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25 Cards in this Set

  • Front
  • Back
What question did Stern and Gerlach help answer?
How many electrons can go in each orbital.
What is the Stern-Gerlach experiment?
When a beam of silver atoms is passed through a strong inhomogeneous magenetic field
What did the Stern-Gerlach experiment investigate?
Whether atoms were magnetic and how they responded to the fields
What does the Pauli Exlusion Prinicple explain?
It explains chemistry in the sense of who electrons interact
Tells how many electrons can occupy an orbital
Can electrons have the same quantum number?
No
Hund's Rule
Electrons won't pair up in an orbital unless they have to
When they are in separate orbitals, both spin in the same direction.
Occupy degenerate orbitals singly (where possible)
Valence electrons
participate in chemical reactions
Elements with similar valence?
have similar chemical properties
Which elements are the "wrinkles" in electron configuration?
Cr, Cu, Ag
period trends with size
increases as going down and from left to right
Ionization energy periodic trends
decreases going down and from left to right
endothermic (2)
loss of electrons
requires energy
Lattice energy
energy needed to form ionic crystal
Born-Haber Cycle
way of calculating Lattice energy
positive ions + negative ions = ?
ionic solid
1st law of thermodynamics
energy is concerved. it is neither lost or gained
electrostatic attractions
effects the control of lattice energy
high lattice energy (4)
difficult to pull apart
high boiling/melting point
strong materials
insoluble in water
refactory materials
high melting points and are very hard
Limelights (4)
CaO
High melting point
light stage theatres back in the day
bright light
Coleman Lamp (3)
ThO (sub 2)
high lattice energy
bright light
low lattice energy (3)
low melting point
soluble in water
still solid @ room temp.
Madelung factor
M in energy equation
1.5-2.0
soluble
low lattice energy
low charge
d factor is large
polyatomic ion
unsoluble
high lattice energy
high charge
d factor is small
monoatomic