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140 Cards in this Set
- Front
- Back
the study of structure and properties of matter
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chemistry
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one who studies the structure and properties of matter in order to figure out something or make something new
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chemist
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designs, builds, and operates a chemical plant
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chemical engineer
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an explanation of a phenomenon; must have a great deal of evidence
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theory
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a specific kind of matter
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chemical
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anything that has the property of inertia
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matter
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the tencency to maintain the present state of motion
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inertia
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the capacity to do work
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energy
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energy: motion, faster is more
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kinetic energy
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energy: position (where something could make it move); higher is more (in accordance to gravity)
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potential energy
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energy: transferred in electromagnetic waves
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radiant energy
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rule of nature
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law
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mass is conserved; mass can neither be created nor destroyed
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law of conservation of mass
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energy is conserved; energy can neither be created nor destroyed
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law of conservation of energy
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Einstein's revised law; mass-->energy, energy-->mass; the total amount of matter and energy in the universe is constant
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law of conservation of mass/energy
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observation --> problem
hypothesis --> educated guess experiment --> test analyze --> right or wrong |
scientific method
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10^12 or 1,000,000,000,000
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tera (T)
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10^9 or 1,000,000,000
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giga (G)
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10^6 or 1,000,000
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mega (M)
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10^3 or 1,000
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kilo (k)
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10^-1 or 1/10
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deci (d)
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10^-2 or 1/100
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centi (c)
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10^-3 or 1/1000
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milli (m)
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10^-6 or 1/1,000,000
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micro
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10^-9 or 1/1,000,000,000
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nano (n)
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10^-12 or 1/1,000,000,000,000
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pico (p)
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converting units
e.g. convert 225 meters to megameters (225 m/1)(1 Mm/1,000,000)=.000225 Mm |
dimensional analysis
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descriptive
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qualitative
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a number
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quantitative
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distance between two points; measured in meters (m); measured by meter stick
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length
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the amount of matter; measured in kilograms (kg); measured by balance scale
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mass
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interval between two events; measured in seconds (s); measured by a watch
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time
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averaged kinetic energy of particles; measured in kelvin (K); measured by thermometer
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temperature
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rate at which charge moves through a wire; measured in ampere (amp, A); measured by ammeter
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electric current
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measured in moles (mol)
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chemical quantity of a substance
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brightness; measured in candela (cd)
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luminous intensity
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amount of space; V=l*w*h; derived from length
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amount of space
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D=m/V; derived from mass and lenght
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density
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measure of force of gravity; SI unit is newton (N); 1 N=1kg*m/s^2; derived from mass, length, and time
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weight
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correctness
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accuracy
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reproducibility in a measurement
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precision
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general term meaning on e kind of matter
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material
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2 or more materials mixed together
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mixture
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physically separate part of a mixture
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phase
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the boundary between two phases
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interface
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mixture that is the same throughout e.g. salt water
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homogeneous
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mixture that is not the same throughout e.g. ice water
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heterogeneous
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a homogeneous mixture
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solution
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what is dissolved (the lesser amount) in a solution
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solute
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what the solute is dissolved in (greater amount)
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solvent
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a way to quantify the concentration of a solution
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molarity
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a homogeneous material that always has the same composition e.g. salt: NaCl, sulfur: S, water: H2O
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substance
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a substance made of only one kind of atom
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element
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a substance made of 2 or more kinds of atoms
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compound
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regardless of the amount of a compound it is always composed of the same elements in the same proportions
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the law of definite proportions
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when different compounds of the same elements are formed e.g. CO, CO2, CO3;always combine in small whole-number ratios
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the law of multiple proportions
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has a shape and volume; particles are close together
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solid
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has volume but no shape; particles aren't as close
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liquid
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has no shape or volume; particles are far apart
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gas (vapor)
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has no shape and no volume; particles very far apart
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plasma (ionized gas)
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removed electrons done by lots of heat; most matter in universe is on this state
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ionized gas (plasma)
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depends on the amount (mass, weight, volume)
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extensive properties
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not dependant on amount (color, shape, melting and boiling points, malleable, ductile, density)
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intensive properties
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change in a physical property; no new substance formed e.g. ice melts, still H2O
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physical changes
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attraction for molecules in paper
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polarity
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change in which new substance is formed; often energy is released or absorbed
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chemical change
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All matter is made of atoms.
All atoms of the same element are identical. Atoms combine in simple ratios to form compounds. |
John Dalton's Atomic Theory
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number of protons in one atom of element (also number of electrons)
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atomic number
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an atom of the same element but with different mass because different number neutrons
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isotope
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one particular kind of atom
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nuclide
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a particle in the nucleus (proton, neutron)
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nucleon
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number of nucleons (protons + neutrons0
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mass number
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average mass of all the isotopes of an element (bottom number)
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atomic mass
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23
Na 11 How many protons? Neutrons? Electrons? |
11
12 11 |
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characterized by lambda; measured in meters
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wavelength
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v=3.00*10^8
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speed of light
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developed quantum theory
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Max Planck
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radiant energy is not just waves it is also particles called photons or quanta (bundles of energy); energy of the light is not proportional the the intensity (brightness), it is related to frequency
Equation: E=hf, h=6.63E-34 electron gains energy and moves up to a higher energy level then drops back to its original energy level therefore gives off energy in the form of light |
Planck's quantum theory
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the study of quanta or photons (very small particles)
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quantum mechanics
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developed the equation that relates particles to waves
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Erwin Schrodinger
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used Schrodinger's equation to calculate the probability of finding the electron in a hydrogen atom at any given position (53 picometers from nucleus)
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Max Born
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quantum number:
the energy level (principal quantum number); tells how many electrons are in each energy level (n=1 -> 2, n=2 -> 8, etc)...max #=2n^2; largest atoms have 7 energy levels |
n
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quantum number:
the sublevel; s-->2 electrons, p-->6 electrons, d-->10 electrons, f-->14 electrons; n=1 --> s; n=2 --> s, p; n=3 --> s,p,d; n=4 --> s,p,d,f |
l
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quantum number:
the orbital-path for 2 electrons; degenerate orbitals- orbitals that have the same amount of energy there same n and same l |
m
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quantum number:
the spin of the electron (clockwise or counter clockwise); 2 electrons in the same orbital always have opposite spins |
s
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no two electrons in the same atom have all four quantum numbers the same
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Pauli Exclusion Principle
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how difficult it is to stop a moving object; =mass*velocity; P=mv
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momentum
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It is impossible to know botht he position and the momentum of an electron simultaneously
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Heisenberg Uncertainty Principle
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model in which electrons spinning around the nucleus form a cloud of negative stuff
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electron cloud model
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arranged elements by atomic masses but found similar chemical properties where not just every 8; found pattern but there were some holes, turned out those elements had not been discovered yet
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Dmitri Mendeleev
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found very few exceptions to Mendeleev's pattern; arranged elements by atomic number then pattern worked
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Henry Mosely
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chemical properties of elements are a function of atomic numbers
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periodic law
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alkali metals
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first group on periodic table
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alkaline earth metals
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second group on periodic table
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chalcogens
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sixteenth group on periodic table
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halogens
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seventeenth group on periodic table
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noble gases
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eighteenth group on periodic table
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short columns on periodic table
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transition elements (metals)
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next to bottom row on periodic table
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lanthanoids
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bottom row on periodic table
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actinoids
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an atom with 8 electrons in its highest energy level is chemically stable
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octet rule
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electrons in the highest energy level
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valence electrons
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hard and shiny; solids; good conductors of heat and electricity; tend to have 1, 2, 3 valence electrons, malleable
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metals
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not hard or shiny; poor conductors; tend to have 5, 6, 7, 8, valence electrons; brittle (if solid)
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nonmetals
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have some properties of both metals and nonmetals
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metalloids
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radius of an atom; distance from nucleus to the highest electron; down a group - increases; across a period - decreases slightly
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atomic radius
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radius of an ion; if ion is positive by losing - decreases; if ion is negative gaining - decreases
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ionic radius
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energy required to remove the outermost electron; move across a period - increases (gets more difficult to remove); move done a group - decreases (shielding effect: how much stuff between nucleus and energy level)
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first ionization energy
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gain 1 electron, lose 1 electron, share its one elctron with another atom
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ways hydrogen can bond with other elements
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different structural forms of the same element
Carbon: 1. graphite: carbon in chains 2. diamond: carbon in diamond shape, much like baseball field Oxygen: 1. O2 in atmosphere 2. O3 ozone |
allotropes
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one or more symbols sometimes with subscripts to represent a compound
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chemical formula
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electrostatic force holding ions together in an ionic compound; high melting points, soluble in water, good conductors of electricity in molten state, well defined crystals, large amount of energy released when formed
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ionic bond
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more than one atom becoming an ion
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polyatomic ions
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attraction of metal positive ions for the delocalized valence electrons
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metallic bonding
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mixture of a metal and another element
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alloy
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bond holding atoms together because they share electrons (to get 8 valence electrons); result is molecule; low melting point, poor conductor, brittle
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covalent bond
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molecules made of 2 atoms of the same element
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diatomic molecule
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which are diatomic molecules?
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elements that end in "gen" or "ine"
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name the prefixes in covalent compounds in order
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mono
di tri tetra penta |
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electronegativity difference is great
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ionic
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electronegativity difference is small
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covalent
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electronegativity of 1.67
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either ionic or covalent
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which type of bond, ionic or covalent, is most likely to be formed
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bond character
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the relative tendency to gain electrons when forming a bond
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electronegativity
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imaginary line in a molecule between the nucleus of one atom and the nucleus of another atom
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bond axis
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distance between the nucleus of one atom and the nucleus of another atom in a molecule
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bond length
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number of degrees between bond axes in a molecule
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bond angle
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radius of an atom not bonded to anything
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atomic radius
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raduis of an ion
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ionic radius
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radius of an atom that is covalently bonded to another atom
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covalent radius
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minimum distance between nucleus of bonded atom and next closes molecule
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van der Waals
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a compound that contains carbon; exceptions- CO2, CO;
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organic compounds
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name the organic prefixes in order
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meth
eth prop but pent hex hept oct non dec |
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two or more substance combined to form new substance
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chemical reaction
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AB+C --> CB+A
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single displacement
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AB+CD --> AD+CB
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double displacement
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A+B --> AB
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synthesis
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AB --> A+B
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decomposition
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organic compound + oxygen --> CO2 + H2O
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combustion
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Amadeo Avagadro
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discovered number of particles
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