_________ provide more sweetening power by weight compared to any of the natural sugars - relative sweetness of sugar solutions at 5% and other sweeteners
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non-sugar sweeteners
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________ refers to the ability of sugar to attract and hold water
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hygroscopicity - sugar have a great affinity for and hold water
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_______ of sugar is helpful in maintaining the freshness of baked products and can also be a potential textural problem at a very high humidity
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hygroscopicity
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Increased temperature increases the ability of sugars to __________________
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absorb moisture from the environment
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_______ refers to sugars ability to go into solution in a specific volume of liquid at standard temperature
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solubility
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______ of sugar is affected by the type of sugar
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solubility
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______ is the most soluble of all sugars and lactose (milk sugar) is the least soluble
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fructose
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Explain the effect of temperature on the solubility of sugar
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more sugar is dissolved in a known volume of liquid at increased temperature compared to lower temperature
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_____ is important in the textural property of foods
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solubility
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____ is smooth because of the high levels of fructose
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candy
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_____ creating gritty texture in ice cream
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lactose
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_____ is the splitting of sugar molecules into its monosaccharides - a common occurrence in sugar
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hydrolysis
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Disaccharides undergo hydrolysis when _______ - an acidic medium favors hydrolysis reaction, so also water
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heated
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Hydrolysis of sucrose (fructose + glucose) result in _________
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invert sugar (inversion)
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______ is formed by hydrolysis of sucrose; creating a mixture of equal amounts of fructose and glucose
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invert sugar
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______ is the opening of sugar structural ring ; it is a prelude to sugars breaking down to the smaller molecules
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degradation
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_____ is the first step in heat destruction of sugars in cookery
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degradation
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A chemical reaction that occurs in both acid and alkaline mediums
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degradation
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In the presence of acid ______ of the molecule occurs as 3 molecules of water are eliminated, resulting in the formation of organic acid and aldehyde substances
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dehydration
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____ is the process of heating dry sugar or sugar solution (with most of its water evaporated) until it melts into a clear, viscous liquid and , as heating continues, it turns into a smooth, brown mixture
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caramelization
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Caramelization is initiated by __________
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sugar inversion
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Caramelization is initated by sugar inversion, then _____ occurs creating polymers ranging from tri to oligosaccharides , then ______ reactions promote the formation of organic acids and cyclic compounds
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condensation occurs , dehydration reactions
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______ promotes pleasing flavor changes ; the color change ranges from pale golden brown to deepening brown
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caramelization
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______ is a non-enzymatic browning resulting from condensation of reducing sugars and amines group of the amino acid when heat is applied or during an extensive storage
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maillard reaction
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__,____,____ are reducing monosaccharides and _____ , ____ are reducing disaccharides, however, sucrose being non-reducing sugar does not undergo maillard reaction
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glucose, fructose, galactose
lactose and maltose |
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What are the 9 functional properties of sugars in foods?
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1. taste (sweet)
2. preservation 3. flavor 4. color 5. texture 6. tenderness 7. volume 8. fermentation 9. stability of foam |
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______ approxiamtely 98% of packaged foods have sugar added to improve this
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sweet taste
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high concentrations of sugar can act as a ______ by inhibiting the growth of microorganisms
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preservation
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application of heat results in sugar degradation contributing to the unique taste of products such as candy is known as _______
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flavor - functional property of sugar
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for Color: subjecting sugar to varying level of heat develops appealing color as a result of ______ and __________
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caramelization and maillard reaction
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the texture of many processed or prepared foods relies on ______, espeically _________
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sweeteners , sucrose
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when shortening the gluten power, ______ is created
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tender products
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Cakes become more tender as ______________
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sugar content is increased until a critical maximum is reached
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____ serves as food for yeast
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sugars
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_____ is increased with increased sugar content if the sugar content is too high
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volume
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many alcoholic beverages and a few other foods around the world rely on the _________
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fermentaiton of carbohydrates
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egg foam is stabilized with the ________
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addition of sugar
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Addition of _____ to egg white causes the foam to have smaller cell size and a fine texture
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sugar
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In starch thickened puddings, sugar serves as a ___________ ingredient
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tenderizing
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Sugar delays the __________ in protein containing products
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protein
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What are the 4 applications of sweeteners in food?
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1. Crystalline candies
2. amorphous candies 3. syrups, sauces, jams and jellies 4. baked products |
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__________ are candies that are easy to bite with large area of organized sugar crystals
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crystalline candies
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_______ lack organized structure because of the high sugar concentration and the interfering substance
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amorphous candies
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The physical characteristics of candy is determined by the ________ and _______
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concentration of sugar and the presence of interfering substances
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At ________ , mixture boil at about 112' C resulting in crystalline candies
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lower sugar concentrations
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________ boil to as high as 142' C yielding amorphous products
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high sugar concentration
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In syrups and sauces sugars provide sweetness and increase the ________
Sauces for desserts utilize sugar as a sweetener |
viscosity
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_____ is essential for the sweet taste in most jams and jellies, and equally vital is sugar's role in preserving fruit
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sugar
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Sugars also serve to prevent ______ - the high concentration of sugar dehydrates microorganisms ; creating unflavor osmotic pressure for microbe to grow
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microbial growth
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In all baked products, sugar __________ of flour
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"shortening the gluten power"
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_____ serves as food for yeast in leavened breads
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sugar
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Sucrose is split and inverted by yeast _______ to provide glucose and fructose for fermentation ; Fermentation produces Co2 that leavens the dough
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invertase
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The pleasing evenly brown crust color of bread is a function of _______________; using glucose (dextrose) or corn syrup produces bread with light and somewhat reddish brown color
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sucrose and high fructose corn syrup
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High levels of sugar used in most cakes __________
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extends the shelf life
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What are the 2 ways the high level of sugar in cakes extend the shelf life?
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1. inhibit spoilage by reducing the aw
2. invert sugar is more effective than sucrose in reducing aw and inhibiting spoilage |
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The longer shelf life in cakes is due to the _______ nature of sugars - as moisture is being drawn into the cake form the air, the cake retains its moistness overtime
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hygroscopic
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During baking, the presence of large amounts of sugar in cakes dilute the protein structure, delaying the setting of protein, which results in ___________
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increased volume
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Browning of the crust occurs quickly when _________ are used (Maillard reaction and some caramelization) in cake.
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monosaccharides - fructose and glucose
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________ is a non-reducing sugar, therefore must be inverted to participate in the Maillard reaction; for this reason, ______ is more applicable for cake making compared to monosacharides or any other disaccharides
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sucrose
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sugar is a primary ingredient in cookies, and contributes to the spreading of the dough during baking. _______ causes considerably more spreading in cookies than goes granulated sugar
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"dessert sugar"
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AFter baking, sucrose recrystallizes as the cookies cool, contributing to __________
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a crisp surface
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Cookies made with more than one type of sugar (ex: fructose and glucose) are _______ because of less sugar crystal formation
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less crispy
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Different types of sugar are available commercially and they vary in their individual characteristics and functions in food; Choices of sweetener for food production include ______, _______, _______ and _________
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sugars, syrups, sugar alcohols , and alternative sweeteners
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______ is the table sugar and is derived from either sugar cane or sugar beets
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sucrose
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_____ also known as dextrose, is the basic building block of most carbohydrates and the major sugar found in the blood
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glucose
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_____ contribute to the malty taste of some milk shakes and candies
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maltose
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What are the types of sugars used in food applications? (3)
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1. Granulated sugar
2. superfine or dessert sugar 3. confectioners sugar |
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What are the types of brown sugar?
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1. turbinado
2. brownulated sugar 3. brown sugar |
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_____ from either sugar cane or sugar beets is the most common sugar
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granulated sugar
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_______ dissolves more readily than granualted sugar - may be more appropriate for making products such as meringues
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superfine or dessert sugars
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_______ are pulverized (finely ground) - sucrose crystals blended with cornstarch at a level of 3% to prevent caking of the sugar
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Confecitoners sugar - better known as powdered sugar
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______ a light brown sugar, only the surface molasses is removed , has a Mild falvor ; is the sugar of choice for individuals seeking a sugar that is considered healthful and natural (but this is not very true)
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turbinado sugar
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_____ is light brown and can be poured
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brownulated sugar
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_____ are slightly acidic and higher in moisture compared to granulated sugar
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brown sugar
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What should the selection of sugar be based upon?
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desired flavor
1. the darker the color, the stronger the flavor 2. claim of nutrition advantage is not untrue |
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Also called levulose or fruit sugar is found naturally in fruits and honey, and the sweetest of all sugars
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fructose
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_____ contributes a greater sweetening power compared to sucrose when used in beverages but not so when used in baking
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fructose
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fructose tends to _______ during baking
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burn
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_____ is considered more tolerated by people with diabetes because of slow physiological assimilation
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fructose
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_____ is a disaccharide, is the least sweet of all sugars , extracted from whey in the process of cheese making
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lactose - milk sugar
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because of its _________, lactose is used as a sweetener and anti-caking agent to coat other sugars for the purpose of restricting moisture absorption
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low hygroscopicity
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_____ keeps candies and icings from becoming sticky on the surface
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lactose
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to the contrary, _____ and _____ attract moisture (keep baked goods moist) and improve their shelf life
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invert sugar and glucose
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____ are sugary solutions that vary widely in viscosity, carbohydrate concentration, flavor and price
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syrups and liquid sweeteners
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Corn syrup, high fructose corn syrup, honey, molassess, maple syrup, and invert sugars are common sources of ________
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syrups and liquid sweeteners
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_____ is a by product of starch productions; approximately 75% sugar, 25% H2O
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corn syrup
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________ is manufactured by adding week acid solution or a combination of acid and enzyme to hydrolysis of corn starch
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corn syrup
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______ is a mixture of carbohydrate, ranging from glucose to oligosaccharides and even dextrins of different chain lengths
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corn syrup
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_________ has a high Dextrose Equivalent (DE) of over 58
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corn syrup
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_________ is the measure of the amount of free dextrose (glucose) , which parallels glucose formation by hydrolysis of larger carbohydrate molecule ( pure dextrose = 100 DE)
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dextrose equivalent (DE)
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_____ reflects the proportion of reducing sugars to the total number of glucose molecules
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DE value
DE = number of reducing sugars/Total number of glucose molecules X 100 |
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_____ is produced by converting nearly 90% of glucose in corn syrup to fructose using isomerase and enzyme produced by Streptomyces
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HFCS
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HFCS has a DE of approx ____, it is _____ compared to corn syrup
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65, less viscous
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_____ has a greater sweetness, ability to ferment, browning reaction and more hygroscopic than regular corn syrup ; it has replaced sucrose in soda
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HFCS
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Corn syrup can influence ____ and _____ of a cake especially chocolate; the _____ of corn syrup tends ot shirt the color form reddish overtone to a deep brown
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crumb and crust color ; acidity
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____ can result in undesirable detectable browning in the interior of white cake ; reducing the pH of a batter from 7.1 - 7.5 to < 7.0 ameliorates the browning problem when cornstarch of HFCS is used as a sweetener
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HFCS
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_____ a by product of sucrose( from sugarcane) production by concentrating sugar cane product ; this process produces _____ which is usually used in animal feeds
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molasses, blackstrap molasses
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____ is used in food preparation including baking and rum making, available as sulfered or unsulfered , contains about 70% sugar
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molasses
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____ is valued for its distinctive flavor , it is the sweetener of choice for diabetic patient because of its high fructose content (slower GI motility )
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honey
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_____ tends to promote rapid browning when used in place of sucrose in baked products
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honey
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_____ is made from grain sorghum by boiling down the juice to a syrup ; contains a maximum of 30% water ; often used in souther dishes and in the beer industry
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sorghum syrup
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_____ is a product of maple syrup; is made by further boiling of the syrup until most of the water evaporates and sugar crystallizes out of the syrup
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Maple sugar
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_____ is the precipitation of crystals form a solution into a solid, geometric network
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crystallization
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about ____ pounds of maple sugar are produced from 1 gallon of maple syrup
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8 lbs
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_____ is an equal mixture of glucose and fructose created by hydrolysis of sucrose ; it is sweeter than granulated sugar , available only in clear liquid
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invert sugar
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________ a sugar of choice for the professional confectioners who desire sugar that yield a smooth, melt in the mouth texture (without gritty texture) ; resists crystallization
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invert sugar
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_____ are not sugars, however they add high degree of sweetness to food products and commercial applications are growing
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alternative sweeteners
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Why is there an interest in alternative sweeteners?
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the consumers' interest in low calorie foods (designer foods)
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____ are foods with increased levels of health promoting substances
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designer
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What are the 2 groups of alternative sweeteners?
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1. polyhydric alcohols
2. nonutritive sweeteners |
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____ are alcohols with several hydroxyl groups enabling them to be used as sweetener even though they are not sugars
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polyhydric alcohols
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sorbitol, mannitol, xylitol, maltitol , isomalt, lactitol , erythritol, mannitol, xylitol are examples of _______
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polyhydric alcohols
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The following are hydrogenized to form alternative sweeteners
sucrose --> __ mannose --> ___ maltose --> ___ xylose --> ____ |
sorbitol
mannitol maltitol xylitol |
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______ is a list of additives "generally recognized as safe" for use in foods because of long use with no evidence of carcinogenicity
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GRAS list
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____ have significant commercial applications when used in small amounts; yield less energy than sugars and have other potential health benefits
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polyhydric alcohols ; often used in combination with other sweeteners in many foods
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Sugar alcohols have ______ (absorbed slowly) makes them more appropriate to a diabetic pt's product
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low glycemic response
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What is the down side to polyhydric alcohols?
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flatulate experience (gas) due to a prolong microbiological action in the intestines result in intestinal discomfort and diarrhea
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____ is used in beverages, frozen dairy desserts, baked goods, chewing gum, and candies
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erythritol
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____ is used in candies, chewing gum, ice cream, jams, and jellies, frostings, beverages and baked goods
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isomalt
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_____ used extensively in sugar free chewing gum because it does not have cariogenic properties associated with sugar
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xylitol
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____ is used in various food products ranging from baked products to beverages and as humectant and bulking agent, as well as sweetener, valuble for its water binding capabilities that limits mold growth and enhacing shelf life
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sorbitol
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______ producing or promoting the development of tooth decay
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cariogenic
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_____ has a chemical structure similar to fructose, and trehalose is a disaccharide found in mushrooms ; are both used as sweetener in foods and beverages and have potential health benefits
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D-tagatose and trehalose
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Some alternative sugars have _____ ; promote the growth of healthy bacteria in the GI
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prebiotic effects
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products containing some polyols can be labeled as ______ but those with D-tagatose and trehalose canoot be labled this way
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"sugar free"
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_______ are also reffered to as intense sweeteners, very low calorie, or alternative sweeteners
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nonnutritive sweeteners
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What are the benefits of using alternative sweeteners?
|
1. offer consumers a way to enjoy the taste of sweetness with little or no energy and or glycemic response
2. nonnutritive sweeteners may assist in weight management, control of blood glucose, and prevention of dental caries |
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The trend in the food industry is to blend ______ with ________ to create new sweet taste profiles
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high intensity sweeteners with other nonnutritive and nutritive sweeteners
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Because nonnutritive sweeteners provide sweet taste with the use of small amounts, manufacturers combine the sweetener with a _______ (ex: polydextrose, maltodextrin, polysacchride polyols) to replace some of the functional properties of the nutritive sweeteners
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bulking agent
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blending the sweeteners create ______ - decreasing the amount of sweeteners needed and improve the overall sweet taste profile
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sweet synergy
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What are the 5 alternative sweeteners currently approved by the FDA for use in the US?
|
1. saccharin
2. aspartame 3. acesulfame-K 4. sucralose 5. neotame |
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_______ are also known as intense sweeteners, defined as those that are substantially sweeter than sucrose by weight
|
alternative sweeteners
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______ is the level of consumption, maintained every day and still safe by a wide margin. Moderation and variety are still recommended
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Acceptable daily intake (ADI)
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Artifical sweeteners and weight control: much research is still being done and using artifical sweeteners will not automatically reduce energy intake
|
true
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____ is used primarily in soft drinks and as a table top sweetener, rapidly excreted in the urine , does not accumulate in the body, has been removed from list of cancer-causing substances
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saccharin
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______ general purpose is sweetener, warning about phenylalanine for those with PKU, controversial finding that it may have caused cancer in rats, excessive intake should be avoided by those with epilepsy
|
aspartame
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____ is made from sugar and passes through the digestive tract
|
sucralose
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____ is the most recent on the market , very sweet, phenylalanine is not an issue
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neotame
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____ is used for foods and beverages , provides less kcals than sugar, high doses can cause flaulence and loose stools
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tagatose
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____ and ____ are pending FDA approval and are approved in other countries
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alitame and cyclamate
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____ is the storage form of carbohydrates in plants
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starch
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_____ is a linear fraction of starch, composed of lgucoe units linked by 1,4 alpha glucosidic linkages, slightly soluble ; weight ranges from a few thousands to as large as 150,000
|
amylose
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starches form various sources differ in the _______
|
amylose content
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_____ is responsible for gelling characteristics of cooked and cooled starch mixtures; any starch high in ___ will gel much better
|
amylose
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____ is higher in cornstarch than wheat starch, higher in wheat starch than potato starch and least in tapioca (17%)
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amylose
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____ is a polymer of d-glucose (an isomer of glucose) composed of glucose units linked by 1,4 alpha and 1,6 alpha- glucosidic linkages; molecules are dendritic (branching) ; they are non-linear, bushy , and dense
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amylopectin
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_____ is more abundant in starches than amylose; roots and tuber starches contain 4 times _____compared to amylose(like cassava/tapioca)
cereal starch is nearly 75% ____ genetic variations of starches usch as waxy maize contains virutally only ________ |
amylopectin
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The behavior of starche sin food during preparation and processing is determined by the proportion of _____ and ____
|
amylose and amylopectin
|
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starch ______ is contribtued to amylose content in a food
|
gelatinizaiton
|
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Why do starches form different plant sources differ in their ability to gel?
|
the concentration of amylose and amylopectin in a solution determin the starches ability to hold water. the higher the amylose content the more likely the starch will gel(form a solid structure) when mixed with water and heated. Cornstarch is high in amylose, while potatoe starch and tapioca are high in amylopectin
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What test is done to determine the amylose/amylopectin content in food?
|
iodine test
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____ is used in estimating the proportion of amylose to amylopectin in starches
amylose turns blue color when it reacts with helix structures of this starch amylopectin turns a purplish red color |
iodine test
|
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What are the funtional properties of starch?(4)
|
1. gelatinization
2. gel formation 3. retrogradation 4. dextrinizaiton |
|
Starch can also be _____
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modified
|
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___ is the swelling of starch granules and migration of some amylose into the cooking water when starch is heated in water (this is mass transfer) ; characteristics changes = increase in volume, increase viscosity, and translucency of starch granules as starch thickens
|
Gelatinization
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______= to serve as a thickening agent, starch must be dispersed in COLD water and subjected to heat
|
process of gelatinization
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During gelatinizaion, the application of ___ causes hydrogen bonds in the starch granules to break - this even facilitates the entry of water into the starch granule ; this is followed by the movement of amylose molecules into the surrounding water
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heat
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The removal of some of the amylose (during gelatinization) and the physical spreading out of the remaining amylose and amylopectin (plays a role but not significant) molecules in the granule results in loss of ___________and increased _________
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birefringence ; translucence
|
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During gelatinizaiton the _____ of the granule increases as more water enters and forms hydrogen bonds with amylopectin and amylose molecules, the bond water increases the physical size of starch granules
|
volume
|
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____ is a violent compression inward of starch granules; reduces viscosity of heated starch mixture
|
implosion
|
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What happens during gelatinization?
|
starch granules heated in liquid instantly swell, increasing viscosity, Heating beyond the maximum obtainable volume ruptures the starch granules resulting in less viscosity
beyond the heat of 194' F implosion occurs and viscosity is lost |
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______ is the ability of the starch granule to refact light in two slightly different directions; is depicted by dark corsses under a microscope providing polarized light
ex: teaspoon of flour in water then shake it, the characteristic of starch in cold water, before the thickening happens |
birefringence
|
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once gelatinizaiton occurs birefringence _______, indicating a loss of crystallinity of starch , this is seen in raw starch
|
disappears
|
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_______ a particle transparency occurs in starch mixture as a result of loss of birefringence ; a characteristic of heated starch
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translucence
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_____ is another term to describe changes occuring in starch as heated in water; occurs when a solution of starch in water is heated beyond gelatinization is between birefringence and translucence
|
pasting
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heating beyond pasting causes starch granular to ______
|
implode
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What is starch gelatinizaiton dependent on ?
|
amount of water
temperature timing stirring the presence of... acid sugar acid + sugar salt fat or protein and type of starch |
|
in gelatinization , sufficient water must be available to _______ and _____ - it must be done in COLD water
|
dissolve starch and for absorption
|
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In gelatinization, the amount of liquid needed for absorption depends on the concentration of _______ and _____ in the starch
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amylose and amylopectin
|
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When preparing starchy foods such as grain or pasta, sufficient water is added to cover and then more for evaporation and two to three time expansion in volume
|
true - think what is done when preparing rice
|
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most starches gelatinize at a temperature between _________
|
133 'F and 167 'F
|
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Starch gelatinize within a narrow temperature range known as ________ ; the higher the amylose content the higher the temperature needed
|
transition temperature
|
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continuous heating causes starch granules to break apart, stresses the bonds holding them together and subsequently the rupture of the granules (implosion) and decrease in viscosity
|
timing effect of gelatinization of starches
|
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starches should be constantly ______ to avoid clumping
|
stirred
|
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a pH below ____ decreases the viscosity of a starch gel
|
4
|
|
any acidic fruit juices should be added to pie fillings or salad dressings ___________
|
after gelatinization is complete
|
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to maintain viscosity in canned high-acid foods, commercial food processors use _______
|
modified starches ; these are chemically altered
read more on this in the book, missing information |
|
Learn the nature of table 20-2 in the book dont need to memorize
|
read in book
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_____ are commonly used as thickeners in products such as desserts and sauces with high sugar concentration
|
starches
|
|
What are the 5 things Sugars tend to do during starch gelatinizaiton?
|
1. compete for water with starch in a mixture because of its hygroscopicity
2. increase translucence of starch paste 3. reduce paste viscosity and gel strength 4. increase gelation temperature (delay or inhibit complete gelatinization) 5. sugars differ in their ability to delay gelatinization with the following sugars having greatest impact( fructose, glucose, and galactose have less effect compared to the disaccharides) |
|
read in book the affect sucrose has on starch gelatinization
|
read in book
|
|
Increased levels of sugar and acid substances (like lemon pie) lead to _____ and _______; meaning that sufficient heat must be applied to ensure complete gelatinizaiton and maximal thickening
|
increased viscosity and lower gelatinization temperature
|
|
in the food industry cross linked starch is used because of its _________
|
resistance to hydrolysis
|
|
_____ preserves the integrity of the gelatinized starch before it ruptures and increases the viscosity of the paste at is maximum peak
|
salt
|
|
______ delays gelatinization by coating the starch and prevents it form absorbing water
|
fat or protein
|
|
_______ are less mucilaginous when made into gelatinization starch pastes than root starches
|
cereal starches
|
|
_____ is the corn starch of choice for thickening, particularly when translucency of the paste is not a concern
|
corn starch
|
|
______ tends to produce stringy texture with translucent paste (unsuitable as a thickening agent for a gel but it can thicken to a flow point)
|
waxy corn starch
|
|
____ in the formation of a gel
|
gelation
|
|
____ is a colloidal of a solid dispersed in a liquid , have flow properties, which amy range form fluid to extremely viscous, the higher the temperature the greater the flow rate, the higher the concentration of the solids in a ____ the more viscous the ___
|
sols
|
|
_____ is solid matter and liquid, water is the dispersed phase and starch is the continuous phase, the solid in the ___ is sufficiently concentrated to provide the network needed to prevent the flow of the colloidal system
|
gel
|
|
in _______, sol or paste is formed by hydrating and dispersing the starch molecules in cold liquid with the application of heat
|
gelation
|
|
in a sol _____ is the dispersed phase, and _____ is the continuous phase
|
starch, water
|
|
in ________, amylose molecules that migrate into the liquid during gelatinization are free to move about in a starch phase; as paste cools, energy is lost and amylose molecules attempt to move together forming a network that holds water in the rigidily bond starch granules ; there fore starches lacking amylose( such as waxy starches) do not form gels in normal concentration
|
gel formation
|
|
What should be done to maximize gel strength? (3)
|
1. allow starch gel to cool without disturbances
2. agitation during gelling disrupts established hydrogren bonds and weakens the gel 3. if butter of flavoring were to be added, add immediately after removing the paste from the heat; then allow the mixture to cool without disturbance |
|
______ occurs as amylose molecules come together in a gel resulting in squeezing out the free water form the gel after extended storage time or a cut is made ; when this happens the integrity of the item is compromised
|
syneresis
|
|
_______ is a gradual increase of crystalline aggregates in starch gels during storage
|
retrogradations
|
|
______ results from amylose rearranging itself in an orderly fashion upon cooling ; this is the difference between fresh baked foods and baked goods
|
retrogradation
|
|
____ plays a larger part in retrogradation
|
amylose vs amylopectin
|
|
When you toast bread what happens?
|
reverse retrogradation
|
|
_____ is perceived as a gritty texture on the tongue
|
retrogradation
|
|
what are examples of retrogradation?
|
a starch thickened pudding held in the refrigerator for a few days and bread
|
|
review figure 5.8
|
functional properties of starch
|
|
_______ is the breakdown of starch molecules to smaller, sweeter tasting dextrin molecules in the presence of dry heat of uptake of one molecule of water whenever cleavage occurs
|
dextrinizaiton
|
|
explain the process of dextrinizaiton
|
starch is heated without any added water, the temp rises beyond the maximum level attainable in starch and water mixture; starch molecules splits at one or more of the linkages between the glucose units (degradation) ; shorter molecules of starch of varying lengths are formed(dextrins)
|
|
_____ are less viscous
|
dextrinized starches
|
|
When browning meat covered in flour, making roux or gravy and sauces,
|
examples of dextrinizaiton
|
|
How do you make a healthy gumbo?
|
heat flour in the oven to brown without the added fat
|
|
if you ________ your starch before cooking gelation will not occur
|
dextrinize
|
|
a small amount of starch are called __________; they are not digested in the small intestine and therefore do not contribute to calories
|
resistant starches
|
|
What is the advantage of toasting your bread?
|
the brown part becomes resistant starch
|
|
What are the 3 types of resistant starches?
|
1. inaccessible starch
2. resistant starch granules 3. retrograded starch |
|
_____ trapped in food prevented from gelatinizing
|
inaccessible starch
|
|
_____ indigestible because of their chemical configuration
|
resistant starch granules - read more in book
|
|
____ are formed when heating/cooling starch renders molecules of amylose and amylopectin
|
retrograded starch
|
|
_____ is the rough outer covering protecting the grain; ex: in legumes this is the outer coating
|
husk
|
|
___ is the hard outer covering just under the husk that protects the grain's soft endosperm
|
bran
|
|
____ is the largest portion of the grain, containing all of the grains starch; reservior of carbohydrates in plants
|
endosperm
|
|
____ is the smallest portion of grain, and the embryo for a future plant; responsible for germination
|
germ
|
|
review figure 21-1 in book
|
reivew
|
|
natural occuring starch souces include all plant sources , T or F?
|
true
|
|
two major forms of naturally occurring starches are ___and ___
|
cereal and root starches
|
|
____ are corn, wheat and rice
|
cereal starches
|
|
_____ are potatoes, arrowroot, cassave (tapioca)
|
root starches
|
|
other starch sources are dried beans, peas, sago palms
|
true
|
|
Legumes are not processed to obtain starch for use in food preparation; they are eaten as the whole seed because the contain ______________
|
other nutrients, espeically protein
|
|
Waxy starch are mainly made of _______; made to avoid amylose completely , they do not gel! primarily developed to thicken but not desirable gel agent
|
waxy starch ; almost 100 % amylopectin
|
|
____ are useful in fruit pie prepartion and othe rproducts in which thickening is desirable without the gelling
|
waxy starches
|
|
____ are chemically or physically altered to create a unique starch
|
modified starches
|
|
Modified starches may affect the starches ?????
|
1. gelatinization
2. heating times 3. freezing stability 4. sold water solubility 5. viscosity |
|
What are 3 examples of modified starches?
|
pregelatinized starches
thin - boiled oxidized starches read in book - missing 5 bullets |
|
_____ do not have to be heated in water to expand and gel; have already been cooked and dried, so absorb cold water immediately and expand; used in instant dry mix pudding, gravy, and sauces
|
instant or pregelatinized starch
|
|
_____ has to be modified to be effective as a thickener
|
tapioca starch
|
|
processed or modified tapioca is called ______
|
pearl tapioca
|
|
______ consists of partially gelatinized starch, dried into pellets - so hard that they require overnight soaking to use; is less mucilaginous when made into gelatinized starches pasts
|
pearl tapioca
ex: of pre-gelatinized starch |
|
________ Pregelatinized starch made primarily for microwave cookery
|
Cold Water Swelling starch
|
|
• An acid hydrolyzed starch by using weak hydrochloric or nitric acid to debranched amylopectin at the 1, 6, alpha glucosidic linkage
|
thin-boiling starch (ex of modified starch)
|
|
What are the characteristics of thin-boiling starch?
|
• More soluble and less viscous
• Forms thin sol when hot but strong gel when cold • Used for making gumdrops |
|
• Exposed to chemical oxidizers
• Less viscous than cross-linked, but clearer and more useful as stabilizers and thickeners • Has a powder-like consistency, which makes it ideal for dusting foods (e.g., gum) |
oxidized starch
|
|
one of the more commonly used modified starches- treated with ethylene or acetic anhydride to link the starch molecules together with crossbridges
• Cross linking makes starch more heat resistant • Improves stability • Effective thickening agents and forms gels that undergo very limited retrogradation • Useful as thickeners and stabilizer in salad dressings and related products • Ideal for use in cooked or canned foods such as pizza, spaghetti, cheese, barbeque sauces, pie fillings, bakery glazes, and puddings |
cross linked starch
|
|
• A derivative made by reacting starch molecules with tripolyphosphate or other phosphate to achieve a thickener with excellent stability and clarity
• Characteristics: • Less viscous than crosslinked • Improved stability • Form smooth, nonstringy pastes and gels • Do not undergo syneresis • In a packaged by this starch would be most appropriate b/c the amylose and amylopectin will not have the opportunity to come together and squeeze water out |
starch phosphates
|
|
characterized by the formation of porous spheres when spray dried with small amount of bonding agents- i.e. Amaranth starch
• Characteristics • Serve as flavor carriers in selected foods • Absorbed a flavor up to 60% of their weight • Without protective coating, flavors can be preserved over several months |
spherical agregates
|
|
What is the criteria for starch selection?
|
➢ Starch selection depends on the desired use
• Thickener needed to produce low-calorie products ➢ Select starches that form strong gel • If mouth feel is an important consideration • Syneresis can be a problem in freeze-thaw products ➢ Select starches with freeze-thaw stability are desired (waxy rice flour) ➢ Freeze-thaw stability • Freeze-thaw stability is the ability of a starch-thickened product to be frozen and thawed without undesirable loss of quality-(gritty crystalline texture) • Waxy rice flour is a useful starch for products to be frozen and thawed • Purified rice starch is not as effective as waxy rice flour, but better than corn and wheat starches for freeze-thaw stability ➢ Retrogradation is a problem when starch-thickened product must be refrigerated for storage (i.e. pudding) ➢ Starches that retrograde easily will quickly develop a gritty texture that is noticeable on the tongue ➢ Use cross-linked starches • Resistant to retrogradation ➢ Other considerations: • Marketing stresses- • Influence the strength of a starch gel such as in pudding or pie filling • Product appeal- • Influenced by the flow characteristics of starch-thickened sauces and other sols rigidly of gels needs to be suited to consumer expectations |
|
plants provide variety in the food supply including ______ and ________
|
gustatory (sense of taste) and beautiful colors
|
|
_____ increases the demand for fruits and vegetables
|
nutrition
|
|
_____ and _______ increase demand for fruits and vegetables
|
disease prevention and enhancement of optimal health
|
|
True or False? There large market for both fruits and vegetables as well as in cans, frozen items and or dried
|
true
|
|
_____ contribute uniqueness among vegetables
|
legumes
|
|
_____ are not traditionally considered foods, however they are becoming increasingly popular as garnishes color and flavor accents
|
edible flowers
|
|
Fresh herbs commonly available in the produce section of the groceries include basil, dill, oregano, parsley, rosemary, sage, tarragon and thyme. are used as _______
|
flavoring agents
|
|
Fresh herbs can be substituded for dried by using about ____ times more of the fresh herb.
|
8 times more
|
|
Fruits and vegetables are made up of ____and various types of _____
|
tissue systems and cell walls
|
|
___ are the building blocks of plant and animal organisms
|
cells
|
|
The cells vary from plant to plant and there is noticeable differences between the ____, ____, and ____ plant foods at different stages of maturity
|
underripen, ripe or overripe
|
|
What are the 3 tissue systems of fruits and vegetbales?
|
1. dermal tissue
2. vascular system 3. ground system |
|
____ represents the skin or ring of the fruit or vegetables, protective covering of the plant
|
dermal tissue
|
|
____ is within the dermal tissue of the fruit or vegetable, responsible for transporting fluids, nutrients, and waste products
|
vascular system
|
|
_____ the most varied component of plant structure ; consisting of parenchyma cells and other supporting tissues such as collenchyma and sclerenchyma cells
|
ground system
|
|
_____ are the principle cells in fruit and vegetables, most abundant type of cell in the ground system ; within the cytoplasm of the cells - they are compounds responsible for the plant's starch content, color, water volume, and flavor
|
parenchyma cells
|
|
_____ are aggregates of elongated cells (ex: those fibrous stands of celery), chewy and resistant to softening when cooked , one of the supporting tissues because it contributes to the overall structure of the edible part of fruits and vegetables containing _____
|
collenchyma cells
|
|
______ are cells of interest in foods because, these wood-like cells are associated with the gritty texture of some plant foods ; the unique texture of pears, is the result of the presence of sclereids a type of ____cell; sclerids and other types of _____ are collectiely callerd fibers, with thick cell walls containing lignin
|
sclerenchyma cells
|
|
_____, _____,and ______ form the structural component of the plant cell walls
|
cellulose, pectic substances, and hemicelluloses
|
|
______ occurs naturally in all vegetables, fruits and legumes. Can be extracted from wood pulp or cotton and used in foods as anticaking, thickening and texturizing agents in food processing
|
cellulose
|
|
_____ is a glucose polymer but unlike amylose its glucose units ar ejoined by 1,4 beta-glucosidic
|
cellulose
|
|
The structural differences between cellulose and starches is responsible for textural differences and also the inability of humans to _______________
|
digest/use cellulose as a source of energy
|
|
Cellulose molecules is capable of aggreagting into _________; a cluster of these occur in some fibrous vegetables
|
fibrils with crystalline structures
|
|
______ heterogeneous group of polysaccharides component of plant cell walls; some are soluble in acid while others are insoluble ; are sensitive to alkaline cooking mediums
|
hemicellulose
|
|
What effect does does alkaline cooking medium have on hemicelluloses?
|
addition of alkaline such as baking soda causes this component of plant cell wall to disintegrate and become flaccid or mushy when heated in cooking water
|
|
_____ is responsible for the unacceptable softness in vegetables and fruits cooked in alkaline medium
|
hemicellulose
|
|
the destruction of ______ is an important consideration discouraging the use of soda in cooking vegetables especially legumes -a good source of the vitamin
|
thiamine
|
|
______ is the term describing a group of polysaccharides found in vegetbales, grains, legumes, and more significantly in fruits
|
pectic substances
|
|
in the cell wall pectic substances combine with ______ to reinforce the structural contribution of cellulose
|
hemicellulose
|
|
What are the 3 pectic substances?
|
1. protopectin
2. pectin (pectinic acids) 3. pectic acid |
|
What are the functions of pectic substances? (3)
|
1. act as cementing substance between cell walls
2. partially responsible for the plants' firmness and structure enabling them to trap water and form a gel 3. contribute significantly to the textural changes as fruits mature |
|
_____ are used commercially to contribute to the gelling of fruit preserves ; the string like pectin molecules bond to each other under the right conditions to form a net-like structure that is able to trap water and form a gel
|
pectic substances
|
|
____ is found between the plant cells and within the cell walls BUT not in the juice
|
pectin
|
|
Commerical sources of ____ include the pulp (pomade) remaining after apples are pressed for juice and the sponge albedo of citrus fruits
|
pectin
|
|
____ is the white inner rind of citrus fruits, which is rich in pectin and aromatic cells
|
albedo
|
|
_____ is a long polymer consisting primarily of galacturonic acids units joined by 1,4 alpha linkages
|
protopectin
|
|
______ is a water insoluble form of pectic substances found in immature/unripe fruits and contributes significantly to the firm texture of unripe fruits
|
protopectin
|
|
as fruit ripens , enzymes (pectinase) convert ______ to a more water-soluble ______ by random demthylation and hydrolysis along the ______ molecules
|
protopectin, pectin , protopectin
|
|
The degree of ripening and softening of fruit is related to the _________, (how many substances were degraded)
|
degree of demethylation
|
|
as fruit ripens,some demethylation and hydrolysis randomly take place along the _________
|
protopectin molecules
|
|
When only a limited amount of degradation has occurred the pectic substances are termed ______
|
pectins
|
|
_____ are galacturonic acid polymers in which most, if not all of the acid radicals have been esterified with methanol
|
pectins
|
|
pectins are valued for ________ properties in making jams and jellies; it is the pectin extract from ripe fruits that is used to gel jam and jellies
|
gel-formation
|
|
as additional demethylation and hydrolysis continues ______ are formed
|
pectinic acids
|
|
______ are galacturonic acid polymers in which between 25% to 50% of the acid radicals have been esterfified with methanol ; form of pectic substances are formed as fruit begins to soften just a little
|
pectinic acids
|
|
If a pectin moleculeis esterified completely ( i.e. all orgnaic acid residues are altered to methyl ester) - the pectin will contain a littler more than 16% methoxyl groups . This is called a ________
|
low methoxy pectinic acid
|
|
most pectins contain fewer than 16% methoxyl groups
|
true
|
|
________ contain methyl ester on no more than every 1/4 unit and frequently only about 1/8 of galacturonic units are esterified
|
low methoxyl pectinic acid
|
|
______ are the form of pectic substances found in fruit that is just beginning to ripen ; forms gel readily with little addition of sugar- valueble in making dietetic jellies and jams
|
low methoxy pectinic acid
|
|
____ is the smallest of the pectic substances ; lacking methyl esters
|
pectic acids
|
|
As protopectin acids become devoid of methyl esters, the molecule gradually become shorter and the fruits become _______
|
overly soft
|
|
_____ is found in overly ripe , very soft fruit and vegetables
|
pectic acid
|
|
____ is found in immature fruit and does not gel
____ is found in ripe fruit and gels ____ is overripe fruit and does not gel |
protopectin ---> pectin --(pectinic acid)--> pectic acid
|
|
What does the food industry use pectin as?
|
emulsifier, stabilizer , thickener, texturizer
|
|
Why does cloudiness occur in juices?
|
when juice is extracted from fruits, pectic substances can somewhat cause cloudiness; Cloudiness is desirable in organe juice, where it contributes to the body BUT undesirable in some other juices including apples ;
|
|
cloudiness in juices is removed via _______
|
clarification process
|
|
_____ is when an enzyme such as pectinases are added to juice to break down pectin compounds that contribute to cloudiness
|
clarificaiton process
|
|
____ and _____ also break down cellulose and hemicellulose the cell walls, respectively to release more juice
|
cellulase and hemicellulase
|
|
_____ is a non carbohydrate polymer of many aromatic structures linked together to form an extremely large complex molecule that gives a woody quality to plant foods
|
lignin
|
|
as plants mature, lignin deposits with hemicellulose in cell walls to form tough ____________ ex: asparagus stalks
|
woody vegetables
|
|
Since the woody desposits are insoluble in water and connot be softened by cooking , it is always _______
|
discarded
|
|
_____ are responsible for the browning and bruising that often occurs in ripening fruit
|
phenolic compounds
|
|
____ are found mostly mostly in unripe fruits, giving them a bitter taste and leaving astringent in mouth
|
tannins
|
|
some fruits that contain _________ are apples, apricots, avocados, bananas, cherries, dates, grapes, nectarines, papayas, peaches, pears and strawberries
|
phenolic compounds
|
|
The tissue of fruits and vegetables when exposed to air ________
|
quickly darkens
|
|
The phenolic compounds promote oxidative browning in the fruits and vegetables resulting in the formation of brown or gray black pigment called ___________
|
melanines
|
|
Phenolases are found in high amounts ____.
|
potatoes, mushrooms, apples, peaches, bananas, avocadoes and tea leaves
|
|
What are the 3 ways to prevent oxidative browning ?
|
Maintaining an acid pH , Reducing contact with oxygen , denaturing enzymes
|
|
As fruits and vegetables mature what 3 things happen?
|
1. cellulose and hemicelluloses content increase
2. fruits and vegetbales become less tender 3. increased levels of lignins - resulting in tough woody texture primarily in vegetables |
|
Pectic substances undergo ________ (catalyzed by protopectinases) and _______ (catalyzed by pectinesterases) ; fruits progress from hard and firm texture to soft or even mushy texture
|
hydrolytic cleavage and deesterification
|
|
All synthesis of organic compounds stops after harvesting but _______ continues
|
physiological changes
|
|
Bulbs, roots, tubers, and seeds become ______ during storage
|
dormant
|
|
The fleshy tissues of fruits and vegetables undergo ripening and continue to _______
|
senescence
|
|
______ is accumulation of metabolic products, increase respiration , and loss of moisture in plant foods after maturation
|
senescence
|
|
_____ is greater in perishable fruits and vegetables ; those plant foods high oxygen consumption and carbon dioxide production are the most perishable
|
respiration rate
|
|
rate of respiration can be delayed by _________
|
refrigeration
|
|
What is the effect of respiration on starch/sugar?
|
1. rapid rate of respiration in corn increases starch desposition at the expense of sugar stores (Ex: freshly harvested corn is sweeter compared to days after harvesting)
2. the sugar in fresh harvested peas and other legumes deplete rapidly during respiration |
|
_____ is the period of maximum respiratory rate just before many fleshy fruits fully ripened
|
climacteric
|
|
______ continue ripening after harvesting - eX: bananas and peaches, apple, pear, tomatoes, etc.
|
climacteric fruits
|
|
______ such as grapes and oranges do not respirate rapidly and ripened after picking therefore needs to be harvested when ripened
|
non-climacteric fruits
|
|
Enzyme levels increase during _______ (including lipase, pectic enzymes, invertase, chlorophyllase ,and peroxidase)
|
during storage
|
|
The increase in enzyme levels contribute to _____________
|
deterioration of harvested fruits and vegetables
|
|
_______ is involved in accelerating ripening and early sensence of fruits during storage
|
ethylene gas
|
|
to control ripening , ______ is bubble into prematurely harvested fruit
|
sythetic ethylene
|
|
Other enzymes include hemicellulases and cellualse can promote the release of ______ from the complex polysaccharides constituting of the cellw all
|
sugars
|
|
Increased hemicellulases and cellulases activties results in the release of complex polysaccharides components of cell walls this makes ____________
|
ripened fruits sweeter
|
|
Starch in fruits is gradually converted to sugars by ________
|
amylase promoted reactions
|
|
Invertase enzyme converts naturally occuring sucrose to inverted sugars (gluose and fructose) - promoting ___________
|
further fruit sweetness
|
|
In potatoes, the enzyme phosphorylase promotes the conversion of _________
|
starch to sugar
|
|
When potatoes are held between freezing and 10'C there is increase ________
|
conversion of starch to sugar
|
|
potatoes stored at this temperature (10'C) tend to ________ , ______ and ______
|
brown excessively, taste sweeter, and less crispy when fried
|
|
To prevent accelerated conversion of potatoes starch to sugar and the undesirable effect, potatoes should be stored ______________
|
above the active temperature range for phosphorylase
|
|
In starch containing vegetables such as legumes and carrots , synthesis may continue to occur if stored at about _____________
|
normal room temperature
|
|
To prevent further starch synthesis, _______ should be used
|
refrigerator storage
|
|
Significant textural changes occur when fruits and vegetables are subject to heat including what 4 processes?`
|
1. gelatinization
2. loss of turgor 3. structural changes 4. osmosis |
|
corn and dried beans are vegetables but becuase of their high starch content, they undergo _________ during preparation
|
gelatinization
|
|
____ is a distension of the protoplasm and cell wall of a plant by fluid content
|
turgor
|
|
When heat is applied (steamed) to spinach and other greens, the cell walls become permeable causing __________
|
loss of water and loss of turgor
|
|
______ is evident by the wilting of the leaves and accumulation of water from the cells in the bottom of the pan
|
turgor
|
|
Pectic substances become more _______ as a result of chemical changes
|
soluble
|
|
HEmicellulous becomes softer as vegetables are heated:
Acids ___________ of hemicelluloses Alkali ______ of hemicelluloses |
slows the softening
accelerates softening |
|
_____ is the movement of solvent through a semipermeable membrane to the side with the higher solute concentrations
|
osmosis
|
|
The _________ of cell walls of fruits allowes water to pass through (but not solutes such sugars or minerals)
|
permeability
|
|
APplication of ______ destroys the cell memrbanes and break the barrier, allowing solutes to pass freely across the membrane until solute concentraions are euqal on both sides
|
heat
|
|
Heating fruit in water causes the natural sugars in fruit to __________________
|
migrate into the water and water moves from outside into the fruit, resulting in the loss of shape
|
|
To prevent loss of shape what should be done??
|
add small amount of sugar to the cooking water; less fruit sugars move into the cooking water and fruits tend to retain the shape and firmness
|
|
____ and _____ also help to firm cooked fruit
|
calcium salts and acids ; a reason why calcium is added to many canned fruits and vegetables
|
|
What is the effect of calcium on the textural changes during preparation?
|
calcium delays the softening of vegetables as a result of calcium ions reaction with pectic substances in the middle lamella ; calcium pectinates or pectates is formed, preciptating calcium ion, which add rigidity to vegetable structure
|
|
Adding calcium water or cooking vegetables in hard water tend to __________ to vegetable the structure
|
add rigidity
|
|
Adding molasses to cooked legumes have similar effect of increasing _______ because of the calcium content of molasses
|
rigidity
|
|
What is the recommended procedure for preparing legumes with added calcium?
|
cook or soften legumes to the desired level before adding molasses to prevent insoluble calcium-pectinates and pectates formation, which cause a significant delay in softening
|
|
What is the effect of added salt on textural changes during prepartion?
|
dried beans have a hard outer covering that requires soaking beans before cooking.
DO NOT use salt in the soaking water because it makes the outer surface of the beans more resistant to water penetration during cooking |
|
What are the effects of Added salt?
|
1. a 2-minute boiling period before an overnight soaking is encouraged to inactivate enzymes and avoid possible souring during an overnight soaking in cold water
2. a quicker alternative is to boil the beans for 2 minutes, soak for another hour, and simmer until done 3. Addition of alkali such as 1/8 tsp of baking soda to about 3 cups of water will reduce the cooking time by about 33%, however, this cooking method results in loss of thiamine |
|
Vegetable and fruits are clothed in array of colors - an important attribute for meal planning and plate presentation .
|
true
|
|
What are the 3 plant pigment categories?
|
1. caretenoids (yellow organe)
2. chlorophylls (Green) 3. flavonoids |
|
both carotenoids and chlorophyls are ______
|
fat solubles
|
|
the _____ are water soluble and have tendency to be lost in cooking water
|
flavonoid pigment s
|
|
What are the 5 pigments of ccarotenoids?
|
carotene(yellow-organe)
lycopene(red-organe) xanthophyll (yellow) lutein zeaxanthins ex: carrots, organges, peaches, pineapples, pink grapefruit, red and yellow pepers, tomatoes, watermelon, winter squashes |
|
What are the types of chlorophylls?
|
cholophyll a (blue green)
chlorophyll b (green) broccoli green cabbage kale lettuce spinach |
|
What are the flavonoids??
|
anthocyanin(red purple)
eggplant radish red cabage red potato anthoxanthin (cream/white) cauliflower onions rice turnips white potato betalains (purple red/yellow) beets |
|
_____ are responsible for the green color of plants ; promote photosynthesis; comprised of large molecules with a magnesium atom at the center of the ring structure ; fat soluble
|
chlorophyllls
|
|
____ is a process by which leaves capture the sun's light energy to covert CO2 and water to carbohydrates
|
photosynthesis
|
|
___ has a methyl group attached
___ has an aldehydge group atached instead |
chlorophyll a
chlorophyll b |
|
_____ is done as part of the preparation for freezing enhances green color because of the expulsion of air from the intercellular spaces
|
blanching
|
|
What are the effects of blanching for chlorophyll?
|
the color is retained during freezing and the subsequent boiling prior to serving the vegetables
|
|
___ is means used for preserving green vegetabels
|
canning
|
|
___ are unstable in the presence of heat
|
chlorophylls
|
|
_____ intensifies the bright green of chlorophyll as air is expelled
|
heat applications
|
|
Continuous heating slowly transform pigments from bright green to an unattractive _______
|
olive green (drab ) color
|
|
When fruits and vegetables are heated in the presnece of acid (ie acetic and oxalic acids) the cells are disrupted and ____________
|
organic acids are released from the cell sap
|
|
When fruits and vegeabtles are heated in the presence of acid, acids then replace the _______ at the center of chlorophyll with 2 atoms of hydrogen
|
magnesium atoms
|
|
What compounds are formed during heat applied in the presnece of acids to fruits and vegetables?
|
pheophytins ( an irreversible color change)
ex: the olive green color canned spinach is a good example of the color change that occurs |
|
The effect of acid on chlorophylls pigment can be prevented by ______
|
adding alkali (ie baking soda)
|
|
Rather than forming pheophytin, the chlorophyll retains Mg at the center of the molecule, phytyl group is split off and a ______ sodium salt is formed what does this created?
|
sodium salts; chlorophyllins
|
|
Chlorophyllin is a water soluble compounds with a _____ color ; the cooking water turns green as the pigment is leahed out
|
bright green color
|
|
In the presence of ____and ____ , chlorophyll pigments turn to a bright green color
|
zinc copper
|
|
For the best result, cook greens how?
|
uncovered and as fast as possible
|
|
______ along with lycopenes and xanthophyll account for most of the yellow organce and some of the red color of fruits and vegetables
|
carotendoids (alpha and beta)
|
|
_____ lend redding organce color to carrots and winter squashes
|
carotenes
|
|
__ and ___ account for most of the red color and fruits and vegtables
|
xanthophylls and lycopenes
|
|
____ is a deeper red color, providing the bright color of tomatoes
|
lycopene
|
|
heat may modifty carotenoids pigments strucutre - ordinary cooking methods have _____________ effect on the color or nutrition value
|
little or no effect
|
|
exposure to oxygen causes ________ of carotenoid pigments resulting in loss of color
|
oxidations
|
|
_____ are not significantly affect by acid, alkali, volume of water or duration of cooking
|
carotenoids
|
|
_____ are a group of more than 4000 water-soluble pigments with 2 types; anthocyannins and anthoxanthins ; most are glycosides - having molecules of sugar attached
|
flavonoids
|
|
_____ occur alone in light colored vegetables such as potatoes, yellow skinned onions, and cauliflower or with other pigments such as anthocyanins
|
flavnoids
|
|
_____ are responsible for most of the red , purple and blue colors of fruits and vegetables such as color of cherries, red apples, varioues berries, blue and red grapes, pomegranates, radishes, eggplant , poatoes, red cabbage, and predpotoat skins, rasberries
|
anthocyannins
|
|
____ intensifies the red color of anthocyanins
at a _____ the pigment is violet in color; _____ changes the reddish blue hue to an unappetizing blue and then to green |
acidic tap water; neutral pH , alkaline water
|
|
_____ from knives or containers made of iron, tin or aluminum turns anthocyanins pigments to off-color ; stainless teel and glass are the best choices of cooking utensils for the prearation and store anthocyanins rich foods ; enamel lined canes are used for food containing anthocyanins to prevent contact with the tin
|
metal ions
|
|
____ are composite of compound known as flavones, flavonols, flavonones and the proanthocyanins ; they are responsible for the cream or white color of cauliflower, onions white potaotes and turnip
|
anthoxanthins
|
|
What is the effect of acids on anthoxanthins?
|
in acidic medium, anthoxanthins pigments become colorless or white; few drops of juice , vinegar, or a pinch of cream of tartar added to anthoxanthins rich foods after cooking keep the pigment snow white
|
|
What is the effect alkali on anthoxanthins?
|
in an alkaline medium ,anthoxanthin pigments turn to an undersirbale yellow color, white foods such as rice, poratos cauliflower and onions have yellowish cast when cooked in alkaline water
|
|
___ are is not significantly affect by heat; with pigment reacts with iron and copper to form a blue black and a reddish brown color; tin and aluminum cause it to turn bright bellow color
|
anthoxanthins
|
|
____ is a water soluble biolet red pigment with limited use as a food additive( gives beets their dep purplissh red color) ; acidic ingredients concert the purplish red hue of beets to brighter red; in an alkaline medium the red color shifts to yellow; it turns brownish in the presence of metals such as copper and iron
|
betalin
|
|
____ is the combination of materials in foods that can not be digested readily by man ; a variety of compounds comprise dietyar fiber
|
fiber
|
|
most fibers comprise of 1, 4 beta linkage which make them _________
|
resistant to digestion by humans; humans lack the enzyme needed to break the 1,4 beta linkage
|
|
_____ are viscous and include some hemicellulose, pectin, gum, and mucilages
___ are non viscous and include lignin, cellulose, and some hemicellulose |
soluble dietary fibers
insoluble dietary fibers |
|
_____ are described by their sources than than their chemical or physical proerpties
|
dietary fiber
|
|
Dietary fibers are described as fiber that occur
1. 2. 3. 4. |
1. naturally in intact plants
2. functional fibers 3. resistant starches 4. total fibers |
|
_____ are fibers extracted from plant or manufactured and have health benefits
|
functional fibers
|
|
____ are starches that are not digested in the small intestine and therefore enter the large intestine intact ; they act as fiber to promote GI motility and also undergo limited digestion to yield some energy ; is useful in formulating food products for the large market of consumers seeking reduced calories and more fiber in their diets
|
Resistant starches (RS)
|
|
___ refers to the sum of dietary fibers and functional fibers ; was created to accommodat ethe labeling of product that may contain new fiber sources iwth potential beneficial effects
|
total fiber
|
|
What are the benefits of fiber? (4)
|
1. plant foods ar evalued in the diet as a significant source of fiber
2. both soluble and incolsuble fibers ar efound int he same food but in different proportions 3. soluble fibers are digested to a limited extent by intestinal bacteria 4. insoluble fibers are excreted undigested- thus providing no energy but increase the bulk of the stool |
|
citrus fruits oat and legumes are excellent sources of ______ while vegetbales are valued for their content of ______
|
soluble fibers
insoluble fibers |
|
_____ in oats (beta-glucan) helps lower blood cholesterol; this characteristic of oats has elevated oat containing product to a higher level - allowing health claim on its lable
|
soluble fiber
|
|
product contianing _____ from ____ (a water soluble gum) can make a similar health claim as oat
|
psyllium from psyllium seed husks
|
|
____ are made with oat bran, flavorings and seasonings suitable for incorporation into ground meat
|
fat replacers
|
|
____ can be blended with low fat ground meats to produce cooked patty containing only 10% fat
|
bran products
|
|
___ enhances the water tention/adhesion ; the finished patties are juicy m flavorful, and ahve acceptable moutfeel ; also used in bread to about 15% of the flour without sensory change
|
bran
|
|
dietary suuplemetn industries are not regulated by the FDA ; true or flase?
|
true
|
|
the 1994 dietary supplement helath and educaiton act(DSHEA) limits the ________
|
FDA authority over dietary supplements
|
|
under DSHEA, the FDA can only prove that dietary supplements are unsafe ________
|
after the supplemtns are int he market
|
|
___ are complex carbohydrates found in plants ; they are hydrophilic in nature - called hydrocolloids ; they are large molecules of monosaccharides units linked together by glycosidic linkages ; they undergo litttle digestion in the small intestine and are classified as soluble fiber
|
gums
|
|
the monosaccharide components of _____ are varried widely compared to the energy -yielding disaccharides and the glucose polymers (dextrins and starch )
|
gums
|
|
What are the characteristics of gums?
|
1. remarkable ability to attract and bind water
2. contributes very limited calorie because of the limited digesiton and absorption |
|
attention is focused on gums as possible ____ because of the potential nutritional and health benefits when incorporated into food products
|
additives
|
|
The _____ of gums increases stool bulk until digestion of gums in the large intestine occurs
|
water holding capacity
|
|
Gums are digested and absorbed _____ compared to sugars and starches ; one of reasons why they are used in low calorie food products (target at weight concious americans)
|
inefficently
|
|
agar, guar gum, gum arabic and pectin provide between _____ caloires per gram
|
1-3
|
|
cartageenan and xanthan gum provide at the most a calorie pergram
|
true
|
|
___ have the potential to protect agianst caner
|
gums
|
|
Gums are valued as ___ and ____
|
thickening agents and fat replacers
|
|
____ is the ability of a liquid an dsemiliquid to flow
|
viscosity
|
|
compative viscosity allows smaller amount to be used for thickening compared to starch; low calier adnatage to starch and sugar
|
gum as a thickening agent
|
|
his attributes that mimic fat and oil in food; substantial kcal reduction when used as fat substitute ; used in salad dressings to provide appropriate thickening in place of some of the oil ordinarily
|
gums as fat replacers
|
|
gums in ____ mimic fat and improve mouthfeel; aggregation of ice crystals in this are blocked when gums are added producing a fine textured product
|
ice cream
|
|
in cakes __ extended shelf life , delay staling, enhance cell structure, increase volume when used in the appropriate amount
|
gums
|
|
in beverages ___ are added to increase the fiber content of foods and beverages
|
gums
|
|
____ is a complex fructooligosaccharide derived from the roots of chicory ; it is a soluble fiber - not digested until it reache the large intestine where some bacterial digestion occurs; it is also an ingredient of interest in the creation of functional foods
|
inulin
|
|
____ shown to promote absorption of calcium and magnesium and decrease cholesterol and serum lipids
|
prebiotic (inulin)
|
|
_____ stimulates lactobacilli and bifidobacteria in the color, which helps to combat possible harmful microoganisms and and promote health
|
gum- inulin
|
|
___ lacks flavor so it can be incorporated into product without introducint detrimental overtones; and it contributes to a pleasing mouthfeel when used in table spreads, yogurt, frozen desserts, and dressings; it can be added to breads and other baked products at levels high enough to be of merit in increasing fiber intake
|
Inulin as a versatile food ingredient
|
|
What is the food industry application of inulin?
|
to develop, modify fat and sugar products that meet consumer's increase demand for fewer calories per product
|
|
___ are carbohydrates derived from seeds, plant exudates , seed weed extracts, and microorganisms
|
gums
|
|
gum sources as a group are called _______
|
hydrophillic polysaccharides
|
|
Gums of primary commercial significance from seeds derived from guar and locust been (carob) classified as _____
|
legumes
|
|
Gums from ________ are gum arabic, tragacanth, karaya, and ghatti ; gum arabic is most commonly used
|
plant fluids - oozing liquid from cuts in tropical trees
|
|
The red and brown algae (irish moss and giant kelp) provide ____, ___, and ____
|
agar, carrageenan and algin
|
|
The most successful of the microbe fermented gums is _________, produced when microorganisms Xanthomonas campestris ferment glucose in the presence of some trace of elements
|
Xanthan gum
|
|
What are common attributes of individual gums?
|
1. they are polysaccharides in which glucose is ususlly absent
2. galactose is common to seed, plant exudates and seaweed gums but not algin |
|
guar and locust beans coomposed primarily of __ and ___ linked together by a 1,4 beta linkage with 1,6 alpha linage at regular interval
|
mannose and galactose
|
|
___ has twice as much galactose as does locust bean gum
|
guar gum
|
|
____ requires heat for maximum hydration while guar gum hydrates in cold water
|
locust bean gum
|
|
____ include gum arabic , tragacanth , karaya and ghatti ; are oozing liquids from cuts in tropical trees; strucutrally they are less orderly and have other ocmpounds other than polysaccharide polymers
|
plant exudates
|
|
____ are rich in galactose (often with sulfate ester) - includes agar, carregeenan and algin
|
seaweed extracts
|
|
____ forms strong and transparaent gels which are reversible when heated and reform when cooled again
|
agar
|
|
____ occurs in various fractions , some form gels and some do not gel
|
carrageenan
|
|
____ has ability to interact with protein to promote stabilization of various milk products including ice cream process cheeses and chocolate milk
|
carrageenan
|
|
_____ has the ability to interact with protein to promote stabilization of various milk products including ice cream process cheeses and chocolate milks
|
carrageenan
|
|
___ is used to form both gels and films ; mannose and gulucronic acid are the prinicple components; in addition, they contain numerous salts resulting from the presence of sodium, potassium and ammonium ions
|
algin
|
|
___ are fermentation produced polysaccharide gums including xanthan and curdian ; fermented by colon bacteria
|
microbial exudates
|
|
___ was approved by the FDA in 1996 and marketd as Pureglucan ; it forms a gel that is stable under freezing and retorting
|
curdlan
|
|
___ is the starting material for the produciton of most synthetic gums
|
cellulose
|
|
Because of the potential nutritionla benefits of adding fiber to various food products, many foods currently are formulated with ___ to replacec part of all of traditional functional ingredients such as starch or fat
|
gums
|
|
____ is a soluble fiber and is will suited for liquid foods such as soups
|
gum arabic
|
|
__________ a soluble fiber can be used alone or in conjuction with gum arabic to increase fiber content of a food
|
carboxymethylcellulose (CMC)
|
|
The _______ of both gum arabic and CMC makes it possible to use comparatively high levels without developing a gritty texture in liquid foods
|
high degree of solubility
|
|
Guar gum and locust bean gums can replace ___% of the starch in thickening thus reducing calires in the food
|
50%
|
|
____ is used successfully as a thickener in salad dressings
|
xanthan gum
|
|
Different starches and various polysaccharide gums are used in commerical foods and define the __________ - ranging from liquids (soups and sauces to bakery products) to snack foods
|
textural attributes of foods
|
|
In product development, to meet a defined need of the consuemrs, starches or gums are used to do what 5 things?
|
1. improve acceptability
2. meets processing requirements 3. repleases or bind flavors appropriately 4. improve shelf life stablity 5. improve visually appealing |
|
lipids like carbohydrates are compared of carbon, hydrogen, and oxygen atoms but in different proportions
|
true
|
|
Lipids will not dissolve in water but can be dissolved in________ not used in food preparation such as benzene, chloroform, ether and acetone
|
organic solvents
|
|
What are the 3 categories edible lipids are divided into?
|
1. triglycerides (fats and oils)
2. phospholipids 3. sterols |
|
There are two major components of simple fats including ____ and ____
|
glycerol and fatty acids
|
|
____ is a polyhydric alchol containing 3 carbon atoms, forms the back bones of lipids
|
glycerol
|
|
___ in simple fats are orgnaic compounds the characteristic carboxyl group identifying them as an acid
|
fatty acid
|
|
___ usually contain an even number of carbon atoms. The smallest number of carbon is 3 carbon (acetic acid with 2 carbon atoms) and the largest is arachidonic acid a 20 carbon atom
|
fatty aicds
|
|
What are the 2 major ways fatty aicds differ from each other?
|
1. degree of saturation
2. the length |
|
___ is determined byt he number of carbon atoms
|
length of fatty acids
|
|
____ is determined by the number of double bonds between carbon atoms
no carbon = carbon double bonds , saturated one carbon = cabron double bond , monounsaturated two or more carbons = cabron double bonds polyunsaturated |
degree of saturation
|
|
Each fatty acid is identified by a common name rather than their sytematic nomenclature; what are the 3 kinds?
|
1. saturated fatty aicds
2. monounsaturated fatty acids 3. polyunsaturated fatty acids |
|
___ have no doubel bonds, primarily animal sources; meats , dairy, milk, butter, plants (coconut, palm, and coconut oil)
|
sautrated fatty acid
|
|
____ are one double bond: primarily plant sources; olives, olive oil, peanuts, peanut butter, and avocado
|
monounsaturated fatty aicds
|
|
___ are two or more doubel bonds, primarily plant sources; vegetable oils and fish
|
polyunsaturated fatty acids
|
|
____ is the most abundant monounsaturated fatty acid (MUFA) a 18:1(18 carbons and 1 double bond)
|
oleic acid
|
|
the ___ is the carbon at the end furthest from carboxyl end is designated as the omega carbon
|
terminal carbon
|
|
the polyunsaturated fatty acids associated with health benefits are the essential fatty acids _____ and _____
|
omega 3(linolenic acid) and omega 6(linoleic acid) fatty acids
|
|
___ can be described chemically as 18:2 (n-6) when identifying its structure by omega category or cis-9 , cis-12-octadecanoic acid
|
linoleic acid
|
|
___ is an omega 6 fatty acid
|
linoleic acid
|
|
_____ commonly called linolenic fatty acid consists of 18 C atoms and double bonds at C 9 ,12, and 15
|
linolenic acid
|
|
____ is an omega 3 fatty acid
|
linolenic acid
|
|
____ fatty acid is of particular importance because it is a precusor of 20-carbon eicosapentanoic aicd (EPA) and 22-carbon docosahexanoic acid (DHA)
|
alpha-linolenic or linolenic fatty acid
|
|
__ and ___ are highly unsaturated fatty acids with high biological activity.
|
EPA and DHA
|
|
The double bonds in naturally occuring polyunsaturated fatty acids are in the _______ with a methylethyl between the carbons at the double bonds
|
cis configuration
|
|
_____ are lipids with the double bonds naturally occuring polyunsaturated fatty acids in the cis configuration with a methylethyl between the carbons and the double bons
|
non-conjugated fatty acids
|
|
____ is a fatty acid naturally abundant in milk fat consisting of double bonds on alternate carbon atoms, with one in a cis and another in the trans form
|
Conjugated linoleic acid (CLA)
|
|
___ is a product of microbial action in the rumen of cattle
|
CLA
|
|
only _________ fatty acids are to be reported on the nutrition lable; CLA is believed to have some health benefits
|
non conjugated trans double bonds
|
|
___ is the temperature at which the crystals of a solid fat melts or becomes a liquid
|
melting point
|
|
the melting points of fatty acids are related to the ___, ____, ___ and ____
|
chain length, degree or saturation , configuration, and crystalline structure
|
|
Which fatty acids have a higher melting point due to degree of saturation?
|
saturated fatty acids have a higher melting point than unsaturated fatty acids
|
|
The higher the degree of saturation , ________
|
the lower the melting point
|
|
____ have a lower melting point
|
short chain fatty acids
|
|
____ are more likely to be solid at mixing temperature than are short chain fatty acids
|
long chain fatty acids
|
|
a fatty acid with a _____ configuration, has a higher melting point than identical fatty acid with a cis form at the double bond
|
TRANS
|
|
The arrangement of the fatty acids (how they are packed or crystalized, in the solid phase ) determines ______
|
the melting point
|
|
The larger the crystals in fatty acids , the _______ melting point
|
higher the melting point
|
|
FAts in foods can be classified on the basis of the number of ___________
|
fatty acids esterified to the glycerol molecule
|
|
one fatty acid linked to glycerol is a _____
two fatty acids linked to a glyerol is a _____ three fatty acids attached to a glycerol molecule is a _____ |
monoglyceribe
diglyceride triglyceride |
|
about 95 % of all lipids are ______
|
triglycerides
|
|
fats and oils in foods belong to a group called ____
|
lipids
|
|
/Fats and oils differ in 2 ways:
1. ? 2. ? |
1. fats are solid at room temperature when oils are liquid
2. fats are usually derived from animal sources, while oils are predominately from plants The exceptions are coconut and palm oils which are solid at room temp , and fish oils which are liquid at room temp. |
|
plant sources high in fats include ___ ,____, ___ and ___; most fruits vegetables and grians contain little if any fat
|
nuts seeds avaocado olives and coconut
|
|
most food contain ___ types of fatty acids but usually one type predominates
|
3 types
|
|
most vegetable and fish oils are high in _______ while olive and canola oils are rich in ______
|
polyunsaturated ; monounsaturated
|
|
The animal fat, coconut and palm oils are more _____
|
saturated
|
|
Foods from animal origin usually contain about a ____ P/S ratio of polyunsaturated and saturated fats , while in plant foods the ratio is usually ____
|
50:50 , 85:15
|
|
The higher the _____ , the more polyunsaturated fats the food contains
|
P/S ratio
|
|
P/S ratio
|
review table in notes
|
|
___ are similar to triglycerides in structure in that fatty acids are attached to the glyelrcol moelcule , the difference is the replacement of fatty acids in the 3rd position of glycerol with phosphate containing compound
|
phospholipids
|
|
The presence of phosphorus containing compound makes phospholipids _____ , while its fatty acid components are only soluble in fat
|
soluble in water
|
|
phospholipids are Widely used by the food industry as ______ in products such as beverages, baked goods , mayonnaise and candy bars
|
emulsifiers
|
|
Foods naturally contianing _____ include egg yolks, liver, soybeans, wheat germ and peanuts
|
phospholipids
|
|
The best known phospholipid is ___ which is found in egg yolks
|
lecithin
|
|
____ acts as an emulsyfing agent - allowing hydrophobic and hydrophillic compunds to mix
|
lecithin
|
|
___ serves as an important component of cell membranes, where it assists in moving fat soluble vitamins and hormones in and out of the cell
|
phospholipids
|
|
___ are large intricate molecules consisting of interconnected rings of carbon atoms with a variety of side chains attached
|
sterols
|
|
____ are of physiological importance because they are involved in maintaining the human body - they include cholesterol, bile, both sex (testosterone, estrogen ) and adrenal (cortisol) hormones and vitamin D
|
sterols
|
|
The sterol of most significance in food is ____
|
cholesterol
|
|
Both animal and plant foods contain sterols, however , cholesterol is found only in foods of _____
|
animal orgiin ( meat, poultry, fish , fish roe(caviar) , organ meats(liver brain kidney) dairy products and egg yolks
|
|
Plants do not contain cholesterol but they may contain other types of sterols , T/F?
|
True
|
|
____ are found in small amounts in many fruits vegetables nuts seeds cereals legumes and other plant sources
|
plant sterols
|
|
in 2000, the FDA allowed the use of health claims in regarding the role of plant sterols or plant sterol esters in reducing the ________
|
risk for coronary heart disease
|
|
To qualify for a claim, a food must contain at least ___ gram of plant sterol or 1.7 grams of plant sterol esters per serving
|
0.65 g
|
|
It qualify for a claim, food must not cintain over ___ g of total fat per serving and per 50 g
|
13 g
|
|
Spreads and salad dressings are exempted if the lable refers the consumer to the product's ______
|
nutrition facts panel
|
|
When discussing the lipid content in foods , they are reffered to as ___
|
fats
|
|
___ are solid at room temp, usually derived from animal origin except fish oil which is liquid at room temp, have high emlting point and smoke point ; more appropriate for frying
|
fats
|
|
___ are liquid at room temp and are usually from plant cources except coconut oils and palm oils; they have low melting points and smoke at low temperatures
|
oils
|
|
Most fats are mixtures of ____ in oils
|
crystals of fats
|
|
What are the 4 chemical changes in lipids ?
|
1. rancidity
2. peroxidation 3. lipolysis 4. reversion |
|
____ is chemical deterioration of fats, that occurs when triglyceride molecules and or the fatty acids attached to the glycerol molecule are broken down into smaller units resulting in off flavors and odor
|
rancidity
|
|
The longer the fat is stored, the greater the possibility of it being ____
|
rancid
|
|
Fat and oils used for cooking tend to become rancid because they are exposed to __,___ and ___; for this reason they should be checked frequently for rancidity
|
oxygen, heat, and light
|
|
What are the 2 types of rancidity?
|
1. oxidative rancidity
2. hydrolytic rancidity |
|
___ involves the uptake of oxygen at a double bond position of an unsaturated fatty acid ; the double bond is broken and oxygen becomes part of the molecule rsulting in the formation of free radicals
|
oxidative rancidity
|
|
What are the steps of oxidative rancidity?
|
1. initiation
2. propagation 3. termination |
|
Compounds from _______ including aldehyde, ketones, and alcohols are responsible for the characteristic off flavor of oxidized fats
|
hydroperoixides
|
|
oxidative rancidity is common in _________
|
polyunsaturated fatty acid such as linoleic fatty acid
|
|
_______ in fat is also faciliated by metals such as iron, copper, and light/warm temperatures
|
chemical degradation/reaction
|
|
_____ results from the splitting/seperation of the fatty acid (lipolysis) from the glycerol backbone as a result of fat uptake of molecule water
|
hydrolytic rancidity
|
|
____ is a reaction of a molecule of water with a fat molecule to release a free fatty acid in the presence of lipase or heat
|
lipolysis ; this reaction is promoted by the action of lipase or by heat
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placing cold, wet food in a heated frying oil introduces water makeing the oil prone to ______
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hydrolytic rancidity
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a complete hydrolysis of a triglyceride yields what?
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3 free fatty acids and one molecule of glycerol
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Free fatty acids generated from hydrolytic rancidity alter _____ and _____
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aroma and flavor of fat or oil
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______ is the break down (oxidation ) of an essential fatty acid, linoenic acid, found in certain vegetable oils , leading to an undesirable flavor change prior to the start of actual rancidity
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flavor reversion
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the odors/ flavors of product undergoing flavor reversion depend on _______
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they type of oil ; soy bean oil intially becomes beany and then fishy
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The two most commonly used oils are ____ and ____ and are resistant to flavor reversion
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cotton seed and corn oils
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When storing fats and oils avoid ___ and ____
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oxygen and heat
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store fat in tightly closed containers in a cool, dark environment. This ____________
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slows the onset and continous perpetulation of oxidative rancidity
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store fats such as butter and maragine in the refrigerator ; butter keeps for months in the freezer but margarine does not freeze
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true
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___ and ____ should be stored in a dark spot or cupboard shelf - will keep longer if refrigerated
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shortening and most oils
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___ should be refigerated after opening because of its short shelf life
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olive oil
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___ are added to foods contianing large amounts of unsaturated fats to prevent rancidity
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antioxidants , natural and commerical
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______ are substance used to preserve food by retarding deterioration, rancidity, or discoloration due to oxidation
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USDA 's Code of federal regualtions definition of antioxidants
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What are the 3 ways in which antioxidants prevnet oxidation of fats?
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1. being oxidized themselves
2. donating their hydrogen to a fatty acid as a reducing agent 3. sequestering metals such as a chelating agent |
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What are the naturally occuring antioxidants?
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vit E, C , lecitin, flavonoid, and gum guaic
many vegetabl oils naturlaly contain vit E |
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nutylated hydroxyanisole (BHA) , butylated hydroxytoluene (BHT), tertiary butyl hydroquinone (TBHQ) , and proply gallate (PG) are examples of ________
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syntheic antiodiants approved by the FDA and used as additive in foods
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What are 5 exmaples of foods to which antioxidants are added to?
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1. dry cereals
2. creackers 3. nuts 4. chips 5. flour mixes |
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___ refers to the clawlike manner in which the agent binds to the metal through coodinated covalent bonds
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chelate
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examples of chelating agents also known as metal sequesterers include ___ , ___ and ____
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EDTA, citric acid and phosphates
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vitamin C, vitamin E (locopherols), beta carotene , flavonoids , erthorbic acid , asorbyl palmitate, sulfites are examples of _________
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reducing agents that transfer hydrogen
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_____ is the temperature at which fats or oils begin begin to emit a trace of smoke as a result of fat degrataion
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smoke point
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fats and oils can be heated to extremely high temperatures however, with extensive use fat moleulces begin to break down ; ____ ocurs at a high temperature in all fats but varies form fat to fat and the previous fats history
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smoke point
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when fats and oils are heated beyond the smoke points, a ____ is met
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flash point
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____ represents the point at which heat fat can ignite when heated beyond the smoke point
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flash point
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___ with the uptake of water this occurs releasing free fatty acids
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lipolysis
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as a result of lipolysis :
monoglycerides --> ? diglycerides --> ? triglyerides --> ? |
glycerol + free fatty acid
glcerol + 2 free fatty acid glycerol + 3 fatty acids |
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heating beyond the flash point causes ______ to break (hydrolyzed )
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ester linkage ( the point where glycerol and fatty acids are joined together)
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With continuous heating beyond hydrolysis (glycerol and fat) , this promotes futher deteriative changes- two molecules of water are removed from the glycerol resulting in the formation of a steel blue smoke called ________
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Acrolein
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____ is a highly imitating and volatile ocmpound formed when glycerol is heated to the point where two moelcules of water split form fatty acid ; its a sharp offensive odor warning people of its presence ; this smoke is extremely irritating and even harmful to the mucous membrane of the mouth and nasal passages
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Acrolein
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The ____ is specific for each fat- as a fat is used at high temperatures over an extended period this will graudualy dorp for that fat until the appearance of fried foods become unacceptable
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smoke point
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Monoglycerides are often added to ______, the presence of monoglycerdies reduces the smoke point too low for acceptable frying products
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shortenings and other fats
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fat for frying is selected based on the _____
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smoke point; the higher the smoke point the better the fat for frying
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_____ is a process in which free fatty acids link/stick together - this occurs when fat is over heated resulting in gummy, dark residue , more viscous , and prone to foaming
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polymerization
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The fatty acid formed from lipolysis promotes ______ when it undergoes additional chemical modificaitons as the frying fat continues to be heated
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polymerization ; among the compounds formed are a variety of polymers including simple dimers and trimers
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fatty acids contianing at least one _______ are susceptible to polymerizaiton
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double bond
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______ is a monomer formed in starch rich foods cooked at high temperature
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acrylamide (ethylene carboxyamide or 2-propenamide)
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potato chips are fried at high temperatures and are high in starch - potato chips is one of the foods with high levels of _______
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acrylamide
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for _____ , high levels have been reported in other staple foods such as rice and potatos, is deemed to be carcinogenic to animal - no evidence of its carcinogenicity in man
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acrylamide
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