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92 Cards in this Set

  • Front
  • Back

Length

In science, we measure
length using the mete

Mass

Mass is a quantity of
matter

Volume

Volume measures the amount of space an object
occupies

Temperature

Temperature should be recorded using Kelvin (K)

Conversion Factor

When a measurement is multiplied by a
conversion factor, the numerical value is generally
changed, but the actual size of the quantity
measured remains the same

Dimensional Analysis

a way to analyze and solve problems using the
units of the measurement

Error

There is a difference between accepted and
experimental values.


– Accepted value: correct value based on reliable references


– Experimental value: value measured in lab

% Error

Is the absolute value, positive value, of the
error divided by the accepted value and then
multiplied by 100%

Accuracy

Accuracy is a measure of how close a
measurement comes to the actual or
true value of whatever is measured

Precision

Precision is a measure of how close a
series of measurements are to one
another

Standard Notation

A given number which is written with decimal
values and without a (x10) value

Scientific Notation

A given number which is written as the
product of two numbers:


– A coefficient and


– 10 raised to a power


Matter

PURE
SUBSTANCES and


Mixtures Made of 2+
substances

Pure Substance

Element & Compound


Element

Can NOT be separated by chemical means

Compound

Separated by chemical means ONLY Made up of 2+ elements chemically combined

MIXTURES

Homogeneous Mixture (solution) & Heterogeneous Mixture

Homogeneous Mixture (solution)

Same composition throughout
“UNIFORM”


Heterogeneous Mixture

Different composition throughout
“NOT UNIFORM”


Annotation of Matter


Chemists use chemical symbols to represent elements.

Properties of Matter

To understand matter, we begin by using observations and listing properties. Physical and Chemical


Extensive Property

A property that depends on how much material you are dealing with

Intensive Properties

A property that does not depend on how much material you are dealing with but helps identify matter (a constant about that particular type of matter)


Chemical Property

A property or behavior of a substance when it undergoes a chemical change or reaction

Changes in Matter

Matter can be altered by physical or chemical means

Physical Change

A change that does NOT alter the chemical properties in a substance

Chemical Change

Any change that results in the formation of new chemical substances. At the molecular level,chemical change involves making or breaking of bonds between atoms.

States of Matter

a solid, liquid, or gas.

Solids

a form of matter that has definite shape and volume.

Liquids

a form of matter that has indefinite shape, flows, but has a fixed volume.

Gases

a form of matter that has indefinite shape and indefinite volume.

Plasma

When air or gas is charged, plasma forms with conductive properties similar to those of metals.

Separation of Matter

In a chemical reaction, COMPOUNDS can be
CHEMICALLY separated into the elements that make it up.

Filtration

Filtrate flows through filter paper, undissolved particles remain on filter paper.

Watch Glass Evaporation

Separate the dissolved solid (solute) from the liquid (solvent) by boiling the solution

Crucible Evaporation

Removes any liquid captured inside the crystals of a solid by heating until boiling point has been reached.

Distillation

Will separate 2 or more liquids by there different boiling points.


Chromatography

Will separate particles based on their size and solubility

The atom

The ATOM is the smallest particle of an element that retains its identity in a chemical reaction.

Parts of any atom

Electrons – Protons – Neutrons

Protons (p+)

Have a mass of approx. 1 atomic mass unit
(a.m.u.)


Positively charged

Neutrons (n0)

Have a mass of approx. 1 a.m.u.


Neutral charge

Electrons (e-)

Have a mass of approx 1/1840 a.m.u.


Negative charge

Democritus

A Greek philosopher that believed
that atoms were indestructible and
indivisible

John Dalton

In the 1700s, John Dalton
transformed Democritus’s ideas on
atoms into a scientific theory by
using experimental methods.

Dalton’s Atomic Theory

All elements are composed of
indivisible atoms.

The Nucleus

The first, Dalton’s theory a solid
indivisible, indestructible particle
The second, J.J. Thompson and others
supposed the atom was filled with
positively charged material and the
electrons were evenly distributed
throughout.
And then came Ernest Rutherford and
his Gold Foil Experiment


Gold-Foil Experiment

In 1911, Rutherford and his coworkers
at the University of Manchester,
England, directed a narrow beam of
alpha particles at a very thin sheet
of gold foil.

Rutherford’s Atomic Theory

Rutherford concluded that the atom
is mostly empty space. All the
positive charge and almost all of the
mass are concentrated in a small
region called the nucleus.

Physical Property

A quality or condition of a substance that can be observed or measured without changing the substance’s composition.


Isotopes

ISOTOPES are atoms that have the same
number of protons but different numbers of
neutrons.

Atomic Mass

The ATOMIC MASS of an element is a
weighted average mass of the atoms in a
naturally occurring sample of the element

How to Calculate
Average Atomic Mass

1. multiply each of the element’s isotopes to their %
abundance
2. Divide each product by 100 (to remove the %)
3. Add up all the values together
(isotope’s mass x it’s % abundance) + …
100

Isotopes

ISOTOPES are atoms that have the
same number of protons but
different numbers of neutrons.

Naming Isotopes &
Isotope Notation

Remember that isotopes have the same # of protons and electrons. They also have the same atomic number.

Atomic Orbitals

An PRINCIPLE ENERGY LEVEL is
often thought of as a region of
space in which there is a high
probability of finding an electron.

Energy Sublevels

There are four energy sublevels: – s – p – d – f

Electron Configurations

The ways in which electrons are arranged
in various orbitals around the nuclei of
atoms

Expanded Configurations

An expanded e- configuration gives us
more information than a short-hand
configuration

Filling the sub-orbitals:

1s2s2p63s23p64s23d10...

Orbital Electron Notations

These notations give us a clearer idea
of what the expanded notation looks
like.

e- Configuration Rules

Electrons MUST occupy the orbitals of
lowest energy first

Filling the sub-orbitals

There are many locations that
electrons might fill in an atom, the most
stable condition exists when they fill
the lowest available energy orbitals
first.

Abbreviated Expanded
Configurations

Using an abbreviated notation allows us to
add on extra electrons to an already
perfectly filled expanded notation.

Quantum Numbers

n, L, m, s

The first: “principle quantum number” = “n”

It is the same as the number of the energy level that contains the electrons

The second: “sublevels” = “L”

Sublevels are described by using the number of the principal energy level together with the letter designation of each sublevel.

The third: “sublevel orientations” = “m”

Relates to the orbitals in the sublevels and their
orientations (orbitals)

The fourth: “spin of an electron” = “s”

This number indicates that each orbital
can contain two electrons spinning in
opposite directions.

Lewis Dot Structures

Lewis Dot Structure, or Electron Dot
Diagrams, are drawn using the
valence number of electrons.

Light

An electromagnetic wave is depicted as a
sine wave that has an amplitude,
wavelength, and frequency.


3.00 x 108 ms-1

Electromagnetic Spectrum

Electromagnetic radiation comes in a broad range of frequencies call the electromagnetic spectrum.

Planck’s Constant

Energy of a photon = E= hν
h is Planck’s constant (6.626 x 10-34 J s)

History of Atomic Emission

Bohr found that electrons, in atoms, exist in
different levels (orbitals) – Energy increased the farther the energy
level is from the nucleus

Ground State

When the electron has its lowest
possible energy

Excited State

Excitation of the electron by absorbing energy raises the atom from the ground state to an excited state

RADIOACTIVITY

the process by which nuclei emit particles and rays

RADIATION

the penetrating rays and particles emitted by a radioactive source

Radioactive Decay

An unstable nucleus releases energy by emitting radiation

Nuclear Stability and Decay

The nuclear force is an attractive force that acts between all nuclear particles that are extremely close together, such as protons and neutrons in a nucleus.

Band of Stability

A nucleus with too many neutrons relative to the number of protons will undergo Beta Decay.

Alpha Radiation

Consists of helium nuclei that have been emitted from a radioactive source. These emitted particles, called alpha particles. they least penetrating.

Beta Radiation

An electron resulting from the breaking apart of a neutron in an atom

Gamma Radiation

High energy photon emitted by a radioisotope They are the most penetrating

Positron Decay

A particle with the same mass as the electron but opposite charge

Transmutation Reactions

The conversion of an atom of one element to an atom of another element

Natural Transmutation

When radioactive elements spontaneously decay over a long period of time and transform into other more stable elements

Artificial Transmutation

Human made reactions in which a nucleus is bombarded with a high speed particle which causes the nucleus to emit a proton or neutron

Half-Life

The time required for one-half of the nuclei of a radioisotope sample to decay to products.

Nuclear Reactors

Use fission to produce useful energy Much of energy generated is in the form of heat A coolant fluid, usually liquid sodium or water, removes the heat from the reactor core. The heat is used to generate steam, which drives a turbine that in turn generates electricity.

Nuclear Waste

Fuel rods from nuclear power plants are one major source of nuclear waste

Nuclear Fusion

FUSION occurs when nuclei combine to produce a nucleus of greater mass. In solar fusion, hydrogen nuclei (protons) fuse to make helium nuclei and two positrons.