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31 Cards in this Set

  • Front
  • Back
intra bonding
strong bonds, 2 types
-ionic bonding
-covalent bonding
ionic bonding
very strong
intra bonding
between metal and nonmetal
strong electrostatic force between charged atoms
covalent bonding
weak
intra bonding
between nonmetals
sharing of electrons
inter bonding
weak bonds, 3 types
-dipole dipole
-hydrogen bonding
-london dispersion
diopole-dipole bonding
inter bonding
polar molecules, between different nonmetals
hydrogen bonding
inter bonding
hydrogen attached to N, O, or F
london dispersion
inter bonding
non-polar molecules, between same nonmetals
nonpolar covalent bonding
electrons are shared equally by the nucleus
atoms want to achieve stable outer shell configuration
same nonmetals
polar covalent bond
unequal sharing of electrons
one atom has a higher affinity for electrons than the other
atom with higher affinity is partially positive and the other is partially negative
between two different nonmetals
electronegativity
the relative ability of an atom within a covalent bond to attract shared electrons to itself
--> +
l
v
-
dipole moment
only happens in polar bonds
when a partial - and a partial + are formed because of the unequal sharing of electrons
arrow points to negative end with the positive tail on the positive end.
why is the fact that water is polar crucial to life
because water molecules can surround and attract positive ions by there - end and - ions by their positive ends. these attractions allow ionic materils to dissolve in water. also polar water molecules are strongly attracted to each other which gives them a high biling point. therefore, it is the polarity of the water molecule that causes water to remain a liquid at the temperature on the earth's surface. if it were non polar, water would be a gas and the oceans would be empty.
lewis structures
shorthand to represent the valence electrons of an atom
only with covalent bond molecules
steps of drawing a lewis structure
1. count total valence electrons (look at group number)
2. for a single bond between central and outer
3. give outer atoms an octet, except H which only needs 2
4. make sure central atom has at least an octet
-C, O, and N don't exceed 8
-B does not need 8
-if you run out of electrons and the
central atom does not have an
octet, begin forming multiple bonds
resonance structures
multiple ways to draw a lewis structure
VSEPR theory
valence shell electron pair repulsion theory
VSEPR model
used to predict the molecular structures of the molecules formed from nonmetals
2-0
linear
180
3-0
trigonal planar
120
4-0
tetrahedral
~109
5-0
trigonal bipyramid
120 & 90
6-0
octahedral
no bond angle
3-1
pyramidal
107
2-2
bent or v-shaped
104
3-2
t-shaped
90
dipole-dipole interactions
when molecules with dipole moments (polar molecules) can attract each other by lining up so the positive and negative ends of the molecules attract one another
works best in the liquid state
polar
hydrogen bonding
when N, F or O bonds with H
gives substances containing h-bonds really high boiling points
substances containing h-bonds are more viscious
very strong bond
polar
london dispersion forces
non polar
noble gases
all HOFBrINCl's
kinetic molecular theory of gases
1. gas consists of tiny particles made up of atoms or molecules
2. the particles are so small they are considered negligible
3. particles are in constant motion, colliding with the container which creates pressure
4. particles do not attract or repel each other
5. kinetic energy is directly related to the temperature in Kelvin
rate of effusion equation
1
rate of effusion =------------
square root molar mass
rate of diffusion equation
rate A square root molar mass B
----- = --------------------
rate B square root molar mass A