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96 Cards in this Set
- Front
- Back
Atoms
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composed of protons (nucleus-positive) neutrons (neutral charge-nucleus) and electrons (orbitals-positive)
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Protons/Neutrons/Electrons
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Protons - number of protons represent the atomic number of an element.
Neutrons- change in the number of neutrons results in different isotopes Electrons- orbitals, changes in the number of electrons results in different ions. |
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Ionic Bonds
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donation of valence electrons from one atom to another, occurs when electronegativity values of two atoms are different
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Covalent Bonds
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sharing of valence electrons between atoms, occurs when electronegativity values are similar
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Polar and Non-Polar Covalent Bonds
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Polar Covalent - electrons are unequally shared between atoms
Non-Polar Covalent - electrons are equally shared between the atoms |
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Avogadro's Number
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6.02x10^23 represents the number of atoms found in 12 grams of carbon 12, one mole.
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Mole
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standardized unit of measurement used to practically measure small amounts of chemicals
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What is Chemistry?
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study of matter and energy and the interactions between them, it focuses on the properties of substances
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Physical States
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solid - fixed shape and volume, liquid - fixed volume/conforms to shape of container/horizontal top surface, gas - takes shape and volume of container
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Matter
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has mass and weight, occupies space
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Mass vs. Weight
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Mass - the amount of matter something contains, unlike weight it doesn't vary with the objects location
Weight - the pull of gravity on an object, varies with the object's location. |
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Scientific Method
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Experiment - Results - Hypothesis - Theory
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Law of Conservation of Mass
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the sum of the masses of the reactants equals the sum of the masses of the products
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Extensive Properties
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depends on the specific sample (mass and weight)
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Intensive Properties
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identical in all samples (color, density, melting point)
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Physical Properties
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can be observed without changing the substances present in the substance
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Chemical Reaction
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reactants undergo chemical change to yield products
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Reaction Indications
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evolution of a gas, change of color, formation of precipitate
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Law of Definite Proportions
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ALL samples of the same pure substance always contain the same elements in the same proportions by weight.
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Pure Substances
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Elements - simplest substances
Compounds - made up of elements |
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Mixtures
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Heterogenous - uneven texture
Homogenous - solution, sample uniform throughout |
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Separation of Mixtures
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Filtration - utilize melting point, fractional crystallization, mechanical means)
Distillation - occurs due to differences in boiling point (separation of water and alcohol occur in a fractioning column) Chromatography |
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Scales
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Fahrenheit - most common
Rankin - F sized degrees, absolute scale Celsius - other common scale Kelvin - C sized degrees, absolute scale |
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Density
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mass/unit vol.
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Mass
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volume x density
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Volume
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mass / density
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Measured Numbers
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numbers obtained by using tools
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Exact Numbers
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not obtained by tools, obtained by definitions or counting.
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Atomic #
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is equal to the # of p+
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Number of Protons
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all atoms of an element have the same # of p+
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Charge of Atoms
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atoms have a zero net charge, they are neutral
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Number of Electrons
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is equal to the number of protons in an atom, hence the atomic number not only gives the number of protons but also the number of electrons
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Isotopes
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are two atoms with the same number of p+ but a different number of n
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Atomic Mass Determination
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atomic mass is determined by the weighted average mass of all the atom's isotopes.
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Atoms are...
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can exist alone or enter into chemical combination, they are the smallest indivisible particle of an element.
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Molecules are...
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a combination of atoms that has its own characteristic set of properties
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Law of Constant Composition
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a chemical compound always contains the same elements, in the same proportions, by mass
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Law of Multiple Proportions
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the same elements can be combined to form different compounds by combining the elements in different proportions
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Dalton's Postulate # 1
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an element is composed of tiny particles called atoms, all atoms of a given element share the same chemical properties
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Dalton's Postulate # 2
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atoms of different elements have different properties
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Dalton's Postulate # 3
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compounds are formed when atoms of 2 or more elements combine, in a given compound the relative number of atoms of each kind are definite and constant
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Dalton's Postulate # 4
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in an ordinary chemical reaction, no atom of any element disappears or is changed into an atom of another element, chemical reactions involve changing the way in which to atoms are joined together
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Alpha Radiation
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two protons and two neutrons, thus a Helium-4 nucleus, possesses a +2 charge and a mass of 4 amu, creates an element with an atomic # of 2 or lower. Ra222 -> Rn222 + He4 (alpha)
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Beta Radiation
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high energy electron which was ejected from nucleus, "neutron" converted to "proton", very little mass, -1 charge, creates element with atomic number 1
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Gamma Radiation
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nucleus has energy levels, energy released from nucleus as it changes from higher to lower energy levels, it has no mass and no charge.
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Thompson's Mass to Charge Ratio
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2 particles with the same mass to charge ratio move in the same path in a vacuum when subjected to the same electric and magnetic fields
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Millikins Oil Drop Experiment
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1909- entailed balancing the downward gravitational charge and the upward electric and buoyant forces on charged oil droplets suspended between two metal electrodes established the charge for a single electron 1.602 x 10^-19.
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Rutherford's Gold Foil
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alpha particle beam was directed onto a sheet of gold surrounded by zinc sulfide (indicator, glowed when struck by alpha particles). the alpha particles bounced off the atoms at angles less than 90 degrees, availing the fact that a dense object was in the center of the atoms.
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Rutherford's Atomic Model
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atoms are composed mostly of vacant space, all the positive charge, and most of the mass, are in a small central area called the nucleus, electrons are in the electron cloud surrounding the nucleus.
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Proton Charge and Mass
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found in nucleus, relative mass of 1.0073 amu, charge of +1
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Neutron Charge and Mass
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found in nucleus, relative mass of 1.0087 amu, neutral charge
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Electron Charge and Mass
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found in the electron cloud, relative mass of .00055, charge of -1
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If the Nucleus were 1" in diameter...
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the atom would be 1.5 miles in diameter
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Cations
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positive ions
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Anions
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negative ions
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Ionic Compounds
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combo of cations and anions
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Z Number
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number of protons in the nucleus, the number of electrons in a neutral atom, the integer on the periodic table for each element
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Mass Number
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integer representing the approximate mass of an atom, equal to the sum of the number of p+ and n in the nucleus
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H-2 Deuterium
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one proton and one neutron
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H-3 Tritium
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one proton and two neutrons
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Natural Atomic Mass
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natural atomic mass = sum [(atomic mass of isotope) x (fractional abundance)]
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Period
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horizontal row on the periodic table
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Group
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vertical column on the periodic table
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Group IA
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alkali metals
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Group IIA
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alkaline earth metals
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Group VIIA
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halogens
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Group VIIIA
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noble gases
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Types of Elements
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metals, non-metals, metalloids-semimetals
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Ionic Bonding - characteristics
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non-volatile, thus high melting points, solids do not conduct electricity, liquid state will, many (but not all) are water soluble
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Celsius to Fahrenheit
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(1.8 x C) + 32 = F
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Fahrenheit to Celsius
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.55 x (F - 32) = C
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Celsius to Kelvin
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C + 273.15
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Kelvin to Fahrenheit
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Convert K to C then C to F
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Boiling Point of Water
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373K
100C 212F |
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Room Temperature
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293K
20C 68F |
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Body Temperature
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37C
98.6F |
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Water Freezes @
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273K
0C 32F |
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Significant Numbers
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ALL Non Zeros
Zeros between Non Zeros Zeros to the right of the Non Zeros and to the right of the decimal |
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Separation of Matter
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Matter is either Hetero- or Homogenous. Heterogenous matter can be separated into Homogenous matter. Homogenous matter combines to form solutions. Solutions can be separated into pure substances, that is, compounds or elements. Elements combine to form compounds which can be separated back into elements.
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Observation
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a statement that accurately describes something we see, hear, taste, feel or smell
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Conclusion
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statement that is based on what we think about a series of observations, "interpretation of the available observations"
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Data
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observations we make while performing an experiment
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Scientific Law
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a generalization that is uniformly applicable to a host of situations based on the results of many experiments
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Hypothesis
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tentative explanation used in the development of a theory
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Decomposition
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one substance is changed into two or more substances
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Number of Elements
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90 - natural, 27 - man-made
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Qualitative Observations
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color, presence of heat, etc. have no numerical value
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Quantitative Observations
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measurements, observations that deal with numerical values
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SI Base Units
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Length (m) meter
Mass (kg) kilogram Time (s) second Electric Current (A) ampere Temperature (K) Kelvin Amount of Substance (mol) mole Luminous Intensity (cd) candela |
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1 amu
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1.66054 x 10^-27 kg
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English to Metric - Length
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1 in. = 2.54 cm
1 yd = .9144 m 1 mi = 1.609 km |
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English to Metric - Mass
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1 lb = 454 g
1 oz = 28.35 g |
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English to Metric - Volume
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1 gal = 3.785 L
1 qt = 946.4 ml 1 fl. oz = 29.6 ml |
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Accuracy
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refers to how close a measurement is to the correct value
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Precision
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how closely repeated measurements of a quantity come to each other and to the average
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Density Mass and Volume Relation
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D = M/V
M = D * V V = M/D |