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91 Cards in this Set
- Front
- Back
Stoichiometry |
-can be used to predict (calculate) amounts & products |
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Limiting Reactant
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Reactant that is completely consumed before any other chemical in a reaction
-limits how much product can be made -other reactants are NOT consumed fully (in excess) |
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Theoretical Yield |
specific maximum of product that can be made
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Actual Yield |
What we make (less than theoretical) |
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% yield= |
(actual yield/theoretical yield)x 100 |
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Solution (Define) |
homogenous mixture of 2 substances *solute + solvent* |
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Solute (Define) |
Stuff that is dissolved -Minor componet |
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Solvent (Define) |
Stuff that is doing the dissolving -major component |
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Concentration |
amount of solute in solution |
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Molarity (M)= |
moles of solute ÷ volume of solution (L) |
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Stock Solution (Define) |
way to store solution in lab |
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Diluted Solutions` |
-less concentrated solution -smaller molarity -#moles does NOT change, only volume changes |
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Diluted Solution Equation |
M₁V₁=M₂V₂ |
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Electrolyte |
material forms ions in solution & will conduct electricity |
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Strong Electrolyte |
completely dissolves in water |
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Weak Electrolyte |
dissociates, not completely |
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How do you know if you have an electrolyte? |
-soluble ionic compounds (strong electrolyte) -slightly soluble salts (weak electrolyte)
-molecular compounds (accept acid/base)= non-electrolytes, including pure elements |
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Strong Acid |
ionizes (dissociates) completely in a solution
Ex: HCL(aq) →H⁺(aq) and Cl⁻(aq) |
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Weak Acid |
ionizes (dissociates) a little bit
Ex: HC₂H₃O₂(aq) ↔ H⁺(aq) + C₂H₃O₂ (aq) |
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In order for Ionic compounds to conduct electricity they must_____. |
dissolve (be soluble) in water |
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Salt |
ionic compounds that result from the neutralization reaction of an acid and a base |
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Aqueous + Aqueous = Aqueous + Aqueous signifies____. |
There was NO REACTION |
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Molecular Equation |
Complete neutral formulas reactions + products |
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Complete Ionic Equation |
-list all ions present in a reaction
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Spectator Ions |
aqueous ions that exist as both reactants & products |
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Acid-Base Reaction |
Acid&Base neutralize eachother
Acid + Base → Water + Salt |
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Polyprotic Acid |
can lose more than one H⁺ in a solution
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Titration |
method of following a reaction until is is stoichiometry complete -reached end point (equivalence point) -no excess
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Indicator (during experiment) |
determines endpoint of experiment (changes color when endpoint is reacher) |
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Gas-Evolution Reactions (list 4) |
1) Sulfides: product H₂S 2) Carbonates & bicarbonates: product CO₂ 3) Sulfites & bisulfites: product SO₂ 4) Ammonium: product NH₃ |
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Redox Reactions |
Transfer of electrons from one atom to another -often involves O₂(g) |
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Oxidation |
loss of electrons (more positive) |
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Reduction |
gain of electrons (more negative) |
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Free elements are assigned an oxidation state of __. |
zero Cu, Le, Si, H₂, N₂, O₂, F₂, Cl₂, P₄, etc. |
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Any simple monatomic anion is assigned an oxidation state____. |
equal to it's charge |
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Alkali Metals (Group 1A) in ionic compounds are assigned an oxidation state of ____. |
+1 |
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Fluorine in compounds is ALWAYS assigned an oxidation state of ____. |
-1 |
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Alkaline Earth Metals (IIA) in compounds are always assigned a ____ oxidation state. |
+2
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Zn & Cd in compounds are always assigned a ____ oxidation state. |
+2 |
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Al & Ga in compounds are always assigned a ____ oxidation state. |
+3 |
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Hydrogen bound to a non-metal is assigned a ___ oxidation state. |
+1 |
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Hydrogen bound to a metal is assigned a ____ oxidation state. |
-1 |
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Oxygen in compounds is assigned a ____oxidation state, except in peroxide where it's assigned ____. |
oxygen in compounds = -2 O₂=-1 |
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The sum of the oxidation states of all atoms in a species must be equal to the _____. |
net charge |
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Activity Series (define) |
ability of a metal to be oxidized -Top: most easily oxidized (best deducting agents) -Bottom: best oxidizing agents (noble metals) |
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Metal ABOVE ion → |
reaction occurs |
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Metal BELOW ion |
no reaction occurs |
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Electrons Mass= |
one trillionth of one trillionth of a gram |
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Electrons determines atoms ____ & ____. Ions & Bonding. |
physical & chemical properties |
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Spectroscopy |
shine light on stuff and see how it reacts
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Wave-Particle Duality |
light behaves as both a wave and a particle |
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Why do we study light? |
It's very similar to the electron |
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Light (define) |
electromagnetic radiation -has a wavelength & frequency
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Electric Field |
electrically charged particles that can experience a force |
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Magnetic Force |
magnetic particle that experiences force |
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Electromagnetic Waves travel at a____ speed. |
travel at a CONSTANT speed. |
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Amplitude (define) |
height of wave -determines brightness/intensity of light |
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Wavelength (symbol, units, equation, define) |
λ meters (m) λ=c÷V distance between 2 PEAKS in a wave |
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Frequency (symbol, units, equation, define) |
V Hz (S⁻¹) V=c÷λ number of waves that pass a point in a given period of time |
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Color is determined by ____. |
wavelength or frequency |
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White Light is ____. |
a mixture of all colors |
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Color of an object is the reflected light that the object ______. |
did not absorb |
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Short Wave Length |
hight frequency=high energy (gamma rays) |
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Long Wave Length |
low frequency=low energy |
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Light behaves light waves except for ____. (list the 3 exceptions) |
1) Black Body Radiation (Thermal Radiation) 2) Photoelectric Effect 3) Atomic Spectroscopy |
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Black Box Radiation (Thermal Radiation) |
Hot objects emit radiation in a specfic spectrum of frequencies & intensities, VARYING with TEMP of object. |
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Hotter Object= ___wavelengths. |
shorter wavelengths blue (blue-white flame) |
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Cooler Objects=____wavelengths. |
longer wavelengths red (toaster) |
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Plank proposed____.
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Light is delivered in packets (quanta) ---> PHOTONS (behave as tiny particles) |
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Photoelectric Effect |
Shining Light on a metal surface → electrons fly off |
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Eistein discovered the _____ exception. |
Photoelectric Effect |
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Threshold Frequency |
Wavelength & Frequency are needed to emit electrons regardless of intensity of light (brightness) |
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Atomic Spectrum |
When an atom absorbs energy, that energy is often released as light energy -each element (gas state) has it's own characteristic line spectrum |
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White Light→Prism→Rainbow (_____) |
continuous spectrum |
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Light from atom→Grating→emission (____) |
line |
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Heinsenberg Uncertainty Principle |
-Wave and Particle Nature are complimentary properties (more you know about one, less you know about other) -Product of uncertainty in both position and speed of a particle are inversely proportioned to mass |
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Schrödiner |
Wave-Particle Duality Hγ=Eγ |
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Bohr predicted____. |
electrons travel around nucleus in orbits -electrons exist only at FIXED distances from nucleus -energy of orbits are FIXED →Stationary States |
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∆=negative, electron moves _____ to nucleus. Photon is _____. |
electron moves CLOSER to nucleus. photon is EMITTED. |
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∆=positive, electron moves____to nucleus. Photon is___. |
electron moves FARTHER from nucleus. Photon is ABSORBED.
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Principle Quantum Number (symbol, define) |
n -size & energy of an orbital as n increase, orbital gets bigger (electrons are further from nucleus) n≥l (integer; n=1,2,3,…) n=principle level
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Angular Momentum Quantum (symbol, define) |
L (lowercase) -shape of orbital where electron resides L = 0,1,2,3…n-1 (always less than n) (L= possible sublevels) = # values of L |
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L = 0 → |
s |
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L = 1→ |
p |
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L = 2 → |
d
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L = 3 → |
f |
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Magnetic Quantum Number (symbol, define) |
m orientation of orbital mι=-L,…-2,-1, 0, 1, 2, …, +L |
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S Orbital (L=__, define, shape) |
L=0 each principle energy level has an S-orbital LOWEST shell -spherical shape |
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P Orbital (L=___, define, shape) |
L=1 orientation is different →P×, Ps, Pz -2 lobes (Bowtie) |
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d Orbital (L=___, define, shape) |
L=2 4 planes dxy, dxz, dyz, dx²-y², dz² -clover leaf shape |
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f Orbital (L=___) |
L=3 |