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73 Cards in this Set

  • Front
  • Back

Acid

A species that is a proton donor

Activation Energy

The minimum energy required to start a reaction by the breaking of bonds

Alkali

A type of base that dissolves in water forming hydroxide ions, OH- (aq) ions.

Amount of substance

The quantity whose unit is the mole. Chemists use ‘amount of substance’ as a mean of counting atoms

Anhydrous

A substance containing no water molecules

Anion

A negatively charged ion

Atomic Orbital

A region within an atom that can hold up to two electrons, with opposite spins

Atomic (proton) number

The number of protons in the nucleus of an atom

Avogadro constant, Na

The number of atoms per mole of the carbon-12 isotope (6.02 x 1023 mol-1)

Base

A species that is a proton acceptor

Cation

A positively charged ions

Compound

A substance formed from two or more chemically bonded elements in a fixed ratio, usually shown by a chemical formula

Concentration

The amount of solute, in mol, per dm3 (1000cm3) of solution

Coordinate bond

A shared pair of electrons which has been provided by one of the bonding atoms only; also called a coordinate bond

Covalent bond

A bond formed by a shared pair of electrons

Dative covalent bond

A shared pair of electrons which been provided by one of the bonding atoms only; also called a coordinate bond

Delocalised electrons

Electrons that are shared between more than two atoms

Displacement Reaction

A reaction in which a more reactive element displaces a less reactive element from an aqueous solution of the latter’s ions

Disproportionation

The oxidation and reduction of the same element in a redox reaction

Electron configuration

The arrangement of electrons in an atom

Electronegativity

A measure of the attraction of a bonded pair of electrons in a covalent bond

Electron shielding

The repulsion between electrons in different inner shells. Shielding reduces the net attractive force from the positive nucleus on the outer shell electrons

Empirical formula

The simplest whole-number ratio of atoms of each element present in a compound

Giant covalent lattice

A three-dimensional structure of atoms, bonded together by strong covalent bonds

Giant ionic lattice

A three-dimensional structure of oppositely charged ions, bonded together by strong ionic bonds

Giant metallic lattice

A three-dimensional structure if positively charged ions and delocalised electrons, bonded together by strong metallic bonds

Group

A vertical column in the periodic table. Elements in a group have similar chemical properties and their atoms have the same number of outer-shell electrons

Hydrated

Crystalline and containing water molecules

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Intermolecular force

An attractive force between neighbouring molecules. Intermolecular forces can be Van der Waals’ forces (including dipole-dipole forces), permanent dipole-dipole forces or hydrogen bonds

Hydrogen Bond

A strong dipole-dipole attraction between an electron deficient hydrogen atom on one molecule and a lone pair of electrons on a highly electronegative atom on a different molecule

Intermolecular force

An attractive force between neighbouring molecules. Intermolecular forces can be Van der Waals’ forces (including dipole-dipole forces), permanent dipole-dipole forces or hydrogen bonds

Ion

A positively or negatively charged atom or (covalently bonded) group of atoms (a molecular ion)

Ionic bond

The electrostatic attraction between oppositely charge ions

(first) Ionisation energy

The energy required to remove one electron from each atom in mole of gaseous atoms to form one mole of gaseous 1+ ions

(second) Ionisation energy

The energy required to remove one electron from each ion in one mole of gaseous 1+ ions to form one mole of gaseous 2+ ions

(successive) Ionisation energy

A measure of the energy required to remove each electron in turn

Isotopes

Atoms of the same element with different numbers of neutrons and different masses

Lone pair

An outer shell pair of electrons that is not involved in chemical bonding

Mass (nucleon number)

The number of particles (protons and neutrons) in the nucleus

Metallic bond

The electrostatic attraction between positive metal ions and delocalised electrons

Molar mass, M

The mass per mole of a substance , g mol-1

Molar volume

The volume per mole of a gas. The units of molar volume are dm3mol-1.

Mole

The amount of any substance containing as many particles as there are carbon in exactly 12g of carbon-12 isotope

Molecular formula

The number of atoms of each element in a molecule

Molecule

A small group of atoms held together by covalent bonds

Oxidation

Loss of electrons or an increase in oxidation number

Oxidation number

A measure of the number of electrons that an atoms uses to bond with atoms of another element. Oxidation numbers are derived from a set of rules

Oxidising agent

A reagent that oxidises (takes electrons from) another species

Period

A horizontal row of elements on the periodic table

Periodicity

A regular periodic variation of properties of elements atomic number and position on the Periodic table

Permanent dipole

A small charge difference across a bond resulting from a difference in electro negativities of the bonded atom

Permanent dipole-dipole force

An attractive force between permanent dipoles in neighbouring molecules

Polar covalent bond

A bond with a permanent dipole

Polar molecule

A molecule with an overall dipole, taking into account any dipoles across bonds

Precipitation reaction

The formation of a solid from a solutions during a chemical reaction. Precipitates are often formed when two aqueous solutions are mixed together

Principle quantum number, n

A number representing the relative overall energy of each orbital , which increases with distance from the nucleus. The sets of orbitals with same n value are referred to as electron shells or energy levels.

Redox reaction

A reaction in which reduction and oxidation take place.

Reducing agent

A reagent that reduces ( adds electrons to ) another species

Reduction

Gain of electrons or a decrease in oxidation number

Relative atomic mass, Ar

The weighted mean mass of a formula unit compared with one-twelfth of the mass of an atoms of catbon-12

Relative isotopic mass

The mass of an atom of an isotope compared with one-twelfth of the mass of an atom of carbon-12

Relative molecular mass, Mr

The weighted mean mass of a molecule compared with one-twelfth of the mass of an atom of carbon-12

Salt

A chemical compound formed from an acid, when a H+ ion from the acid has been replaced by a metal ion or another positive ion

Shell

A group of atomic orbitals with the same principal quantum number, n. Also known as a main energy level

Simple molecular lattice

A three-dimensional structure of molecules, bonded together by weak intermolecular forces

Species

Any type of particle that takes part in a chemical reaction

Standard solution

A solution of known concentration . Standard solutions are normally used in titration to determine unknown information about another substance

Stoichiometry

The molar relationship between the quantities of substances taking part in a reaction

Sub-shell

A group of the same type of atomic orbitals(s, p, d or f) within a shell

Thermal decomposition

The breaking up of a chemical substance with heat into at least two chemical substances

Van der Waals’ forces

Very weak attractive forces between induced dipoles in neighbouring molecules

Water of crystallisation

Water molecules that form an essential part of the crystalline structure of a compound