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37 Cards in this Set

  • Front
  • Back

Electron pair geometry

You simply count the number of outer atoms and decide from there the shape.


Each lone pair will take the shape up another step...

Linear

Two outer atoms.

Triginal planer

3 outer atoms.


Or


2 outer atoms and one lone pair on the central atom!

Tetrahedral

4 outer atoms.


Or


3 outer atoms + 1 lone pair


Or


2 outer atoms + 2 lone pairs

Trigonal bipyramidal

5 outer atoms


Or


4 outer atoms + 1 lone pair


Or


etc.........

Polar

The atom is assametric


Ex:


H------N:--------H


|


H

Non polar

The atom is symetric, no electrons on the central atom.

Hydrogen bonding

H is attached to N, O, or F

Ionic bonding

It's an ionic molecule

Dipole-Dipole

Polar


Assymetric

Dispersion/London/Van Der Waals

Weakest


Non-polar


Symetric

Covalent

Two non-metals

Ionic

Metal + non-metal.

Boiling point

Bigger molecule = Higher BP = Higher IMF

Intermolecular Forces

- Forces between molecules (Two or more molecules interact)


- Deals with physical properties

Intramolecular Forces

Forces between atoms in a molecule


(Atoms doing stuff in a single molecule)

High IMF

High BP


High viscosity (thickness)


High Surface Tension


High Melting Point


(Hard to seperate the molecules)

Low IMF

High Vapor Pressure


(Can be separated easily)

Bond Order

Sigma bonds happen first and then Pi bonds happen.

Electronegativity

Decreases from right to left


Decreases from top to bottom

Surface tension

the tendency of a liquid to possess elasticity at its surface

Capillary action

movement of a liquid through a narrow tube because of attractive forces between the liquid and the container

Cohesion

The attractive forces between a single type of molecule


(Intermolecular forces, Dispersion forces, Hydrogen bonding)

Adhesion

the attractive forces between two different types of molecules

Meniscus

curvature at the liquid-container interface

Paramagnetic

One electron is unpaired it has a weird net spin

Diamagnetic

All electrons are paired

Polar Covalent

Moderate Electronegativity difference.


Electrons unequally shared.

Pure Covalent

Little-to-no Electronegativity difference.


Electrons shared equally.

Electron vs molecular geometry

Molecular geometry only pays attetion to bonds, not lone pairs

Types of bonding

Non-polar Covalent


Polar Covalent


Ionic


Hydrogen


Dipole-Dipole


Dispersion

Hybrid Orbitals

sp, sp^2, sp^3, sp^3d, sp^3d^2


This is talking about electron geometry, so focus on how many areas of high density it has. Doesn't matter for this if they're lone pairs or not. (INCLUDE LONE PAIRS THOUGH)

Types of solids

Covalent/Network Solids


Ionic Solids


Metallic Solids


Molecular Solids

Covalent/Network Solids

Strongest


Covalent bonding

Ionic Solids

Second strongest


Ionic bonding

Metallic Solids

Third strongest


Mostly pure metal, but can be mixed.

Molecular Solids

Weakest


Held together by IMF basically two molecules held together.