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597 Cards in this Set

  • Front
  • Back
fatty acids with one (mono) or two or more double bonds (polyunsaturated )
mono- and polyunsaturated fatty acids
Nearly ____ of foods on our grocery shelves have added sweeteners - for sweetness or as preservative
98%
Sweeteners elicit pleasurable sensations with ______ or without ______ energy
nutritive or non-nutritive
Naturally sweet foods _____ and ____ contain important nutrients to support health
fruit and breast milk
_________ are generally recognized as safe (GRAS) by the Food and Drug Administration ; yet concern exists about increasing sweetener use relative to optimal nutrition and health
Nutritive sweeteners ( ex: sucrose and fructose)
Dietary quality suffers at intake above _____ of total daily energy
25%
Sweet taste is stimulated by a wide variety of compounds include ____, ____, and _____
sugars, sugar alcohols, dipeptides
True or false: The various mono- and disaccharides are the most common natural sweeteners used in foods, however, non-carbohydrate compounds such as saccharin and aspartame are also incorportaed into manufactured foods
true
Sweeteners are valuable in foods because of the physical and functional properties including what 7 characteristics?
1. sweetness
2. hygroscopicity
3. solubility
4. hydrolysis
5. degradation
6. caramelization
7. maillard reaction
The properties of foods and beverages affect sweetening power including _____, ______, and ________
physcial state, temperature, and the presence of other flavors
When dissolved, all sugars are sweet to the tongue, but some are sweeter than others;

The ability of sugar to sweeten a food product is of interest because ________________.
sugars contribute to the total kcal content of foods at 4 kcal/g.
sugar that is very sweet can be used in smaller quantities than the less sweet type minimizing total kcal without sacrificing sweetness; The relative sweetness of sugar is affected by ______________________
the temperature of the solution is of the solution it is dissolved
FRuctose is the sweetest sugar and is 1.4 times sweeter than sucrose at 5 ' C but 0.8 times as sweet at 40 ' C; is an example of what affect on sugar?
temperature affecting the relative sweetness of sugar
_________ provide more sweetening power by weight compared to any of the natural sugars - relative sweetness of sugar solutions at 5% and other sweeteners
non-sugar sweeteners
________ refers to the ability of sugar to attract and hold water
hygroscopicity - sugar have a great affinity for and hold water
_______ of sugar is helpful in maintaining the freshness of baked products and can also be a potential textural problem at a very high humidity
hygroscopicity
Increased temperature increases the ability of sugars to __________________
absorb moisture from the environment
_______ refers to sugars ability to go into solution in a specific volume of liquid at standard temperature
solubility
______ of sugar is affected by the type of sugar
solubility
______ is the most soluble of all sugars and lactose (milk sugar) is the least soluble
fructose
Explain the effect of temperature on the solubility of sugar
more sugar is dissolved in a known volume of liquid at increased temperature compared to lower temperature
_____ is important in the textural property of foods
solubility
____ is smooth because of the high levels of fructose
candy
_____ creating gritty texture in ice cream
lactose
_____ is the splitting of sugar molecules into its monosaccharides - a common occurrence in sugar
hydrolysis
Disaccharides undergo hydrolysis when _______ - an acidic medium favors hydrolysis reaction, so also water
heated
Hydrolysis of sucrose (fructose + glucose) result in _________
invert sugar (inversion)
______ is formed by hydrolysis of sucrose; creating a mixture of equal amounts of fructose and glucose
invert sugar
______ is the opening of sugar structural ring ; it is a prelude to sugars breaking down to the smaller molecules
degradation
_____ is the first step in heat destruction of sugars in cookery
degradation
A chemical reaction that occurs in both acid and alkaline mediums
degradation
In the presence of acid ______ of the molecule occurs as 3 molecules of water are eliminated, resulting in the formation of organic acid and aldehyde substances
dehydration
____ is the process of heating dry sugar or sugar solution (with most of its water evaporated) until it melts into a clear, viscous liquid and , as heating continues, it turns into a smooth, brown mixture
caramelization
Caramelization is initiated by __________
sugar inversion
Caramelization is initated by sugar inversion, then _____ occurs creating polymers ranging from tri to oligosaccharides , then ______ reactions promote the formation of organic acids and cyclic compounds
condensation occurs , dehydration reactions
______ promotes pleasing flavor changes ; the color change ranges from pale golden brown to deepening brown
caramelization
______ is a non-enzymatic browning resulting from condensation of reducing sugars and amines group of the amino acid when heat is applied or during an extensive storage
maillard reaction
__,____,____ are reducing monosaccharides and _____ , ____ are reducing disaccharides, however, sucrose being non-reducing sugar does not undergo maillard reaction
glucose, fructose, galactose

lactose and maltose
What are the 9 functional properties of sugars in foods?
1. taste (sweet)
2. preservation
3. flavor
4. color
5. texture
6. tenderness
7. volume
8. fermentation
9. stability of foam
______ approxiamtely 98% of packaged foods have sugar added to improve this
sweet taste
high concentrations of sugar can act as a ______ by inhibiting the growth of microorganisms
preservation
application of heat results in sugar degradation contributing to the unique taste of products such as candy is known as _______
flavor - functional property of sugar
for Color: subjecting sugar to varying level of heat develops appealing color as a result of ______ and __________
caramelization and maillard reaction
the texture of many processed or prepared foods relies on ______, espeically _________
sweeteners , sucrose
when shortening the gluten power, ______ is created
tender products
Cakes become more tender as ______________
sugar content is increased until a critical maximum is reached
____ serves as food for yeast
sugars
_____ is increased with increased sugar content if the sugar content is too high
volume
many alcoholic beverages and a few other foods around the world rely on the _________
fermentaiton of carbohydrates
egg foam is stabilized with the ________
addition of sugar
Addition of _____ to egg white causes the foam to have smaller cell size and a fine texture
sugar
In starch thickened puddings, sugar serves as a ___________ ingredient
tenderizing
Sugar delays the __________ in protein containing products
protein
What are the 4 applications of sweeteners in food?
1. Crystalline candies
2. amorphous candies
3. syrups, sauces, jams and jellies
4. baked products
__________ are candies that are easy to bite with large area of organized sugar crystals
crystalline candies
_______ lack organized structure because of the high sugar concentration and the interfering substance
amorphous candies
The physical characteristics of candy is determined by the ________ and _______
concentration of sugar and the presence of interfering substances
At ________ , mixture boil at about 112' C resulting in crystalline candies
lower sugar concentrations
________ boil to as high as 142' C yielding amorphous products
high sugar concentration
In syrups and sauces sugars provide sweetness and increase the ________

Sauces for desserts utilize sugar as a sweetener
viscosity
_____ is essential for the sweet taste in most jams and jellies, and equally vital is sugar's role in preserving fruit
sugar
Sugars also serve to prevent ______ - the high concentration of sugar dehydrates microorganisms ; creating unflavor osmotic pressure for microbe to grow
microbial growth
In all baked products, sugar __________ of flour
"shortening the gluten power"
_____ serves as food for yeast in leavened breads
sugar
Sucrose is split and inverted by yeast _______ to provide glucose and fructose for fermentation ; Fermentation produces Co2 that leavens the dough
invertase
The pleasing evenly brown crust color of bread is a function of _______________; using glucose (dextrose) or corn syrup produces bread with light and somewhat reddish brown color
sucrose and high fructose corn syrup
High levels of sugar used in most cakes __________
extends the shelf life
What are the 2 ways the high level of sugar in cakes extend the shelf life?
1. inhibit spoilage by reducing the aw
2. invert sugar is more effective than sucrose in reducing aw and inhibiting spoilage
The longer shelf life in cakes is due to the _______ nature of sugars - as moisture is being drawn into the cake form the air, the cake retains its moistness overtime
hygroscopic
During baking, the presence of large amounts of sugar in cakes dilute the protein structure, delaying the setting of protein, which results in ___________
increased volume
Browning of the crust occurs quickly when _________ are used (Maillard reaction and some caramelization) in cake.
monosaccharides - fructose and glucose
________ is a non-reducing sugar, therefore must be inverted to participate in the Maillard reaction; for this reason, ______ is more applicable for cake making compared to monosacharides or any other disaccharides
sucrose
sugar is a primary ingredient in cookies, and contributes to the spreading of the dough during baking. _______ causes considerably more spreading in cookies than goes granulated sugar
"dessert sugar"
AFter baking, sucrose recrystallizes as the cookies cool, contributing to __________
a crisp surface
Cookies made with more than one type of sugar (ex: fructose and glucose) are _______ because of less sugar crystal formation
less crispy
Different types of sugar are available commercially and they vary in their individual characteristics and functions in food; Choices of sweetener for food production include ______, _______, _______ and _________
sugars, syrups, sugar alcohols , and alternative sweeteners
______ is the table sugar and is derived from either sugar cane or sugar beets
sucrose
_____ also known as dextrose, is the basic building block of most carbohydrates and the major sugar found in the blood
glucose
_____ contribute to the malty taste of some milk shakes and candies
maltose
What are the types of sugars used in food applications? (3)
1. Granulated sugar
2. superfine or dessert sugar
3. confectioners sugar
What are the types of brown sugar?
1. turbinado
2. brownulated sugar
3. brown sugar
_____ from either sugar cane or sugar beets is the most common sugar
granulated sugar
_______ dissolves more readily than granualted sugar - may be more appropriate for making products such as meringues
superfine or dessert sugars
_______ are pulverized (finely ground) - sucrose crystals blended with cornstarch at a level of 3% to prevent caking of the sugar
Confecitoners sugar - better known as powdered sugar
______ a light brown sugar, only the surface molasses is removed , has a Mild falvor ; is the sugar of choice for individuals seeking a sugar that is considered healthful and natural (but this is not very true)
turbinado sugar
_____ is light brown and can be poured
brownulated sugar
_____ are slightly acidic and higher in moisture compared to granulated sugar
brown sugar
What should the selection of sugar be based upon?
desired flavor
1. the darker the color, the stronger the flavor
2. claim of nutrition advantage is not untrue
Also called levulose or fruit sugar is found naturally in fruits and honey, and the sweetest of all sugars
fructose
_____ contributes a greater sweetening power compared to sucrose when used in beverages but not so when used in baking
fructose
fructose tends to _______ during baking
burn
_____ is considered more tolerated by people with diabetes because of slow physiological assimilation
fructose
_____ is a disaccharide, is the least sweet of all sugars , extracted from whey in the process of cheese making
lactose - milk sugar
because of its _________, lactose is used as a sweetener and anti-caking agent to coat other sugars for the purpose of restricting moisture absorption
low hygroscopicity
_____ keeps candies and icings from becoming sticky on the surface
lactose
to the contrary, _____ and _____ attract moisture (keep baked goods moist) and improve their shelf life
invert sugar and glucose
____ are sugary solutions that vary widely in viscosity, carbohydrate concentration, flavor and price
syrups and liquid sweeteners
Corn syrup, high fructose corn syrup, honey, molassess, maple syrup, and invert sugars are common sources of ________
syrups and liquid sweeteners
_____ is a by product of starch productions; approximately 75% sugar, 25% H2O
corn syrup
________ is manufactured by adding week acid solution or a combination of acid and enzyme to hydrolysis of corn starch
corn syrup
______ is a mixture of carbohydrate, ranging from glucose to oligosaccharides and even dextrins of different chain lengths
corn syrup
_________ has a high Dextrose Equivalent (DE) of over 58
corn syrup
_________ is the measure of the amount of free dextrose (glucose) , which parallels glucose formation by hydrolysis of larger carbohydrate molecule ( pure dextrose = 100 DE)
dextrose equivalent (DE)
_____ reflects the proportion of reducing sugars to the total number of glucose molecules
DE value

DE = number of reducing sugars/Total number of glucose molecules X 100
_____ is produced by converting nearly 90% of glucose in corn syrup to fructose using isomerase and enzyme produced by Streptomyces
HFCS
HFCS has a DE of approx ____, it is _____ compared to corn syrup
65, less viscous
_____ has a greater sweetness, ability to ferment, browning reaction and more hygroscopic than regular corn syrup ; it has replaced sucrose in soda
HFCS
Corn syrup can influence ____ and _____ of a cake especially chocolate; the _____ of corn syrup tends ot shirt the color form reddish overtone to a deep brown
crumb and crust color ; acidity
____ can result in undesirable detectable browning in the interior of white cake ; reducing the pH of a batter from 7.1 - 7.5 to < 7.0 ameliorates the browning problem when cornstarch of HFCS is used as a sweetener
HFCS
_____ a by product of sucrose( from sugarcane) production by concentrating sugar cane product ; this process produces _____ which is usually used in animal feeds
molasses, blackstrap molasses
____ is used in food preparation including baking and rum making, available as sulfered or unsulfered , contains about 70% sugar
molasses
____ is valued for its distinctive flavor , it is the sweetener of choice for diabetic patient because of its high fructose content (slower GI motility )
honey
_____ tends to promote rapid browning when used in place of sucrose in baked products
honey
_____ is made from grain sorghum by boiling down the juice to a syrup ; contains a maximum of 30% water ; often used in souther dishes and in the beer industry
sorghum syrup
_____ is a product of maple syrup; is made by further boiling of the syrup until most of the water evaporates and sugar crystallizes out of the syrup
Maple sugar
_____ is the precipitation of crystals form a solution into a solid, geometric network
crystallization
about ____ pounds of maple sugar are produced from 1 gallon of maple syrup
8 lbs
_____ is an equal mixture of glucose and fructose created by hydrolysis of sucrose ; it is sweeter than granulated sugar , available only in clear liquid
invert sugar
________ a sugar of choice for the professional confectioners who desire sugar that yield a smooth, melt in the mouth texture (without gritty texture) ; resists crystallization
invert sugar
_____ are not sugars, however they add high degree of sweetness to food products and commercial applications are growing
alternative sweeteners
Why is there an interest in alternative sweeteners?
the consumers' interest in low calorie foods (designer foods)
____ are foods with increased levels of health promoting substances
designer
What are the 2 groups of alternative sweeteners?
1. polyhydric alcohols
2. nonutritive sweeteners
____ are alcohols with several hydroxyl groups enabling them to be used as sweetener even though they are not sugars
polyhydric alcohols
sorbitol, mannitol, xylitol, maltitol , isomalt, lactitol , erythritol, mannitol, xylitol are examples of _______
polyhydric alcohols
The following are hydrogenized to form alternative sweeteners
sucrose --> __
mannose --> ___
maltose --> ___
xylose --> ____
sorbitol
mannitol
maltitol
xylitol
______ is a list of additives "generally recognized as safe" for use in foods because of long use with no evidence of carcinogenicity
GRAS list
____ have significant commercial applications when used in small amounts; yield less energy than sugars and have other potential health benefits
polyhydric alcohols ; often used in combination with other sweeteners in many foods
Sugar alcohols have ______ (absorbed slowly) makes them more appropriate to a diabetic pt's product
low glycemic response
What is the down side to polyhydric alcohols?
flatulate experience (gas) due to a prolong microbiological action in the intestines result in intestinal discomfort and diarrhea
____ is used in beverages, frozen dairy desserts, baked goods, chewing gum, and candies
erythritol
____ is used in candies, chewing gum, ice cream, jams, and jellies, frostings, beverages and baked goods
isomalt
_____ used extensively in sugar free chewing gum because it does not have cariogenic properties associated with sugar
xylitol
____ is used in various food products ranging from baked products to beverages and as humectant and bulking agent, as well as sweetener, valuble for its water binding capabilities that limits mold growth and enhacing shelf life
sorbitol
______ producing or promoting the development of tooth decay
cariogenic
_____ has a chemical structure similar to fructose, and trehalose is a disaccharide found in mushrooms ; are both used as sweetener in foods and beverages and have potential health benefits
D-tagatose and trehalose
Some alternative sugars have _____ ; promote the growth of healthy bacteria in the GI
prebiotic effects
products containing some polyols can be labeled as ______ but those with D-tagatose and trehalose canoot be labled this way
"sugar free"
_______ are also reffered to as intense sweeteners, very low calorie, or alternative sweeteners
nonnutritive sweeteners
What are the benefits of using alternative sweeteners?
1. offer consumers a way to enjoy the taste of sweetness with little or no energy and or glycemic response
2. nonnutritive sweeteners may assist in weight management, control of blood glucose, and prevention of dental caries
The trend in the food industry is to blend ______ with ________ to create new sweet taste profiles
high intensity sweeteners with other nonnutritive and nutritive sweeteners
Because nonnutritive sweeteners provide sweet taste with the use of small amounts, manufacturers combine the sweetener with a _______ (ex: polydextrose, maltodextrin, polysacchride polyols) to replace some of the functional properties of the nutritive sweeteners
bulking agent
blending the sweeteners create ______ - decreasing the amount of sweeteners needed and improve the overall sweet taste profile
sweet synergy
What are the 5 alternative sweeteners currently approved by the FDA for use in the US?
1. saccharin
2. aspartame
3. acesulfame-K
4. sucralose
5. neotame
_______ are also known as intense sweeteners, defined as those that are substantially sweeter than sucrose by weight
alternative sweeteners
______ is the level of consumption, maintained every day and still safe by a wide margin. Moderation and variety are still recommended
Acceptable daily intake (ADI)
Artifical sweeteners and weight control: much research is still being done and using artifical sweeteners will not automatically reduce energy intake
true
____ is used primarily in soft drinks and as a table top sweetener, rapidly excreted in the urine , does not accumulate in the body, has been removed from list of cancer-causing substances
saccharin
______ general purpose is sweetener, warning about phenylalanine for those with PKU, controversial finding that it may have caused cancer in rats, excessive intake should be avoided by those with epilepsy
aspartame
____ is made from sugar and passes through the digestive tract
sucralose
____ is the most recent on the market , very sweet, phenylalanine is not an issue
neotame
____ is used for foods and beverages , provides less kcals than sugar, high doses can cause flaulence and loose stools
tagatose
____ and ____ are pending FDA approval and are approved in other countries
alitame and cyclamate
____ is the storage form of carbohydrates in plants
starch
_____ is a linear fraction of starch, composed of lgucoe units linked by 1,4 alpha glucosidic linkages, slightly soluble ; weight ranges from a few thousands to as large as 150,000
amylose
starches form various sources differ in the _______
amylose content
_____ is responsible for gelling characteristics of cooked and cooled starch mixtures; any starch high in ___ will gel much better
amylose
____ is higher in cornstarch than wheat starch, higher in wheat starch than potato starch and least in tapioca (17%)
amylose
____ is a polymer of d-glucose (an isomer of glucose) composed of glucose units linked by 1,4 alpha and 1,6 alpha- glucosidic linkages; molecules are dendritic (branching) ; they are non-linear, bushy , and dense
amylopectin
_____ is more abundant in starches than amylose; roots and tuber starches contain 4 times _____compared to amylose(like cassava/tapioca)
cereal starch is nearly 75% ____
genetic variations of starches usch as waxy maize contains virutally only ________
amylopectin
The behavior of starche sin food during preparation and processing is determined by the proportion of _____ and ____
amylose and amylopectin
starch ______ is contribtued to amylose content in a food
gelatinizaiton
Why do starches form different plant sources differ in their ability to gel?
the concentration of amylose and amylopectin in a solution determin the starches ability to hold water. the higher the amylose content the more likely the starch will gel(form a solid structure) when mixed with water and heated. Cornstarch is high in amylose, while potatoe starch and tapioca are high in amylopectin
What test is done to determine the amylose/amylopectin content in food?
iodine test
____ is used in estimating the proportion of amylose to amylopectin in starches

amylose turns blue color when it reacts with helix structures of this starch

amylopectin turns a purplish red color
iodine test
What are the funtional properties of starch?(4)
1. gelatinization
2. gel formation
3. retrogradation
4. dextrinizaiton
Starch can also be _____
modified
___ is the swelling of starch granules and migration of some amylose into the cooking water when starch is heated in water (this is mass transfer) ; characteristics changes = increase in volume, increase viscosity, and translucency of starch granules as starch thickens
Gelatinization
______= to serve as a thickening agent, starch must be dispersed in COLD water and subjected to heat
process of gelatinization
During gelatinizaion, the application of ___ causes hydrogen bonds in the starch granules to break - this even facilitates the entry of water into the starch granule ; this is followed by the movement of amylose molecules into the surrounding water
heat
The removal of some of the amylose (during gelatinization) and the physical spreading out of the remaining amylose and amylopectin (plays a role but not significant) molecules in the granule results in loss of ___________and increased _________
birefringence ; translucence
During gelatinizaiton the _____ of the granule increases as more water enters and forms hydrogen bonds with amylopectin and amylose molecules, the bond water increases the physical size of starch granules
volume
____ is a violent compression inward of starch granules; reduces viscosity of heated starch mixture
implosion
What happens during gelatinization?
starch granules heated in liquid instantly swell, increasing viscosity, Heating beyond the maximum obtainable volume ruptures the starch granules resulting in less viscosity

beyond the heat of 194' F implosion occurs and viscosity is lost
______ is the ability of the starch granule to refact light in two slightly different directions; is depicted by dark corsses under a microscope providing polarized light

ex: teaspoon of flour in water then shake it, the characteristic of starch in cold water, before the thickening happens
birefringence
once gelatinizaiton occurs birefringence _______, indicating a loss of crystallinity of starch , this is seen in raw starch
disappears
_______ a particle transparency occurs in starch mixture as a result of loss of birefringence ; a characteristic of heated starch
translucence
_____ is another term to describe changes occuring in starch as heated in water; occurs when a solution of starch in water is heated beyond gelatinization is between birefringence and translucence
pasting
heating beyond pasting causes starch granular to ______
implode
What is starch gelatinizaiton dependent on ?
amount of water
temperature
timing
stirring
the presence of...
acid
sugar
acid + sugar
salt
fat or protein
and type of starch
in gelatinization , sufficient water must be available to _______ and _____ - it must be done in COLD water
dissolve starch and for absorption
In gelatinization, the amount of liquid needed for absorption depends on the concentration of _______ and _____ in the starch
amylose and amylopectin
When preparing starchy foods such as grain or pasta, sufficient water is added to cover and then more for evaporation and two to three time expansion in volume
true - think what is done when preparing rice
most starches gelatinize at a temperature between _________
133 'F and 167 'F
Starch gelatinize within a narrow temperature range known as ________ ; the higher the amylose content the higher the temperature needed
transition temperature
continuous heating causes starch granules to break apart, stresses the bonds holding them together and subsequently the rupture of the granules (implosion) and decrease in viscosity
timing effect of gelatinization of starches
starches should be constantly ______ to avoid clumping
stirred
a pH below ____ decreases the viscosity of a starch gel
4
any acidic fruit juices should be added to pie fillings or salad dressings ___________
after gelatinization is complete
to maintain viscosity in canned high-acid foods, commercial food processors use _______
modified starches ; these are chemically altered

read more on this in the book, missing information
Learn the nature of table 20-2 in the book dont need to memorize
read in book
_____ are commonly used as thickeners in products such as desserts and sauces with high sugar concentration
starches
What are the 5 things Sugars tend to do during starch gelatinizaiton?
1. compete for water with starch in a mixture because of its hygroscopicity
2. increase translucence of starch paste
3. reduce paste viscosity and gel strength
4. increase gelation temperature (delay or inhibit complete gelatinization)
5. sugars differ in their ability to delay gelatinization with the following sugars having greatest impact( fructose, glucose, and galactose have less effect compared to the disaccharides)
read in book the affect sucrose has on starch gelatinization
read in book
Increased levels of sugar and acid substances (like lemon pie) lead to _____ and _______; meaning that sufficient heat must be applied to ensure complete gelatinizaiton and maximal thickening
increased viscosity and lower gelatinization temperature
in the food industry cross linked starch is used because of its _________
resistance to hydrolysis
_____ preserves the integrity of the gelatinized starch before it ruptures and increases the viscosity of the paste at is maximum peak
salt
______ delays gelatinization by coating the starch and prevents it form absorbing water
fat or protein
_______ are less mucilaginous when made into gelatinization starch pastes than root starches
cereal starches
_____ is the corn starch of choice for thickening, particularly when translucency of the paste is not a concern
corn starch
______ tends to produce stringy texture with translucent paste (unsuitable as a thickening agent for a gel but it can thicken to a flow point)
waxy corn starch
____ in the formation of a gel
gelation
____ is a colloidal of a solid dispersed in a liquid , have flow properties, which amy range form fluid to extremely viscous, the higher the temperature the greater the flow rate, the higher the concentration of the solids in a ____ the more viscous the ___
sols
_____ is solid matter and liquid, water is the dispersed phase and starch is the continuous phase, the solid in the ___ is sufficiently concentrated to provide the network needed to prevent the flow of the colloidal system
gel
in _______, sol or paste is formed by hydrating and dispersing the starch molecules in cold liquid with the application of heat
gelation
in a sol _____ is the dispersed phase, and _____ is the continuous phase
starch, water
in ________, amylose molecules that migrate into the liquid during gelatinization are free to move about in a starch phase; as paste cools, energy is lost and amylose molecules attempt to move together forming a network that holds water in the rigidily bond starch granules ; there fore starches lacking amylose( such as waxy starches) do not form gels in normal concentration
gel formation
What should be done to maximize gel strength? (3)
1. allow starch gel to cool without disturbances
2. agitation during gelling disrupts established hydrogren bonds and weakens the gel
3. if butter of flavoring were to be added, add immediately after removing the paste from the heat; then allow the mixture to cool without disturbance
______ occurs as amylose molecules come together in a gel resulting in squeezing out the free water form the gel after extended storage time or a cut is made ; when this happens the integrity of the item is compromised
syneresis
_______ is a gradual increase of crystalline aggregates in starch gels during storage
retrogradations
______ results from amylose rearranging itself in an orderly fashion upon cooling ; this is the difference between fresh baked foods and baked goods
retrogradation
____ plays a larger part in retrogradation
amylose vs amylopectin
When you toast bread what happens?
reverse retrogradation
_____ is perceived as a gritty texture on the tongue
retrogradation
what are examples of retrogradation?
a starch thickened pudding held in the refrigerator for a few days and bread
review figure 5.8
functional properties of starch
_______ is the breakdown of starch molecules to smaller, sweeter tasting dextrin molecules in the presence of dry heat of uptake of one molecule of water whenever cleavage occurs
dextrinizaiton
explain the process of dextrinizaiton
starch is heated without any added water, the temp rises beyond the maximum level attainable in starch and water mixture; starch molecules splits at one or more of the linkages between the glucose units (degradation) ; shorter molecules of starch of varying lengths are formed(dextrins)
_____ are less viscous
dextrinized starches
When browning meat covered in flour, making roux or gravy and sauces,
examples of dextrinizaiton
How do you make a healthy gumbo?
heat flour in the oven to brown without the added fat
if you ________ your starch before cooking gelation will not occur
dextrinize
a small amount of starch are called __________; they are not digested in the small intestine and therefore do not contribute to calories
resistant starches
What is the advantage of toasting your bread?
the brown part becomes resistant starch
What are the 3 types of resistant starches?
1. inaccessible starch
2. resistant starch granules
3. retrograded starch
_____ trapped in food prevented from gelatinizing
inaccessible starch
_____ indigestible because of their chemical configuration
resistant starch granules - read more in book
____ are formed when heating/cooling starch renders molecules of amylose and amylopectin
retrograded starch
_____ is the rough outer covering protecting the grain; ex: in legumes this is the outer coating
husk
___ is the hard outer covering just under the husk that protects the grain's soft endosperm
bran
____ is the largest portion of the grain, containing all of the grains starch; reservior of carbohydrates in plants
endosperm
____ is the smallest portion of grain, and the embryo for a future plant; responsible for germination
germ
review figure 21-1 in book
reivew
natural occuring starch souces include all plant sources , T or F?
true
two major forms of naturally occurring starches are ___and ___
cereal and root starches
____ are corn, wheat and rice
cereal starches
_____ are potatoes, arrowroot, cassave (tapioca)
root starches
other starch sources are dried beans, peas, sago palms
true
Legumes are not processed to obtain starch for use in food preparation; they are eaten as the whole seed because the contain ______________
other nutrients, espeically protein
Waxy starch are mainly made of _______; made to avoid amylose completely , they do not gel! primarily developed to thicken but not desirable gel agent
waxy starch ; almost 100 % amylopectin
____ are useful in fruit pie prepartion and othe rproducts in which thickening is desirable without the gelling
waxy starches
____ are chemically or physically altered to create a unique starch
modified starches
Modified starches may affect the starches ?????
1. gelatinization
2. heating times
3. freezing stability
4. sold water solubility
5. viscosity
What are 3 examples of modified starches?
pregelatinized starches
thin - boiled
oxidized starches


read in book - missing 5 bullets
_____ do not have to be heated in water to expand and gel; have already been cooked and dried, so absorb cold water immediately and expand; used in instant dry mix pudding, gravy, and sauces
instant or pregelatinized starch
_____ has to be modified to be effective as a thickener
tapioca starch
processed or modified tapioca is called ______
pearl tapioca
______ consists of partially gelatinized starch, dried into pellets - so hard that they require overnight soaking to use; is less mucilaginous when made into gelatinized starches pasts
pearl tapioca

ex: of pre-gelatinized starch
________ Pregelatinized starch made primarily for microwave cookery
Cold Water Swelling starch
• An acid hydrolyzed starch by using weak hydrochloric or nitric acid to debranched amylopectin at the 1, 6, alpha glucosidic linkage
thin-boiling starch (ex of modified starch)
What are the characteristics of thin-boiling starch?
• More soluble and less viscous
• Forms thin sol when hot but strong gel when cold
• Used for making gumdrops
• Exposed to chemical oxidizers
• Less viscous than cross-linked, but clearer and more useful as stabilizers and thickeners
• Has a powder-like consistency, which makes it ideal for dusting foods (e.g., gum)
oxidized starch
one of the more commonly used modified starches- treated with ethylene or acetic anhydride to link the starch molecules together with crossbridges
• Cross linking makes starch more heat resistant
• Improves stability
• Effective thickening agents and forms gels that undergo very limited retrogradation
• Useful as thickeners and stabilizer in salad dressings and related products
• Ideal for use in cooked or canned foods such as pizza, spaghetti, cheese, barbeque sauces, pie fillings, bakery glazes, and puddings
cross linked starch
• A derivative made by reacting starch molecules with tripolyphosphate or other phosphate to achieve a thickener with excellent stability and clarity
• Characteristics:
• Less viscous than crosslinked
• Improved stability
• Form smooth, nonstringy pastes and gels
• Do not undergo syneresis
• In a packaged by this starch would be most appropriate b/c the amylose and amylopectin will not have the opportunity to come together and squeeze water out
starch phosphates
characterized by the formation of porous spheres when spray dried with small amount of bonding agents- i.e. Amaranth starch
• Characteristics
• Serve as flavor carriers in selected foods
• Absorbed a flavor up to 60% of their weight
• Without protective coating, flavors can be preserved over several months
spherical agregates
What is the criteria for starch selection?
➢ Starch selection depends on the desired use
• Thickener needed to produce low-calorie products
➢ Select starches that form strong gel
• If mouth feel is an important consideration
• Syneresis can be a problem in freeze-thaw products
➢ Select starches with freeze-thaw stability are desired (waxy rice flour)
➢ Freeze-thaw stability
• Freeze-thaw stability is the ability of a starch-thickened product to be frozen and thawed without undesirable loss of quality-(gritty crystalline texture)
• Waxy rice flour is a useful starch for products to be frozen and thawed
• Purified rice starch is not as effective as waxy rice flour, but better than corn and wheat starches for freeze-thaw stability
➢ Retrogradation is a problem when starch-thickened product must be refrigerated for storage (i.e. pudding)
➢ Starches that retrograde easily will quickly develop a gritty texture that is noticeable on the tongue
➢ Use cross-linked starches
• Resistant to retrogradation
➢ Other considerations:
• Marketing stresses-
• Influence the strength of a starch gel such as in pudding or pie filling
• Product appeal-
• Influenced by the flow characteristics of starch-thickened sauces and other sols rigidly of gels needs to be suited to consumer expectations
plants provide variety in the food supply including ______ and ________
gustatory (sense of taste) and beautiful colors
_____ increases the demand for fruits and vegetables
nutrition
_____ and _______ increase demand for fruits and vegetables
disease prevention and enhancement of optimal health
True or False? There large market for both fruits and vegetables as well as in cans, frozen items and or dried
true
_____ contribute uniqueness among vegetables
legumes
_____ are not traditionally considered foods, however they are becoming increasingly popular as garnishes color and flavor accents
edible flowers
Fresh herbs commonly available in the produce section of the groceries include basil, dill, oregano, parsley, rosemary, sage, tarragon and thyme. are used as _______
flavoring agents
Fresh herbs can be substituded for dried by using about ____ times more of the fresh herb.
8 times more
Fruits and vegetables are made up of ____and various types of _____
tissue systems and cell walls
___ are the building blocks of plant and animal organisms
cells
The cells vary from plant to plant and there is noticeable differences between the ____, ____, and ____ plant foods at different stages of maturity
underripen, ripe or overripe
What are the 3 tissue systems of fruits and vegetbales?
1. dermal tissue
2. vascular system
3. ground system
____ represents the skin or ring of the fruit or vegetables, protective covering of the plant
dermal tissue
____ is within the dermal tissue of the fruit or vegetable, responsible for transporting fluids, nutrients, and waste products
vascular system
_____ the most varied component of plant structure ; consisting of parenchyma cells and other supporting tissues such as collenchyma and sclerenchyma cells
ground system
_____ are the principle cells in fruit and vegetables, most abundant type of cell in the ground system ; within the cytoplasm of the cells - they are compounds responsible for the plant's starch content, color, water volume, and flavor
parenchyma cells
_____ are aggregates of elongated cells (ex: those fibrous stands of celery), chewy and resistant to softening when cooked , one of the supporting tissues because it contributes to the overall structure of the edible part of fruits and vegetables containing _____
collenchyma cells
______ are cells of interest in foods because, these wood-like cells are associated with the gritty texture of some plant foods ; the unique texture of pears, is the result of the presence of sclereids a type of ____cell; sclerids and other types of _____ are collectiely callerd fibers, with thick cell walls containing lignin
sclerenchyma cells
_____, _____,and ______ form the structural component of the plant cell walls
cellulose, pectic substances, and hemicelluloses
______ occurs naturally in all vegetables, fruits and legumes. Can be extracted from wood pulp or cotton and used in foods as anticaking, thickening and texturizing agents in food processing
cellulose
_____ is a glucose polymer but unlike amylose its glucose units ar ejoined by 1,4 beta-glucosidic
cellulose
The structural differences between cellulose and starches is responsible for textural differences and also the inability of humans to _______________
digest/use cellulose as a source of energy
Cellulose molecules is capable of aggreagting into _________; a cluster of these occur in some fibrous vegetables
fibrils with crystalline structures
______ heterogeneous group of polysaccharides component of plant cell walls; some are soluble in acid while others are insoluble ; are sensitive to alkaline cooking mediums
hemicellulose
What effect does does alkaline cooking medium have on hemicelluloses?
addition of alkaline such as baking soda causes this component of plant cell wall to disintegrate and become flaccid or mushy when heated in cooking water
_____ is responsible for the unacceptable softness in vegetables and fruits cooked in alkaline medium
hemicellulose
the destruction of ______ is an important consideration discouraging the use of soda in cooking vegetables especially legumes -a good source of the vitamin
thiamine
______ is the term describing a group of polysaccharides found in vegetbales, grains, legumes, and more significantly in fruits
pectic substances
in the cell wall pectic substances combine with ______ to reinforce the structural contribution of cellulose
hemicellulose
What are the 3 pectic substances?
1. protopectin
2. pectin (pectinic acids)
3. pectic acid
What are the functions of pectic substances? (3)
1. act as cementing substance between cell walls
2. partially responsible for the plants' firmness and structure enabling them to trap water and form a gel
3. contribute significantly to the textural changes as fruits mature
_____ are used commercially to contribute to the gelling of fruit preserves ; the string like pectin molecules bond to each other under the right conditions to form a net-like structure that is able to trap water and form a gel
pectic substances
____ is found between the plant cells and within the cell walls BUT not in the juice
pectin
Commerical sources of ____ include the pulp (pomade) remaining after apples are pressed for juice and the sponge albedo of citrus fruits
pectin
____ is the white inner rind of citrus fruits, which is rich in pectin and aromatic cells
albedo
_____ is a long polymer consisting primarily of galacturonic acids units joined by 1,4 alpha linkages
protopectin
______ is a water insoluble form of pectic substances found in immature/unripe fruits and contributes significantly to the firm texture of unripe fruits
protopectin
as fruit ripens , enzymes (pectinase) convert ______ to a more water-soluble ______ by random demthylation and hydrolysis along the ______ molecules
protopectin, pectin , protopectin
The degree of ripening and softening of fruit is related to the _________, (how many substances were degraded)
degree of demethylation
as fruit ripens,some demethylation and hydrolysis randomly take place along the _________
protopectin molecules
When only a limited amount of degradation has occurred the pectic substances are termed ______
pectins
_____ are galacturonic acid polymers in which most, if not all of the acid radicals have been esterified with methanol
pectins
pectins are valued for ________ properties in making jams and jellies; it is the pectin extract from ripe fruits that is used to gel jam and jellies
gel-formation
as additional demethylation and hydrolysis continues ______ are formed
pectinic acids
______ are galacturonic acid polymers in which between 25% to 50% of the acid radicals have been esterfified with methanol ; form of pectic substances are formed as fruit begins to soften just a little
pectinic acids
If a pectin moleculeis esterified completely ( i.e. all orgnaic acid residues are altered to methyl ester) - the pectin will contain a littler more than 16% methoxyl groups . This is called a ________
low methoxy pectinic acid
most pectins contain fewer than 16% methoxyl groups
true
________ contain methyl ester on no more than every 1/4 unit and frequently only about 1/8 of galacturonic units are esterified
low methoxyl pectinic acid
______ are the form of pectic substances found in fruit that is just beginning to ripen ; forms gel readily with little addition of sugar- valueble in making dietetic jellies and jams
low methoxy pectinic acid
____ is the smallest of the pectic substances ; lacking methyl esters
pectic acids
As protopectin acids become devoid of methyl esters, the molecule gradually become shorter and the fruits become _______
overly soft
_____ is found in overly ripe , very soft fruit and vegetables
pectic acid
____ is found in immature fruit and does not gel
____ is found in ripe fruit and gels
____ is overripe fruit and does not gel
protopectin ---> pectin --(pectinic acid)--> pectic acid
What does the food industry use pectin as?
emulsifier, stabilizer , thickener, texturizer
Why does cloudiness occur in juices?
when juice is extracted from fruits, pectic substances can somewhat cause cloudiness; Cloudiness is desirable in organe juice, where it contributes to the body BUT undesirable in some other juices including apples ;
cloudiness in juices is removed via _______
clarification process
_____ is when an enzyme such as pectinases are added to juice to break down pectin compounds that contribute to cloudiness
clarificaiton process
____ and _____ also break down cellulose and hemicellulose the cell walls, respectively to release more juice
cellulase and hemicellulase
_____ is a non carbohydrate polymer of many aromatic structures linked together to form an extremely large complex molecule that gives a woody quality to plant foods
lignin
as plants mature, lignin deposits with hemicellulose in cell walls to form tough ____________ ex: asparagus stalks
woody vegetables
Since the woody desposits are insoluble in water and connot be softened by cooking , it is always _______
discarded
_____ are responsible for the browning and bruising that often occurs in ripening fruit
phenolic compounds
____ are found mostly mostly in unripe fruits, giving them a bitter taste and leaving astringent in mouth
tannins
some fruits that contain _________ are apples, apricots, avocados, bananas, cherries, dates, grapes, nectarines, papayas, peaches, pears and strawberries
phenolic compounds
The tissue of fruits and vegetables when exposed to air ________
quickly darkens
The phenolic compounds promote oxidative browning in the fruits and vegetables resulting in the formation of brown or gray black pigment called ___________
melanines
Phenolases are found in high amounts ____.
potatoes, mushrooms, apples, peaches, bananas, avocadoes and tea leaves
What are the 3 ways to prevent oxidative browning ?
Maintaining an acid pH , Reducing contact with oxygen , denaturing enzymes
As fruits and vegetables mature what 3 things happen?
1. cellulose and hemicelluloses content increase
2. fruits and vegetbales become less tender
3. increased levels of lignins - resulting in tough woody texture primarily in vegetables
Pectic substances undergo ________ (catalyzed by protopectinases) and _______ (catalyzed by pectinesterases) ; fruits progress from hard and firm texture to soft or even mushy texture
hydrolytic cleavage and deesterification
All synthesis of organic compounds stops after harvesting but _______ continues
physiological changes
Bulbs, roots, tubers, and seeds become ______ during storage
dormant
The fleshy tissues of fruits and vegetables undergo ripening and continue to _______
senescence
______ is accumulation of metabolic products, increase respiration , and loss of moisture in plant foods after maturation
senescence
_____ is greater in perishable fruits and vegetables ; those plant foods high oxygen consumption and carbon dioxide production are the most perishable
respiration rate
rate of respiration can be delayed by _________
refrigeration
What is the effect of respiration on starch/sugar?
1. rapid rate of respiration in corn increases starch desposition at the expense of sugar stores (Ex: freshly harvested corn is sweeter compared to days after harvesting)
2. the sugar in fresh harvested peas and other legumes deplete rapidly during respiration
_____ is the period of maximum respiratory rate just before many fleshy fruits fully ripened
climacteric
______ continue ripening after harvesting - eX: bananas and peaches, apple, pear, tomatoes, etc.
climacteric fruits
______ such as grapes and oranges do not respirate rapidly and ripened after picking therefore needs to be harvested when ripened
non-climacteric fruits
Enzyme levels increase during _______ (including lipase, pectic enzymes, invertase, chlorophyllase ,and peroxidase)
during storage
The increase in enzyme levels contribute to _____________
deterioration of harvested fruits and vegetables
_______ is involved in accelerating ripening and early sensence of fruits during storage
ethylene gas
to control ripening , ______ is bubble into prematurely harvested fruit
sythetic ethylene
Other enzymes include hemicellulases and cellualse can promote the release of ______ from the complex polysaccharides constituting of the cellw all
sugars
Increased hemicellulases and cellulases activties results in the release of complex polysaccharides components of cell walls this makes ____________
ripened fruits sweeter
Starch in fruits is gradually converted to sugars by ________
amylase promoted reactions
Invertase enzyme converts naturally occuring sucrose to inverted sugars (gluose and fructose) - promoting ___________
further fruit sweetness
In potatoes, the enzyme phosphorylase promotes the conversion of _________
starch to sugar
When potatoes are held between freezing and 10'C there is increase ________
conversion of starch to sugar
potatoes stored at this temperature (10'C) tend to ________ , ______ and ______
brown excessively, taste sweeter, and less crispy when fried
To prevent accelerated conversion of potatoes starch to sugar and the undesirable effect, potatoes should be stored ______________
above the active temperature range for phosphorylase
In starch containing vegetables such as legumes and carrots , synthesis may continue to occur if stored at about _____________
normal room temperature
To prevent further starch synthesis, _______ should be used
refrigerator storage
Significant textural changes occur when fruits and vegetables are subject to heat including what 4 processes?`
1. gelatinization
2. loss of turgor
3. structural changes
4. osmosis
corn and dried beans are vegetables but becuase of their high starch content, they undergo _________ during preparation
gelatinization
____ is a distension of the protoplasm and cell wall of a plant by fluid content
turgor
When heat is applied (steamed) to spinach and other greens, the cell walls become permeable causing __________
loss of water and loss of turgor
______ is evident by the wilting of the leaves and accumulation of water from the cells in the bottom of the pan
turgor
Pectic substances become more _______ as a result of chemical changes
soluble
HEmicellulous becomes softer as vegetables are heated:
Acids ___________ of hemicelluloses
Alkali ______ of hemicelluloses
slows the softening

accelerates softening
_____ is the movement of solvent through a semipermeable membrane to the side with the higher solute concentrations
osmosis
The _________ of cell walls of fruits allowes water to pass through (but not solutes such sugars or minerals)
permeability
APplication of ______ destroys the cell memrbanes and break the barrier, allowing solutes to pass freely across the membrane until solute concentraions are euqal on both sides
heat
Heating fruit in water causes the natural sugars in fruit to __________________
migrate into the water and water moves from outside into the fruit, resulting in the loss of shape
To prevent loss of shape what should be done??
add small amount of sugar to the cooking water; less fruit sugars move into the cooking water and fruits tend to retain the shape and firmness
____ and _____ also help to firm cooked fruit
calcium salts and acids ; a reason why calcium is added to many canned fruits and vegetables
What is the effect of calcium on the textural changes during preparation?
calcium delays the softening of vegetables as a result of calcium ions reaction with pectic substances in the middle lamella ; calcium pectinates or pectates is formed, preciptating calcium ion, which add rigidity to vegetable structure
Adding calcium water or cooking vegetables in hard water tend to __________ to vegetable the structure
add rigidity
Adding molasses to cooked legumes have similar effect of increasing _______ because of the calcium content of molasses
rigidity
What is the recommended procedure for preparing legumes with added calcium?
cook or soften legumes to the desired level before adding molasses to prevent insoluble calcium-pectinates and pectates formation, which cause a significant delay in softening
What is the effect of added salt on textural changes during prepartion?
dried beans have a hard outer covering that requires soaking beans before cooking.
DO NOT use salt in the soaking water because it makes the outer surface of the beans more resistant to water penetration during cooking
What are the effects of Added salt?
1. a 2-minute boiling period before an overnight soaking is encouraged to inactivate enzymes and avoid possible souring during an overnight soaking in cold water
2. a quicker alternative is to boil the beans for 2 minutes, soak for another hour, and simmer until done
3. Addition of alkali such as 1/8 tsp of baking soda to about 3 cups of water will reduce the cooking time by about 33%, however, this cooking method results in loss of thiamine
Vegetable and fruits are clothed in array of colors - an important attribute for meal planning and plate presentation .
true
What are the 3 plant pigment categories?
1. caretenoids (yellow organe)
2. chlorophylls (Green)
3. flavonoids
both carotenoids and chlorophyls are ______
fat solubles
the _____ are water soluble and have tendency to be lost in cooking water
flavonoid pigment s
What are the 5 pigments of ccarotenoids?
carotene(yellow-organe)
lycopene(red-organe)
xanthophyll (yellow)
lutein
zeaxanthins

ex: carrots, organges, peaches, pineapples, pink grapefruit, red and yellow pepers, tomatoes, watermelon, winter squashes
What are the types of chlorophylls?
cholophyll a (blue green)
chlorophyll b (green)

broccoli
green cabbage
kale
lettuce
spinach
What are the flavonoids??
anthocyanin(red purple)
eggplant radish red cabage red potato

anthoxanthin (cream/white)
cauliflower
onions
rice
turnips
white potato

betalains (purple red/yellow)
beets
_____ are responsible for the green color of plants ; promote photosynthesis; comprised of large molecules with a magnesium atom at the center of the ring structure ; fat soluble
chlorophyllls
____ is a process by which leaves capture the sun's light energy to covert CO2 and water to carbohydrates
photosynthesis
___ has a methyl group attached

___ has an aldehydge group atached instead
chlorophyll a

chlorophyll b
_____ is done as part of the preparation for freezing enhances green color because of the expulsion of air from the intercellular spaces
blanching
What are the effects of blanching for chlorophyll?
the color is retained during freezing and the subsequent boiling prior to serving the vegetables
___ is means used for preserving green vegetabels
canning
___ are unstable in the presence of heat
chlorophylls
_____ intensifies the bright green of chlorophyll as air is expelled
heat applications
Continuous heating slowly transform pigments from bright green to an unattractive _______
olive green (drab ) color
When fruits and vegetables are heated in the presnece of acid (ie acetic and oxalic acids) the cells are disrupted and ____________
organic acids are released from the cell sap
When fruits and vegeabtles are heated in the presence of acid, acids then replace the _______ at the center of chlorophyll with 2 atoms of hydrogen
magnesium atoms
What compounds are formed during heat applied in the presnece of acids to fruits and vegetables?
pheophytins ( an irreversible color change)

ex: the olive green color canned spinach is a good example of the color change that occurs
The effect of acid on chlorophylls pigment can be prevented by ______
adding alkali (ie baking soda)
Rather than forming pheophytin, the chlorophyll retains Mg at the center of the molecule, phytyl group is split off and a ______ sodium salt is formed what does this created?
sodium salts; chlorophyllins
Chlorophyllin is a water soluble compounds with a _____ color ; the cooking water turns green as the pigment is leahed out
bright green color
In the presence of ____and ____ , chlorophyll pigments turn to a bright green color
zinc copper
For the best result, cook greens how?
uncovered and as fast as possible
______ along with lycopenes and xanthophyll account for most of the yellow organce and some of the red color of fruits and vegetables
carotendoids (alpha and beta)
_____ lend redding organce color to carrots and winter squashes
carotenes
__ and ___ account for most of the red color and fruits and vegtables
xanthophylls and lycopenes
____ is a deeper red color, providing the bright color of tomatoes
lycopene
heat may modifty carotenoids pigments strucutre - ordinary cooking methods have _____________ effect on the color or nutrition value
little or no effect
exposure to oxygen causes ________ of carotenoid pigments resulting in loss of color
oxidations
_____ are not significantly affect by acid, alkali, volume of water or duration of cooking
carotenoids
_____ are a group of more than 4000 water-soluble pigments with 2 types; anthocyannins and anthoxanthins ; most are glycosides - having molecules of sugar attached
flavonoids
_____ occur alone in light colored vegetables such as potatoes, yellow skinned onions, and cauliflower or with other pigments such as anthocyanins
flavnoids
_____ are responsible for most of the red , purple and blue colors of fruits and vegetables such as color of cherries, red apples, varioues berries, blue and red grapes, pomegranates, radishes, eggplant , poatoes, red cabbage, and predpotoat skins, rasberries
anthocyannins
____ intensifies the red color of anthocyanins
at a _____ the pigment is violet in color; _____ changes the reddish blue hue to an unappetizing blue and then to green
acidic tap water; neutral pH , alkaline water
_____ from knives or containers made of iron, tin or aluminum turns anthocyanins pigments to off-color ; stainless teel and glass are the best choices of cooking utensils for the prearation and store anthocyanins rich foods ; enamel lined canes are used for food containing anthocyanins to prevent contact with the tin
metal ions
____ are composite of compound known as flavones, flavonols, flavonones and the proanthocyanins ; they are responsible for the cream or white color of cauliflower, onions white potaotes and turnip
anthoxanthins
What is the effect of acids on anthoxanthins?
in acidic medium, anthoxanthins pigments become colorless or white; few drops of juice , vinegar, or a pinch of cream of tartar added to anthoxanthins rich foods after cooking keep the pigment snow white
What is the effect alkali on anthoxanthins?
in an alkaline medium ,anthoxanthin pigments turn to an undersirbale yellow color, white foods such as rice, poratos cauliflower and onions have yellowish cast when cooked in alkaline water
___ are is not significantly affect by heat; with pigment reacts with iron and copper to form a blue black and a reddish brown color; tin and aluminum cause it to turn bright bellow color
anthoxanthins
____ is a water soluble biolet red pigment with limited use as a food additive( gives beets their dep purplissh red color) ; acidic ingredients concert the purplish red hue of beets to brighter red; in an alkaline medium the red color shifts to yellow; it turns brownish in the presence of metals such as copper and iron
betalin
____ is the combination of materials in foods that can not be digested readily by man ; a variety of compounds comprise dietyar fiber
fiber
most fibers comprise of 1, 4 beta linkage which make them _________
resistant to digestion by humans; humans lack the enzyme needed to break the 1,4 beta linkage
_____ are viscous and include some hemicellulose, pectin, gum, and mucilages

___ are non viscous and include lignin, cellulose, and some hemicellulose
soluble dietary fibers

insoluble dietary fibers
_____ are described by their sources than than their chemical or physical proerpties
dietary fiber
Dietary fibers are described as fiber that occur

1.
2.
3.
4.
1. naturally in intact plants
2. functional fibers
3. resistant starches
4. total fibers
_____ are fibers extracted from plant or manufactured and have health benefits
functional fibers
____ are starches that are not digested in the small intestine and therefore enter the large intestine intact ; they act as fiber to promote GI motility and also undergo limited digestion to yield some energy ; is useful in formulating food products for the large market of consumers seeking reduced calories and more fiber in their diets
Resistant starches (RS)
___ refers to the sum of dietary fibers and functional fibers ; was created to accommodat ethe labeling of product that may contain new fiber sources iwth potential beneficial effects
total fiber
What are the benefits of fiber? (4)
1. plant foods ar evalued in the diet as a significant source of fiber
2. both soluble and incolsuble fibers ar efound int he same food but in different proportions
3. soluble fibers are digested to a limited extent by intestinal bacteria
4. insoluble fibers are excreted undigested- thus providing no energy but increase the bulk of the stool
citrus fruits oat and legumes are excellent sources of ______ while vegetbales are valued for their content of ______
soluble fibers

insoluble fibers
_____ in oats (beta-glucan) helps lower blood cholesterol; this characteristic of oats has elevated oat containing product to a higher level - allowing health claim on its lable
soluble fiber
product contianing _____ from ____ (a water soluble gum) can make a similar health claim as oat
psyllium from psyllium seed husks
____ are made with oat bran, flavorings and seasonings suitable for incorporation into ground meat
fat replacers
____ can be blended with low fat ground meats to produce cooked patty containing only 10% fat
bran products
___ enhances the water tention/adhesion ; the finished patties are juicy m flavorful, and ahve acceptable moutfeel ; also used in bread to about 15% of the flour without sensory change
bran
dietary suuplemetn industries are not regulated by the FDA ; true or flase?
true
the 1994 dietary supplement helath and educaiton act(DSHEA) limits the ________
FDA authority over dietary supplements
under DSHEA, the FDA can only prove that dietary supplements are unsafe ________
after the supplemtns are int he market
___ are complex carbohydrates found in plants ; they are hydrophilic in nature - called hydrocolloids ; they are large molecules of monosaccharides units linked together by glycosidic linkages ; they undergo litttle digestion in the small intestine and are classified as soluble fiber
gums
the monosaccharide components of _____ are varried widely compared to the energy -yielding disaccharides and the glucose polymers (dextrins and starch )
gums
What are the characteristics of gums?
1. remarkable ability to attract and bind water
2. contributes very limited calorie because of the limited digesiton and absorption
attention is focused on gums as possible ____ because of the potential nutritional and health benefits when incorporated into food products
additives
The _____ of gums increases stool bulk until digestion of gums in the large intestine occurs
water holding capacity
Gums are digested and absorbed _____ compared to sugars and starches ; one of reasons why they are used in low calorie food products (target at weight concious americans)
inefficently
agar, guar gum, gum arabic and pectin provide between _____ caloires per gram
1-3
cartageenan and xanthan gum provide at the most a calorie pergram
true
___ have the potential to protect agianst caner
gums
Gums are valued as ___ and ____
thickening agents and fat replacers
____ is the ability of a liquid an dsemiliquid to flow
viscosity
compative viscosity allows smaller amount to be used for thickening compared to starch; low calier adnatage to starch and sugar
gum as a thickening agent
his attributes that mimic fat and oil in food; substantial kcal reduction when used as fat substitute ; used in salad dressings to provide appropriate thickening in place of some of the oil ordinarily
gums as fat replacers
gums in ____ mimic fat and improve mouthfeel; aggregation of ice crystals in this are blocked when gums are added producing a fine textured product
ice cream
in cakes __ extended shelf life , delay staling, enhance cell structure, increase volume when used in the appropriate amount
gums
in beverages ___ are added to increase the fiber content of foods and beverages
gums
____ is a complex fructooligosaccharide derived from the roots of chicory ; it is a soluble fiber - not digested until it reache the large intestine where some bacterial digestion occurs; it is also an ingredient of interest in the creation of functional foods
inulin
____ shown to promote absorption of calcium and magnesium and decrease cholesterol and serum lipids
prebiotic (inulin)
_____ stimulates lactobacilli and bifidobacteria in the color, which helps to combat possible harmful microoganisms and and promote health
gum- inulin
___ lacks flavor so it can be incorporated into product without introducint detrimental overtones; and it contributes to a pleasing mouthfeel when used in table spreads, yogurt, frozen desserts, and dressings; it can be added to breads and other baked products at levels high enough to be of merit in increasing fiber intake
Inulin as a versatile food ingredient
What is the food industry application of inulin?
to develop, modify fat and sugar products that meet consumer's increase demand for fewer calories per product
___ are carbohydrates derived from seeds, plant exudates , seed weed extracts, and microorganisms
gums
gum sources as a group are called _______
hydrophillic polysaccharides
Gums of primary commercial significance from seeds derived from guar and locust been (carob) classified as _____
legumes
Gums from ________ are gum arabic, tragacanth, karaya, and ghatti ; gum arabic is most commonly used
plant fluids - oozing liquid from cuts in tropical trees
The red and brown algae (irish moss and giant kelp) provide ____, ___, and ____
agar, carrageenan and algin
The most successful of the microbe fermented gums is _________, produced when microorganisms Xanthomonas campestris ferment glucose in the presence of some trace of elements
Xanthan gum
What are common attributes of individual gums?
1. they are polysaccharides in which glucose is ususlly absent
2. galactose is common to seed, plant exudates and seaweed gums but not algin
guar and locust beans coomposed primarily of __ and ___ linked together by a 1,4 beta linkage with 1,6 alpha linage at regular interval
mannose and galactose
___ has twice as much galactose as does locust bean gum
guar gum
____ requires heat for maximum hydration while guar gum hydrates in cold water
locust bean gum
____ include gum arabic , tragacanth , karaya and ghatti ; are oozing liquids from cuts in tropical trees; strucutrally they are less orderly and have other ocmpounds other than polysaccharide polymers
plant exudates
____ are rich in galactose (often with sulfate ester) - includes agar, carregeenan and algin
seaweed extracts
____ forms strong and transparaent gels which are reversible when heated and reform when cooled again
agar
____ occurs in various fractions , some form gels and some do not gel
carrageenan
____ has ability to interact with protein to promote stabilization of various milk products including ice cream process cheeses and chocolate milk
carrageenan
_____ has the ability to interact with protein to promote stabilization of various milk products including ice cream process cheeses and chocolate milks
carrageenan
___ is used to form both gels and films ; mannose and gulucronic acid are the prinicple components; in addition, they contain numerous salts resulting from the presence of sodium, potassium and ammonium ions
algin
___ are fermentation produced polysaccharide gums including xanthan and curdian ; fermented by colon bacteria
microbial exudates
___ was approved by the FDA in 1996 and marketd as Pureglucan ; it forms a gel that is stable under freezing and retorting
curdlan
___ is the starting material for the produciton of most synthetic gums
cellulose
Because of the potential nutritionla benefits of adding fiber to various food products, many foods currently are formulated with ___ to replacec part of all of traditional functional ingredients such as starch or fat
gums
____ is a soluble fiber and is will suited for liquid foods such as soups
gum arabic
__________ a soluble fiber can be used alone or in conjuction with gum arabic to increase fiber content of a food
carboxymethylcellulose (CMC)
The _______ of both gum arabic and CMC makes it possible to use comparatively high levels without developing a gritty texture in liquid foods
high degree of solubility
Guar gum and locust bean gums can replace ___% of the starch in thickening thus reducing calires in the food
50%
____ is used successfully as a thickener in salad dressings
xanthan gum
Different starches and various polysaccharide gums are used in commerical foods and define the __________ - ranging from liquids (soups and sauces to bakery products) to snack foods
textural attributes of foods
In product development, to meet a defined need of the consuemrs, starches or gums are used to do what 5 things?
1. improve acceptability
2. meets processing requirements
3. repleases or bind flavors appropriately
4. improve shelf life stablity
5. improve visually appealing
lipids like carbohydrates are compared of carbon, hydrogen, and oxygen atoms but in different proportions
true
Lipids will not dissolve in water but can be dissolved in________ not used in food preparation such as benzene, chloroform, ether and acetone
organic solvents
What are the 3 categories edible lipids are divided into?
1. triglycerides (fats and oils)
2. phospholipids
3. sterols
There are two major components of simple fats including ____ and ____
glycerol and fatty acids
____ is a polyhydric alchol containing 3 carbon atoms, forms the back bones of lipids
glycerol
___ in simple fats are orgnaic compounds the characteristic carboxyl group identifying them as an acid
fatty acid
___ usually contain an even number of carbon atoms. The smallest number of carbon is 3 carbon (acetic acid with 2 carbon atoms) and the largest is arachidonic acid a 20 carbon atom
fatty aicds
What are the 2 major ways fatty aicds differ from each other?
1. degree of saturation
2. the length
___ is determined byt he number of carbon atoms
length of fatty acids
____ is determined by the number of double bonds between carbon atoms

no carbon = carbon double bonds , saturated
one carbon = cabron double bond , monounsaturated
two or more carbons = cabron double bonds polyunsaturated
degree of saturation
Each fatty acid is identified by a common name rather than their sytematic nomenclature; what are the 3 kinds?
1. saturated fatty aicds
2. monounsaturated fatty acids
3. polyunsaturated fatty acids
___ have no doubel bonds, primarily animal sources; meats , dairy, milk, butter, plants (coconut, palm, and coconut oil)
sautrated fatty acid
____ are one double bond: primarily plant sources; olives, olive oil, peanuts, peanut butter, and avocado
monounsaturated fatty aicds
___ are two or more doubel bonds, primarily plant sources; vegetable oils and fish
polyunsaturated fatty acids
____ is the most abundant monounsaturated fatty acid (MUFA) a 18:1(18 carbons and 1 double bond)
oleic acid
the ___ is the carbon at the end furthest from carboxyl end is designated as the omega carbon
terminal carbon
the polyunsaturated fatty acids associated with health benefits are the essential fatty acids _____ and _____
omega 3(linolenic acid) and omega 6(linoleic acid) fatty acids
___ can be described chemically as 18:2 (n-6) when identifying its structure by omega category or cis-9 , cis-12-octadecanoic acid
linoleic acid
___ is an omega 6 fatty acid
linoleic acid
_____ commonly called linolenic fatty acid consists of 18 C atoms and double bonds at C 9 ,12, and 15
linolenic acid
____ is an omega 3 fatty acid
linolenic acid
____ fatty acid is of particular importance because it is a precusor of 20-carbon eicosapentanoic aicd (EPA) and 22-carbon docosahexanoic acid (DHA)
alpha-linolenic or linolenic fatty acid
__ and ___ are highly unsaturated fatty acids with high biological activity.
EPA and DHA
The double bonds in naturally occuring polyunsaturated fatty acids are in the _______ with a methylethyl between the carbons at the double bonds
cis configuration
_____ are lipids with the double bonds naturally occuring polyunsaturated fatty acids in the cis configuration with a methylethyl between the carbons and the double bons
non-conjugated fatty acids
____ is a fatty acid naturally abundant in milk fat consisting of double bonds on alternate carbon atoms, with one in a cis and another in the trans form
Conjugated linoleic acid (CLA)
___ is a product of microbial action in the rumen of cattle
CLA
only _________ fatty acids are to be reported on the nutrition lable; CLA is believed to have some health benefits
non conjugated trans double bonds
___ is the temperature at which the crystals of a solid fat melts or becomes a liquid
melting point
the melting points of fatty acids are related to the ___, ____, ___ and ____
chain length, degree or saturation , configuration, and crystalline structure
Which fatty acids have a higher melting point due to degree of saturation?
saturated fatty acids have a higher melting point than unsaturated fatty acids
The higher the degree of saturation , ________
the lower the melting point
____ have a lower melting point
short chain fatty acids
____ are more likely to be solid at mixing temperature than are short chain fatty acids
long chain fatty acids
a fatty acid with a _____ configuration, has a higher melting point than identical fatty acid with a cis form at the double bond
TRANS
The arrangement of the fatty acids (how they are packed or crystalized, in the solid phase ) determines ______
the melting point
The larger the crystals in fatty acids , the _______ melting point
higher the melting point
FAts in foods can be classified on the basis of the number of ___________
fatty acids esterified to the glycerol molecule
one fatty acid linked to glycerol is a _____

two fatty acids linked to a glyerol is a _____

three fatty acids attached to a glycerol molecule is a _____
monoglyceribe

diglyceride

triglyceride
about 95 % of all lipids are ______
triglycerides
fats and oils in foods belong to a group called ____
lipids
/Fats and oils differ in 2 ways:
1. ?
2. ?
1. fats are solid at room temperature when oils are liquid
2. fats are usually derived from animal sources, while oils are predominately from plants

The exceptions are coconut and palm oils which are solid at room temp , and fish oils which are liquid at room temp.
plant sources high in fats include ___ ,____, ___ and ___; most fruits vegetables and grians contain little if any fat
nuts seeds avaocado olives and coconut
most food contain ___ types of fatty acids but usually one type predominates
3 types
most vegetable and fish oils are high in _______ while olive and canola oils are rich in ______
polyunsaturated ; monounsaturated
The animal fat, coconut and palm oils are more _____
saturated
Foods from animal origin usually contain about a ____ P/S ratio of polyunsaturated and saturated fats , while in plant foods the ratio is usually ____
50:50 , 85:15
The higher the _____ , the more polyunsaturated fats the food contains
P/S ratio
P/S ratio
review table in notes
___ are similar to triglycerides in structure in that fatty acids are attached to the glyelrcol moelcule , the difference is the replacement of fatty acids in the 3rd position of glycerol with phosphate containing compound
phospholipids
The presence of phosphorus containing compound makes phospholipids _____ , while its fatty acid components are only soluble in fat
soluble in water
phospholipids are Widely used by the food industry as ______ in products such as beverages, baked goods , mayonnaise and candy bars
emulsifiers
Foods naturally contianing _____ include egg yolks, liver, soybeans, wheat germ and peanuts
phospholipids
The best known phospholipid is ___ which is found in egg yolks
lecithin
____ acts as an emulsyfing agent - allowing hydrophobic and hydrophillic compunds to mix
lecithin
___ serves as an important component of cell membranes, where it assists in moving fat soluble vitamins and hormones in and out of the cell
phospholipids
___ are large intricate molecules consisting of interconnected rings of carbon atoms with a variety of side chains attached
sterols
____ are of physiological importance because they are involved in maintaining the human body - they include cholesterol, bile, both sex (testosterone, estrogen ) and adrenal (cortisol) hormones and vitamin D
sterols
The sterol of most significance in food is ____
cholesterol
Both animal and plant foods contain sterols, however , cholesterol is found only in foods of _____
animal orgiin ( meat, poultry, fish , fish roe(caviar) , organ meats(liver brain kidney) dairy products and egg yolks
Plants do not contain cholesterol but they may contain other types of sterols , T/F?
True
____ are found in small amounts in many fruits vegetables nuts seeds cereals legumes and other plant sources
plant sterols
in 2000, the FDA allowed the use of health claims in regarding the role of plant sterols or plant sterol esters in reducing the ________
risk for coronary heart disease
To qualify for a claim, a food must contain at least ___ gram of plant sterol or 1.7 grams of plant sterol esters per serving
0.65 g
It qualify for a claim, food must not cintain over ___ g of total fat per serving and per 50 g
13 g
Spreads and salad dressings are exempted if the lable refers the consumer to the product's ______
nutrition facts panel
When discussing the lipid content in foods , they are reffered to as ___
fats
___ are solid at room temp, usually derived from animal origin except fish oil which is liquid at room temp, have high emlting point and smoke point ; more appropriate for frying
fats
___ are liquid at room temp and are usually from plant cources except coconut oils and palm oils; they have low melting points and smoke at low temperatures
oils
Most fats are mixtures of ____ in oils
crystals of fats
What are the 4 chemical changes in lipids ?
1. rancidity
2. peroxidation
3. lipolysis
4. reversion
____ is chemical deterioration of fats, that occurs when triglyceride molecules and or the fatty acids attached to the glycerol molecule are broken down into smaller units resulting in off flavors and odor
rancidity
The longer the fat is stored, the greater the possibility of it being ____
rancid
Fat and oils used for cooking tend to become rancid because they are exposed to __,___ and ___; for this reason they should be checked frequently for rancidity
oxygen, heat, and light
What are the 2 types of rancidity?
1. oxidative rancidity
2. hydrolytic rancidity
___ involves the uptake of oxygen at a double bond position of an unsaturated fatty acid ; the double bond is broken and oxygen becomes part of the molecule rsulting in the formation of free radicals
oxidative rancidity
What are the steps of oxidative rancidity?
1. initiation
2. propagation
3. termination
Compounds from _______ including aldehyde, ketones, and alcohols are responsible for the characteristic off flavor of oxidized fats
hydroperoixides
oxidative rancidity is common in _________
polyunsaturated fatty acid such as linoleic fatty acid
_______ in fat is also faciliated by metals such as iron, copper, and light/warm temperatures
chemical degradation/reaction
_____ results from the splitting/seperation of the fatty acid (lipolysis) from the glycerol backbone as a result of fat uptake of molecule water
hydrolytic rancidity
____ is a reaction of a molecule of water with a fat molecule to release a free fatty acid in the presence of lipase or heat
lipolysis ; this reaction is promoted by the action of lipase or by heat
placing cold, wet food in a heated frying oil introduces water makeing the oil prone to ______
hydrolytic rancidity
a complete hydrolysis of a triglyceride yields what?
3 free fatty acids and one molecule of glycerol
Free fatty acids generated from hydrolytic rancidity alter _____ and _____
aroma and flavor of fat or oil
______ is the break down (oxidation ) of an essential fatty acid, linoenic acid, found in certain vegetable oils , leading to an undesirable flavor change prior to the start of actual rancidity
flavor reversion
the odors/ flavors of product undergoing flavor reversion depend on _______
they type of oil ; soy bean oil intially becomes beany and then fishy
The two most commonly used oils are ____ and ____ and are resistant to flavor reversion
cotton seed and corn oils
When storing fats and oils avoid ___ and ____
oxygen and heat
store fat in tightly closed containers in a cool, dark environment. This ____________
slows the onset and continous perpetulation of oxidative rancidity
store fats such as butter and maragine in the refrigerator ; butter keeps for months in the freezer but margarine does not freeze
true
___ and ____ should be stored in a dark spot or cupboard shelf - will keep longer if refrigerated
shortening and most oils
___ should be refigerated after opening because of its short shelf life
olive oil
___ are added to foods contianing large amounts of unsaturated fats to prevent rancidity
antioxidants , natural and commerical
______ are substance used to preserve food by retarding deterioration, rancidity, or discoloration due to oxidation
USDA 's Code of federal regualtions definition of antioxidants
What are the 3 ways in which antioxidants prevnet oxidation of fats?
1. being oxidized themselves
2. donating their hydrogen to a fatty acid as a reducing agent
3. sequestering metals such as a chelating agent
What are the naturally occuring antioxidants?
vit E, C , lecitin, flavonoid, and gum guaic

many vegetabl oils naturlaly contain vit E
nutylated hydroxyanisole (BHA) , butylated hydroxytoluene (BHT), tertiary butyl hydroquinone (TBHQ) , and proply gallate (PG) are examples of ________
syntheic antiodiants approved by the FDA and used as additive in foods
What are 5 exmaples of foods to which antioxidants are added to?
1. dry cereals
2. creackers
3. nuts
4. chips
5. flour mixes
___ refers to the clawlike manner in which the agent binds to the metal through coodinated covalent bonds
chelate
examples of chelating agents also known as metal sequesterers include ___ , ___ and ____
EDTA, citric acid and phosphates
vitamin C, vitamin E (locopherols), beta carotene , flavonoids , erthorbic acid , asorbyl palmitate, sulfites are examples of _________
reducing agents that transfer hydrogen
_____ is the temperature at which fats or oils begin begin to emit a trace of smoke as a result of fat degrataion
smoke point
fats and oils can be heated to extremely high temperatures however, with extensive use fat moleulces begin to break down ; ____ ocurs at a high temperature in all fats but varies form fat to fat and the previous fats history
smoke point
when fats and oils are heated beyond the smoke points, a ____ is met
flash point
____ represents the point at which heat fat can ignite when heated beyond the smoke point
flash point
___ with the uptake of water this occurs releasing free fatty acids
lipolysis
as a result of lipolysis :

monoglycerides --> ?
diglycerides --> ?
triglyerides --> ?
glycerol + free fatty acid
glcerol + 2 free fatty acid
glycerol + 3 fatty acids
heating beyond the flash point causes ______ to break (hydrolyzed )
ester linkage ( the point where glycerol and fatty acids are joined together)
With continuous heating beyond hydrolysis (glycerol and fat) , this promotes futher deteriative changes- two molecules of water are removed from the glycerol resulting in the formation of a steel blue smoke called ________
Acrolein
____ is a highly imitating and volatile ocmpound formed when glycerol is heated to the point where two moelcules of water split form fatty acid ; its a sharp offensive odor warning people of its presence ; this smoke is extremely irritating and even harmful to the mucous membrane of the mouth and nasal passages
Acrolein
The ____ is specific for each fat- as a fat is used at high temperatures over an extended period this will graudualy dorp for that fat until the appearance of fried foods become unacceptable
smoke point
Monoglycerides are often added to ______, the presence of monoglycerdies reduces the smoke point too low for acceptable frying products
shortenings and other fats
fat for frying is selected based on the _____
smoke point; the higher the smoke point the better the fat for frying
_____ is a process in which free fatty acids link/stick together - this occurs when fat is over heated resulting in gummy, dark residue , more viscous , and prone to foaming
polymerization
The fatty acid formed from lipolysis promotes ______ when it undergoes additional chemical modificaitons as the frying fat continues to be heated
polymerization ; among the compounds formed are a variety of polymers including simple dimers and trimers
fatty acids contianing at least one _______ are susceptible to polymerizaiton
double bond
______ is a monomer formed in starch rich foods cooked at high temperature
acrylamide (ethylene carboxyamide or 2-propenamide)
potato chips are fried at high temperatures and are high in starch - potato chips is one of the foods with high levels of _______
acrylamide
for _____ , high levels have been reported in other staple foods such as rice and potatos, is deemed to be carcinogenic to animal - no evidence of its carcinogenicity in man
acrylamide