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91 Cards in this Set

  • Front
  • Back

Stoichiometry

-can be used to predict (calculate) amounts & products

Limiting Reactant
Reactant that is completely consumed before any other chemical in a reaction
-limits how much product can be made
-other reactants are NOT consumed fully (in excess)

Theoretical Yield

specific maximum of product that can be made


Actual Yield

What we make (less than theoretical)

% yield=

(actual yield/theoretical yield)x 100

Solution (Define)

homogenous mixture of 2 substances


*solute + solvent*

Solute (Define)

Stuff that is dissolved


-Minor componet

Solvent (Define)

Stuff that is doing the dissolving


-major component

Concentration

amount of solute in solution

Molarity (M)=

moles of solute ÷ volume of solution (L)

Stock Solution (Define)

way to store solution in lab

Diluted Solutions`

-less concentrated solution


-smaller molarity


-#moles does NOT change, only volume changes

Diluted Solution Equation

M₁V₁=M₂V₂

Electrolyte

material forms ions in solution & will conduct electricity

Strong Electrolyte

completely dissolves in water

Weak Electrolyte

dissociates, not completely

How do you know if you have an electrolyte?

-soluble ionic compounds (strong electrolyte)


-slightly soluble salts (weak electrolyte)



-molecular compounds (accept acid/base)= non-electrolytes, including pure elements

Strong Acid

ionizes (dissociates) completely in a solution



Ex: HCL(aq) →H⁺(aq) and Cl⁻(aq)

Weak Acid

ionizes (dissociates) a little bit



Ex: HC₂H₃O₂(aq) ↔ H⁺(aq) + C₂H₃O₂ (aq)

In order for Ionic compounds to conduct electricity they must_____.

dissolve (be soluble) in water

Salt

ionic compounds that result from the neutralization reaction of an acid and a base

Aqueous + Aqueous = Aqueous + Aqueous


signifies____.

There was NO REACTION

Molecular Equation

Complete neutral formulas


reactions + products

Complete Ionic Equation

-list all ions present in a reaction


Spectator Ions

aqueous ions that exist as both reactants & products

Acid-Base Reaction

Acid&Base neutralize eachother



Acid + Base → Water + Salt

Polyprotic Acid

can lose more than one H⁺ in a solution


Titration

method of following a reaction until is is stoichiometry complete


-reached end point (equivalence point)


-no excess


Indicator (during experiment)

determines endpoint of experiment (changes color when endpoint is reacher)

Gas-Evolution Reactions


(list 4)

1) Sulfides: product H₂S


2) Carbonates & bicarbonates: product CO₂


3) Sulfites & bisulfites: product SO₂


4) Ammonium: product NH₃

Redox Reactions

Transfer of electrons from one atom to another


-often involves O₂(g)

Oxidation

loss of electrons (more positive)

Reduction

gain of electrons (more negative)

Free elements are assigned an oxidation state of __.

zero


Cu, Le, Si, H₂, N₂, O₂, F₂, Cl₂, P₄, etc.

Any simple monatomic anion is assigned an oxidation state____.

equal to it's charge

Alkali Metals (Group 1A) in ionic compounds are assigned an oxidation state of ____.

+1

Fluorine in compounds is ALWAYS assigned an oxidation state of ____.

-1

Alkaline Earth Metals (IIA) in compounds are always assigned a ____ oxidation state.

+2


Zn & Cd in compounds are always assigned a ____ oxidation state.

+2

Al & Ga in compounds are always assigned a ____ oxidation state.

+3

Hydrogen bound to a non-metal is assigned a ___ oxidation state.

+1

Hydrogen bound to a metal is assigned a ____ oxidation state.

-1

Oxygen in compounds is assigned a ____oxidation state, except in peroxide where it's assigned ____.

oxygen in compounds = -2


O₂=-1

The sum of the oxidation states of all atoms in a species must be equal to the _____.

net charge

Activity Series (define)

ability of a metal to be oxidized


-Top: most easily oxidized (best deducting agents)


-Bottom: best oxidizing agents (noble metals)

Metal ABOVE ion →

reaction occurs

Metal BELOW ion

no reaction occurs

Electrons Mass=

one trillionth of one trillionth of a gram

Electrons determines atoms ____ & ____. Ions & Bonding.

physical & chemical properties

Spectroscopy

shine light on stuff and see how it reacts


Wave-Particle Duality

light behaves as both a wave and a particle

Why do we study light?

It's very similar to the electron

Light (define)

electromagnetic radiation


-has a wavelength & frequency


Electric Field

electrically charged particles that can experience a force

Magnetic Force

magnetic particle that experiences force

Electromagnetic Waves travel at a____ speed.

travel at a CONSTANT speed.

Amplitude (define)

height of wave


-determines brightness/intensity of light

Wavelength (symbol, units, equation, define)

λ


meters (m)


λ=c÷V


distance between 2 PEAKS in a wave

Frequency (symbol, units, equation, define)

V


Hz (S⁻¹)


V=c÷λ


number of waves that pass a point in a given period of time

Color is determined by ____.

wavelength or frequency

White Light is ____.

a mixture of all colors

Color of an object is the reflected light that the object ______.

did not absorb

Short Wave Length

hight frequency=high energy (gamma rays)

Long Wave Length

low frequency=low energy

Light behaves light waves except for ____. (list the 3 exceptions)

1) Black Body Radiation (Thermal Radiation)


2) Photoelectric Effect


3) Atomic Spectroscopy

Black Box Radiation (Thermal Radiation)

Hot objects emit radiation in a specfic spectrum of frequencies & intensities, VARYING with TEMP of object.

Hotter Object= ___wavelengths.

shorter wavelengths


blue (blue-white flame)

Cooler Objects=____wavelengths.

longer wavelengths


red (toaster)

Plank proposed____.


Light is delivered in packets (quanta)


---> PHOTONS (behave as tiny particles)

Photoelectric Effect

Shining Light on a metal surface → electrons fly off

Eistein discovered the _____ exception.

Photoelectric Effect

Threshold Frequency

Wavelength & Frequency are needed to emit electrons regardless of intensity of light (brightness)

Atomic Spectrum

When an atom absorbs energy, that energy is often released as light energy


-each element (gas state) has it's own characteristic line spectrum

White Light→Prism→Rainbow (_____)

continuous spectrum

Light from atom→Grating→emission (____)

line

Heinsenberg Uncertainty Principle

-Wave and Particle Nature are complimentary properties


(more you know about one, less you know about other)


-Product of uncertainty in both position and speed of a particle are inversely proportioned to mass

Schrödiner

Wave-Particle Duality


Hγ=Eγ

Bohr predicted____.

electrons travel around nucleus in orbits


-electrons exist only at FIXED distances from nucleus


-energy of orbits are FIXED →Stationary States

∆=negative, electron moves _____ to nucleus. Photon is _____.

electron moves CLOSER to nucleus.


photon is EMITTED.

∆=positive, electron moves____to nucleus.


Photon is___.

electron moves FARTHER from nucleus.


Photon is ABSORBED.


Principle Quantum Number (symbol, define)

n


-size & energy of an orbital


as n increase, orbital gets bigger


(electrons are further from nucleus)


n≥l (integer; n=1,2,3,…)


n=principle level


Angular Momentum Quantum (symbol, define)

L (lowercase)


-shape of orbital where electron resides


L = 0,1,2,3…n-1 (always less than n)


(L= possible sublevels) = # values of L

L = 0 →

s

L = 1→

p

L = 2 →

d


L = 3 →

f

Magnetic Quantum Number (symbol, define)

m


orientation of orbital


mι=-L,…-2,-1, 0, 1, 2, …, +L

S Orbital (L=__, define, shape)

L=0


each principle energy level has an S-orbital


LOWEST shell


-spherical shape

P Orbital (L=___, define, shape)

L=1


orientation is different


→P×, Ps, Pz


-2 lobes (Bowtie)

d Orbital (L=___, define, shape)

L=2


4 planes


dxy, dxz, dyz, dx²-y², dz²


-clover leaf shape

f Orbital (L=___)

L=3